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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(naphthalen-1-ylthio)pyridine 92498-41-4 C15H11NS
    2-(naphthalen-1-ylthio)pyridine
    —— N'-(4-methylsulfanylphenyl)pyridine-4-carboximidamide 812692-61-8 C13H13N3S
    N'-(4-methylsulfanylphenyl)pyridine-4-carboximidamide
    —— [3-(3-Chloro-1,1,2,2,3,3-hexafluoro-propoxy)-1,1,2,2,3,3-hexafluoro-propoxy]-difluoro-thioacetic acid S-pyridin-2-yl ester 380239-48-5 C13H4ClF14NO3S
    [3-(3-Chloro-1,1,2,2,3,3-hexafluoro-propoxy)-1,1,2,2,3,3-hexafluoro-propoxy]-difluoro-thioacetic acid S-pyridin-2-yl ester
    —— 4-(2-pyridylthio)-3,5-dimethylphenol 59089-58-6 C13H13NOS
    4-(2-pyridylthio)-3,5-dimethylphenol
    —— 5-methyl-N-[4-(methylthio)phenyl]-2-pyridinecarboximidamide 177662-56-5 C14H15N3S
    5-methyl-N-[4-(methylthio)phenyl]-2-pyridinecarboximidamide
    —— (perfluorophenyl)(o-tolyl)sulfane 1374639-69-6 C13H7F5S
    (perfluorophenyl)(o-tolyl)sulfane
    —— 5-methyl-2-[4-hydroxy-1-[4-(methylthio)phenyl]-4-(trifluoromethyl)-4,5-dihydro-1H-imidazol-2-yl]pyridine 177662-57-6 C17H16F3N3OS
    5-methyl-2-[4-hydroxy-1-[4-(methylthio)phenyl]-4-(trifluoromethyl)-4,5-dihydro-1H-imidazol-2-yl]pyridine
    —— S-pyridin-2-yl 4-phenylbutanethioate 76063-11-1 C15H15NOS
    S-pyridin-2-yl 4-phenylbutanethioate
    —— (all-Z)-Octadeca-3,6,9,12,15-pentaene-1-thiol 300552-99-2 C18H28S
    (all-Z)-Octadeca-3,6,9,12,15-pentaene-1-thiol
    —— 4-mercapto-4-methylbutan-1-ol 90325-01-2 C5H12OS
    4-mercapto-4-methylbutan-1-ol
    —— tridec-1-ene-3-thiol 909025-52-1 C13H26S
    tridec-1-ene-3-thiol
    —— 6-Hydroxy-2-(isopropylthio)pyrimidin-4(3H)-one 1026862-83-8 C7H10N2O2S
    6-Hydroxy-2-(isopropylthio)pyrimidin-4(3H)-one
    —— S-pyridin-2-yl 5,5-dimethyl-1,3-dioxane-2-carbothioate 744220-88-0 C12H15NO3S
    S-pyridin-2-yl 5,5-dimethyl-1,3-dioxane-2-carbothioate
    —— S-(pyridin-2-yl) 3-cyclohexylpropanethioate 749928-21-0 C14H19NOS
    S-(pyridin-2-yl) 3-cyclohexylpropanethioate
    —— 2'-(2″-pyridylthio)-1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-ol 1456629-15-4 C14H9F6NOS
    2'-(2″-pyridylthio)-1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-ol
    —— N-[4-(methylthio)phenyl]-3-pyridinecarboxamide 298204-73-6 C13H13N3S
    N-[4-(methylthio)phenyl]-3-pyridinecarboxamide
    —— 2-oxopropanethioamide 31787-50-5 C3H5NOS
    2-oxopropanethioamide
    —— 3-cyclohex-1-enyl-thiopropionic acid S-pyridin-2-yl ester 749927-74-0 C14H17NOS
    3-cyclohex-1-enyl-thiopropionic acid S-pyridin-2-yl ester
    —— 4-hydroxy-1 - [4-(methylthio)phenyl]-2-[2-(methylthio)-1,3,4-thiadiazol-5-yl]-4-(trifluoromethyl)-4,5-dihydro-1H-imidazole 518015-15-1 C14H13F3N4OS3
    4-hydroxy-1 - [4-(methylthio)phenyl]-2-[2-(methylthio)-1,3,4-thiadiazol-5-yl]-4-(trifluoromethyl)-4,5-dihydro-1H-imidazole
    —— (2,4-dimethylphenyl)(perfluorophenyl)sulfane 1374639-70-9 C14H9F5S
    (2,4-dimethylphenyl)(perfluorophenyl)sulfane
    —— S-2-pyridyl ethanethioate 10111-76-9 C7H7NOS
    S-2-pyridyl ethanethioate
    —— 2,3-Dihydrothiopyrano<2,3-b>pyridine 103020-21-9 C8H9NS
    2,3-Dihydrothiopyrano<2,3-b>pyridine
    —— 4-Methyl-2-(pyridin-2-ylsulfanyl)-pentanoic acid amide 189809-77-6 C11H16N2OS
    4-Methyl-2-(pyridin-2-ylsulfanyl)-pentanoic acid amide
    —— 7-(2-pyridylthio)heptanoic acid ethyl ester 1356156-33-6 C14H21NO2S
    7-(2-pyridylthio)heptanoic acid ethyl ester
    —— 4,4-Dimethyl-2-(pyridin-2-ylsulfanyl)-pentanoic acid amide 189809-79-8 C12H18N2OS
    4,4-Dimethyl-2-(pyridin-2-ylsulfanyl)-pentanoic acid amide
    —— 3-cyclohexyl-2-(2-pyridylsulfanyl)-propionamide 189809-76-5 C14H20N2OS
    3-cyclohexyl-2-(2-pyridylsulfanyl)-propionamide
    —— 2-(2-pyridylthio)-hexanedioic acid-1-methyl ester 6-pentyl ester 1356156-34-7 C17H25NO4S
    2-(2-pyridylthio)-hexanedioic acid-1-methyl ester 6-pentyl ester
    —— ethyl 2-methyl-2-(pyridin-2-ylthio)propanoate 119368-35-3 C11H15NO2S
    ethyl 2-methyl-2-(pyridin-2-ylthio)propanoate
    —— N-methyl 2-methylthiopyridium 45661-51-6 C7H10NS
    N-methyl 2-methylthiopyridium
    —— 3-(pyridin-2-yl sulfanyl)-propionic acid pentyl ester 1356156-32-5 C13H19NO2S
    3-(pyridin-2-yl sulfanyl)-propionic acid pentyl ester
    —— 1,1,1,3,3,3-Hexafluor-2-Chlor-Isopropyl-(Hexafluorisopropylidenimino)-Schwefel(II) 76080-54-1 C6ClF12NS
    1,1,1,3,3,3-Hexafluor-2-Chlor-Isopropyl-(Hexafluorisopropylidenimino)-Schwefel(II)
    —— naphthalen-2-yl(2,3,5,6-tetrafluorophenyl)sulfane 1372616-50-6 C16H8F4S
    naphthalen-2-yl(2,3,5,6-tetrafluorophenyl)sulfane
    —— (perfluorophenyl)(m-tolyl)sulfane 1374639-68-5 C13H7F5S
    (perfluorophenyl)(m-tolyl)sulfane
    —— 2-(2,3,5,6-tetrafluorophenylthio)benzo[d]thiazole 1374639-72-1 C13H5F4NS2
    2-(2,3,5,6-tetrafluorophenylthio)benzo[d]thiazole
    —— 1,4-bis(o-tolylthio)-2,3,5,6-tetrafluorobenzene 1374639-64-1 C20H14F4S2
    1,4-bis(o-tolylthio)-2,3,5,6-tetrafluorobenzene
    —— 1,4-bis(2,4-dimethylphenylthio)-2,3,5,6-tetrafluorobenzene 1374639-65-2 C22H18F4S2
    1,4-bis(2,4-dimethylphenylthio)-2,3,5,6-tetrafluorobenzene
    —— 1,4-bis(m-tolylthio)-2,3,5,6-tetrafluorobenzene 1374639-63-0 C20H14F4S2
    1,4-bis(m-tolylthio)-2,3,5,6-tetrafluorobenzene
    —— benzyl(2,3,5,6-tetrafluorophenyl)sulfane 1376608-47-7 C13H8F4S
    benzyl(2,3,5,6-tetrafluorophenyl)sulfane
    —— 1,4-bis(3-fluorophenylthio)-2,3,5,6-tetrafluorobenzene 1374639-67-4 C18H8F6S2
    1,4-bis(3-fluorophenylthio)-2,3,5,6-tetrafluorobenzene
    —— 4-methyl-6-[(3-methylphenyl)amino]-2-(methylthio)-5-pyrimidinecarbonitrile 1208170-18-6 C14H14N4S
    4-methyl-6-[(3-methylphenyl)amino]-2-(methylthio)-5-pyrimidinecarbonitrile
    —— 4-[(E)-2-(dimethylamino)ethenyl]-6-[(3-methylphenyl)amino]-2-(methylthio)-5-pyrimidinecarbonitrile 1208170-19-7 C17H19N5S
    4-[(E)-2-(dimethylamino)ethenyl]-6-[(3-methylphenyl)amino]-2-(methylthio)-5-pyrimidinecarbonitrile
    —— ethyl 4-((3-chloro-4-fluorophenyl)amino)-5-methylthioselenopheno[3,4-d]pyrimidine-7-carboxylate 1380809-08-4 C16H13ClFN3O2SSe
    ethyl 4-((3-chloro-4-fluorophenyl)amino)-5-methylthioselenopheno[3,4-d]pyrimidine-7-carboxylate
    —— 1-(Phenylthio)hexan-2-one 66716-59-4 C12H16OS
    1-(Phenylthio)hexan-2-one
    —— (3-phenylpropane-1,1-diyl)bis(phenylsulfane) 58749-30-7 C21H20S2
    (3-phenylpropane-1,1-diyl)bis(phenylsulfane)
    —— 4-(1H-pyrazol-3-yl)-2-(methylthio)pyrimidine 496863-64-0 C8H8N4S
    4-(1H-pyrazol-3-yl)-2-(methylthio)pyrimidine
    —— 2,4-bisethylthio-5-bromo-6-methylpyrimidine 93238-49-4 C9H13BrN2S2
    2,4-bisethylthio-5-bromo-6-methylpyrimidine
    —— α-cyano-β-dimethylaminocrotonamide 92119-57-8 C7H11N3S
    α-cyano-β-dimethylaminocrotonamide
    —— 2-methoxy-3-<<ethoxy(thiocarbonyl)>thio>-5-ethyl-6-methylpyridine 139548-63-3 C12H17NO2S2
    2-methoxy-3-<<ethoxy(thiocarbonyl)>thio>-5-ethyl-6-methylpyridine
    —— 2-(tert-butylthio)-5-ethyl-6-methyl-3-aminopyridine 139393-97-8 C12H20N2S
    2-(tert-butylthio)-5-ethyl-6-methyl-3-aminopyridine
    —— 2-(tert-butylthio)-5-ethyl-6-methyl-3-nitropyridine 139393-96-7 C12H18N2O2S
    2-(tert-butylthio)-5-ethyl-6-methyl-3-nitropyridine