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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[[4-(dimethylamino)phenyl]methyl]acetamide —— C20H24N2O3S
    2-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylsulfanyl)-N-[[4-(dimethylamino)phenyl]methyl]acetamide
    —— 2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide —— C19H26FN5OS
    2-[[4-amino-5-(2-cyclohexylethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide
    —— N-[2-(4-bromophenyl)sulfanylethyl]-2-(5-nitro-2-oxopyridin-1-yl)acetamide —— C15H14BrN3O4S
    N-[2-(4-bromophenyl)sulfanylethyl]-2-(5-nitro-2-oxopyridin-1-yl)acetamide
    —— N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-(5-nitro-2-oxopyridin-1-yl)acetamide —— C16H17N3O4S
    N-methyl-N-[(4-methylsulfanylphenyl)methyl]-2-(5-nitro-2-oxopyridin-1-yl)acetamide
    —— [2-oxo-2-[[(R)-phenyl(thiophen-2-yl)methyl]amino]ethyl] (2R)-2-phenylsulfanylpropanoate —— C22H21NO3S2
    [2-oxo-2-[[(R)-phenyl(thiophen-2-yl)methyl]amino]ethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl] (2R)-2-phenylsulfanylpropanoate —— C22H23NO3S
    [2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl] (2R)-2-phenylsulfanylpropanoate
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide —— C17H22N2OS
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide
    —— [5-(furan-2-yl)-1,2-oxazol-3-yl]methyl (2R)-2-phenylsulfanylpropanoate —— C17H15NO4S
    [5-(furan-2-yl)-1,2-oxazol-3-yl]methyl (2R)-2-phenylsulfanylpropanoate
    —— (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dimethylphenyl)sulfanylpropanamide —— C17H24N2OS
    (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(3,4-dimethylphenyl)sulfanylpropanamide
    —— [2-Oxo-2-(2,4,4-trimethylpentan-2-ylamino)ethyl] 2-(2-fluorophenyl)sulfanylacetate —— C18H26FNO3S
    [2-Oxo-2-(2,4,4-trimethylpentan-2-ylamino)ethyl] 2-(2-fluorophenyl)sulfanylacetate
    —— 3-benzylsulfanyl-4-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C16H12ClFN4S2
    3-benzylsulfanyl-4-[(Z)-(2-chloro-6-fluorophenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(4-ethylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C18H18N4S2
    3-benzylsulfanyl-4-[(Z)-(4-ethylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-benzylsulfanyl-4-[(Z)-(4-methylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C17H16N4S2
    3-benzylsulfanyl-4-[(Z)-(4-methylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 2-(5-bromo-2-oxopyridin-1-yl)-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C16H17BrN2O2S
    2-(5-bromo-2-oxopyridin-1-yl)-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 3-benzylsulfanyl-4-[(Z)-thiophen-2-ylmethylideneamino]-1H-1,2,4-triazole-5-thione —— C14H12N4S3
    3-benzylsulfanyl-4-[(Z)-thiophen-2-ylmethylideneamino]-1H-1,2,4-triazole-5-thione
    —— [2-[methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl] (E)-3-thiophen-3-ylprop-2-enoate —— C18H19NO3S2
    [2-[methyl-[(4-methylsulfanylphenyl)methyl]amino]-2-oxoethyl] (E)-3-thiophen-3-ylprop-2-enoate
    —— 1-methyl-1-[(1S)-1-phenylethyl]-3-(2-phenylsulfanylethyl)thiourea —— C18H22N2S2
    1-methyl-1-[(1S)-1-phenylethyl]-3-(2-phenylsulfanylethyl)thiourea
    —— 2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propylacetamide —— C15H22N4O2S
    2-[[5-(furan-2-yl)-4-(2-methylpropyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propylacetamide
    —— 2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide —— C18H29N5OS2
    2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-N-(thiophen-2-ylmethyl)acetamide
    —— 3,5-Dimethyl-4-[(4-phenyl-1,3-thiazol-2-yl)sulfanylmethyl]-1,2-oxazole —— C15H14N2OS2
    3,5-Dimethyl-4-[(4-phenyl-1,3-thiazol-2-yl)sulfanylmethyl]-1,2-oxazole
    —— Phenyl 2-phenylsulfanylpyridine-3-carboxylate —— C18H13NO2S
    Phenyl 2-phenylsulfanylpyridine-3-carboxylate
    —— 3-(3,5-dinitrophenyl)sulfanyl-1H-indole —— C14H9N3O4S
    3-(3,5-dinitrophenyl)sulfanyl-1H-indole
    —— N'-[2-(2,4-dimethylphenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide —— C15H17N3O2S
    N'-[2-(2,4-dimethylphenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide
    —— (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C14H18N4OS2
    (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— N'-[2-(4-bromo-2-methylphenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide —— C14H14BrN3O2S
    N'-[2-(4-bromo-2-methylphenyl)sulfanylacetyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[3-(3,4-dimethylphenyl)sulfanylpropanoyl]-1H-pyrrole-2-carbohydrazide —— C16H19N3O2S
