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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenyl)acetamide —— C23H23NO2S
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenyl)acetamide
    —— (1'S,5'R)-N-(furan-2-ylmethyl)spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide —— C17H23NO2S2
    (1'S,5'R)-N-(furan-2-ylmethyl)spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxamide
    —— 2-(4-cyanophenoxy)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide —— C23H20N2O2S
    2-(4-cyanophenoxy)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide
    —— 1-(2,3-Dimethylphenyl)-3-(3-phenylsulfanylpropanoylamino)thiourea —— C18H21N3OS2
    1-(2,3-Dimethylphenyl)-3-(3-phenylsulfanylpropanoylamino)thiourea
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenoxy)acetamide —— C23H23NO3S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(4-methoxyphenoxy)acetamide
    —— N-[4-(4-bromophenyl)sulfanylphenyl]-3-phenylpropanamide —— C21H18BrNOS
    N-[4-(4-bromophenyl)sulfanylphenyl]-3-phenylpropanamide
    —— 1-(Azepan-1-yl)-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H18FN3OS3
    1-(Azepan-1-yl)-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— 3-[(4-fluorophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine —— C16H15FN6S
    3-[(4-fluorophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— 2-[[5-[(2E)-2-[1-(4-bromophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C12H11BrN6S
    2-[[5-[(2E)-2-[1-(4-bromophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— 3-[(3-bromophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine —— C16H15BrN6S
    3-[(3-bromophenyl)methylsulfanyl]-N-[(E)-1-pyridin-2-ylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— N-(2-phenylethyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H22N6OS
    N-(2-phenylethyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(4-fluorophenyl)methyl]-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H13F2N3OS3
    N-[(4-fluorophenyl)methyl]-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C14H16FN3O2S3
    2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— N-[(E)-1-(4-bromophenyl)ethylideneamino]-3-(pyridin-4-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine —— C16H15BrN6S
    N-[(E)-1-(4-bromophenyl)ethylideneamino]-3-(pyridin-4-ylmethylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— 3-benzylsulfanyl-N-[(E)-1-(4-fluorophenyl)ethylideneamino]-1H-1,2,4-triazol-5-amine —— C17H16FN5S
    3-benzylsulfanyl-N-[(E)-1-(4-fluorophenyl)ethylideneamino]-1H-1,2,4-triazol-5-amine
    —— N-tert-butyl-2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H21FN6OS
    N-tert-butyl-2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[2-(4-fluorophenyl)ethyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H21FN6OS
    N-[2-(4-fluorophenyl)ethyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-[(3-bromophenyl)methylsulfanyl]-N-[(E)-1-phenylethylideneamino]-1H-1,2,4-triazol-5-amine —— C17H16BrN5S
    3-[(3-bromophenyl)methylsulfanyl]-N-[(E)-1-phenylethylideneamino]-1H-1,2,4-triazol-5-amine
    —— 2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C17H17FN6O2S
    2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— N-benzyl-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H19N7OS
    N-benzyl-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-cyclopentyl-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H21N7OS
    N-cyclopentyl-2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-(2-adamantyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C22H27N5OS
    1-(2-adamantyl)-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— N-[(4-fluorophenyl)methyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H19FN6OS
    N-[(4-fluorophenyl)methyl]-2-[[5-[(2E)-2-(1-phenylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C11H13N7OS
    2-[[5-[(2E)-2-(1-pyridin-2-ylethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-cyclopentyl-2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H21FN6OS
    N-cyclopentyl-2-[[5-[(2E)-2-[1-(4-fluorophenyl)ethylidene]hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-ethanimidoyl-3-oxo-4-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]butanenitrile —— C17H19N5O2S2
    2-ethanimidoyl-3-oxo-4-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]butanenitrile
    —— 2-ethanimidoyl-3-oxo-4-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]butanenitrile —— C17H19N5O2S2
    2-ethanimidoyl-3-oxo-4-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]butanenitrile
    —— 2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone —— C19H24N4O2S
    2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone
    —— N-[(3-chlorophenyl)methyl]-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H13Cl2N3O2S
    N-[(3-chlorophenyl)methyl]-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N,N-bis(2-cyanoethyl)-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C15H14N6O2S
    N,N-bis(2-cyanoethyl)-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1R)-1-(1-adamantyl)ethyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C21H26N4O2S
    N-[(1R)-1-(1-adamantyl)ethyl]-2-[(5-pyridin-3-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— ethyl (2S)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-phenylacetate —— C18H15ClN2O3S
    ethyl (2S)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-2-phenylacetate
    —— 4-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one —— C16H13ClN2O2S2
    4-[[5-(4-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-thiophen-2-ylbutan-1-one
    —— N-[(1R,2R)-2-methylcyclohexyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide —— C14H20N2O2S
    N-[(1R,2R)-2-methylcyclohexyl]-2-(1-oxidopyridin-1-ium-2-yl)sulfanylacetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C13H14ClN3O3S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide —— C14H16ClN3O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methylpropyl)acetamide
    —— 2-(4-Chlorophenyl)-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,3,4-oxadiazole —— C17H15ClN2OS
    2-(4-Chlorophenyl)-5-[(2,5-dimethylphenyl)methylsulfanyl]-1,3,4-oxadiazole
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide —— C18H15ClFN3O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide —— C20H20ClN3O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)acetamide —— C18H16ClN3O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-phenylethyl)acetamide
    —— N-(1-adamantylmethyl)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H24ClN3O2S
    N-(1-adamantylmethyl)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-(4-Chlorophenyl)-5-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole —— C18H12ClN3OS2
    2-(4-Chlorophenyl)-5-[(2-phenyl-1,3-thiazol-4-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— (2S)-2-(4-methylsulfanylphenyl)pentan-2-ol —— C12H18OS
    (2S)-2-(4-methylsulfanylphenyl)pentan-2-ol
    —— (2S)-2-(3-methylsulfanylphenyl)pentan-2-ol —— C12H18OS
    (2S)-2-(3-methylsulfanylphenyl)pentan-2-ol
    —— [2-(Ethoxycarbonylamino)-2-oxoethyl] 2-(4-bromophenyl)sulfanylacetate —— C13H14BrNO5S
    [2-(Ethoxycarbonylamino)-2-oxoethyl] 2-(4-bromophenyl)sulfanylacetate
    —— (1S)-1-[2-(3-methylbutylsulfanyl)phenyl]ethanol —— C13H20OS
    (1S)-1-[2-(3-methylbutylsulfanyl)phenyl]ethanol
    —— (2S)-2-(4-ethylsulfanylphenyl)pentan-2-ol —— C13H20OS
    (2S)-2-(4-ethylsulfanylphenyl)pentan-2-ol
    —— (1S)-1-(2-pentylsulfanylphenyl)ethanol —— C13H20OS
    (1S)-1-(2-pentylsulfanylphenyl)ethanol
    —— (2S)-2-(2-methylsulfanylphenyl)pentan-2-ol —— C12H18OS
    (2S)-2-(2-methylsulfanylphenyl)pentan-2-ol
    —— (1S)-1-(4-methylsulfanylphenyl)but-3-en-1-ol —— C11H14OS
    (1S)-1-(4-methylsulfanylphenyl)but-3-en-1-ol