    N'-[3-(3,4-dimethylphenyl)sulfanylpropanoyl]-1H-pyrrole-2-carbohydrazide
    —— N'-[2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-1H-pyrrole-2-carbohydrazide —— C15H12FN5O3S
    N'-[2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]-1H-pyrrole-2-carbohydrazide
    —— [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C14H18BrNO3S
    [(2R)-1-(ethylamino)-1-oxopropan-2-yl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— N-cyclopentyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H20N4O3S2
    N-cyclopentyl-N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— N-cyclopentyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C13H20N4O3S2
    N-cyclopentyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-1-oxidopyridin-1-ium —— C15H14ClNO3S
    2-[(6-chloro-3,4-dihydro-2H-1,5-benzodioxepin-8-yl)methylsulfanyl]-1-oxidopyridin-1-ium
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[3-(3,5-dimethylpyrazol-1-yl)propyl]acetamide —— C18H22N6OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[3-(3,5-dimethylpyrazol-1-yl)propyl]acetamide
    —— Ethyl 4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanoate —— C16H21N3O2S2
    Ethyl 4-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanoate
    —— 5-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-phenyl-1,3,4-thiadiazol-2-amine —— C17H15N5O2S2
    5-[[5-(2,5-dimethylfuran-3-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-N-phenyl-1,3,4-thiadiazol-2-amine
    —— 5-[[(1S)-2,2-dichlorocyclopropyl]methylsulfanyl]-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine —— C13H13Cl2N3S2
    5-[[(1S)-2,2-dichlorocyclopropyl]methylsulfanyl]-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— N-[[1-[(3R)-1,1-dioxothiolan-3-yl]-3,5-dimethylpyrazol-4-yl]methyl]-N-methyl-2-phenylsulfanylacetamide —— C19H25N3O3S2
    N-[[1-[(3R)-1,1-dioxothiolan-3-yl]-3,5-dimethylpyrazol-4-yl]methyl]-N-methyl-2-phenylsulfanylacetamide
    —— 5-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine —— C13H13Cl2N3S2
    5-[[(1R)-2,2-dichlorocyclopropyl]methylsulfanyl]-N-(4-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— N-[[1-[(3S)-1,1-dioxothiolan-3-yl]-3,5-dimethylpyrazol-4-yl]methyl]-N-methyl-3-phenylsulfanylpropanamide —— C20H27N3O3S2
    N-[[1-[(3S)-1,1-dioxothiolan-3-yl]-3,5-dimethylpyrazol-4-yl]methyl]-N-methyl-3-phenylsulfanylpropanamide
    —— Ethyl 4-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanoate —— C15H19N3O2S2
    Ethyl 4-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanoate
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-6-oxo-4,5-dihydro-1H-pyridazine-3-carboxamide —— C19H19N3O2S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-6-oxo-4,5-dihydro-1H-pyridazine-3-carboxamide
    —— 2-[[5-(3,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C12H15N3OS2
    2-[[5-(3,4-Dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— 5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-N-phenyl-1,3,4-thiadiazol-2-amine —— C19H17N5OS2
    5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-N-phenyl-1,3,4-thiadiazol-2-amine
    —— (2R)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C15H20N4OS2
    (2R)-2-[[5-(4-ethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— [2-(cyclopentylamino)-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C16H19N3O4S
    [2-(cyclopentylamino)-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C18H23N3O4S
    [2-[[(1S,2S)-2-methylcyclohexyl]amino]-2-oxoethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— [2-oxo-2-(propylamino)ethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate —— C14H17N3O4S
    [2-oxo-2-(propylamino)ethyl] 2-[(3-cyano-4-methyl-6-oxo-1H-pyridin-2-yl)sulfanyl]acetate
    —— (2R)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C15H20N4OS2
    (2R)-2-[[5-(2,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— 4-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile —— C11H13N5OS2
    4-[[5-(Cyclopropylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-ethanimidoyl-3-oxobutanenitrile
    —— N-(2-methylphenyl)-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C20H19N5OS2
    N-(2-methylphenyl)-5-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-(3,4-dimethylphenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C15H19N3OS2
    N-(3,4-dimethylphenyl)-5-[[(2R)-oxolan-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine