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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylethyl)-N-(thiophen-2-ylmethyl)acetamide —— C19H21N5O2S2
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-(2-phenylethyl)-N-(thiophen-2-ylmethyl)acetamide
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(2R)-6-methylheptan-2-yl]acetamide —— C14H25N5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(2R)-6-methylheptan-2-yl]acetamide
    —— N-methyl-N-[(5-methylfuran-2-yl)methyl]-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H23N3O3S2
    N-methyl-N-[(5-methylfuran-2-yl)methyl]-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2-methylphenyl)methyl]-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H23N3O2S2
    N-[(2-methylphenyl)methyl]-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2S)-heptan-2-yl]-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H29N3O2S2
    N-[(2S)-heptan-2-yl]-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-propan-2-yloxypropyl)acetamide —— C19H27N3O3S2
    2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-propan-2-yloxypropyl)acetamide
    —— 1-(2,5-Difluorophenyl)sulfanyl-2,4-dinitrobenzene —— C12H6F2N2O4S
    1-(2,5-Difluorophenyl)sulfanyl-2,4-dinitrobenzene
    —— N-hexyl-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H27N3O2S2
    N-hexyl-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2-fluorophenyl)methyl]-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20FN3O2S2
    N-[(2-fluorophenyl)methyl]-2-[[5-[(5R)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2-fluorophenyl)methyl]-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20FN3O2S2
    N-[(2-fluorophenyl)methyl]-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-[(2S)-5-methylhexan-2-yl]-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H29N3O2S2
    N-[(2S)-5-methylhexan-2-yl]-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 4-(2,5-difluorophenyl)sulfanyl-N,N-diethyl-3-nitrobenzenesulfonamide —— C16H16F2N2O4S2
    4-(2,5-difluorophenyl)sulfanyl-N,N-diethyl-3-nitrobenzenesulfonamide
    —— N-[(1R)-1-cyclopropylethyl]-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C18H23N3O2S2
    N-[(1R)-1-cyclopropylethyl]-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(2-fluorophenyl)ethyl]acetamide —— C12H14FN5OS
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(2-fluorophenyl)ethyl]acetamide
    —— 4-[[4-(2,4-Difluorophenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium —— C19H20F2N3OS2+
    4-[[4-(2,4-Difluorophenyl)sulfanyl-5,6-dimethylthieno[2,3-d]pyrimidin-2-yl]methyl]morpholin-4-ium
    —— 2-(2,4-Difluorophenyl)sulfanyl-5-nitrobenzonitrile —— C13H6F2N2O2S
    2-(2,4-Difluorophenyl)sulfanyl-5-nitrobenzonitrile
    —— 4-(2,4-difluorophenyl)sulfanyl-N,N-diethyl-3-nitrobenzenesulfonamide —— C16H16F2N2O4S2
    4-(2,4-difluorophenyl)sulfanyl-N,N-diethyl-3-nitrobenzenesulfonamide
    —— 2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-(3-phenylsulfanylpropyl)acetamide —— C13H17N5OS2
    2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-(3-phenylsulfanylpropyl)acetamide
    —— N-(2-phenylsulfanylethyl)-4-(thiophen-3-ylmethyl)piperazin-4-ium-1-carbothioamide —— C18H24N3S3+
    N-(2-phenylsulfanylethyl)-4-(thiophen-3-ylmethyl)piperazin-4-ium-1-carbothioamide
    —— 2-(4-Methoxyphenyl)-5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-1,3,4-oxadiazole —— C16H10F3N3O4S
    2-(4-Methoxyphenyl)-5-[2-nitro-4-(trifluoromethyl)phenyl]sulfanyl-1,3,4-oxadiazole
    —— Ethyl 2-[2-(2-chloro-4-nitrophenyl)sulfanyl-1,3-thiazol-4-yl]acetate —— C13H11ClN2O4S2
    Ethyl 2-[2-(2-chloro-4-nitrophenyl)sulfanyl-1,3-thiazol-4-yl]acetate
    —— 2-[2-Nitro-4-(trifluoromethyl)phenyl]sulfanyl-5-phenyl-1,3,4-oxadiazole —— C15H8F3N3O3S
    2-[2-Nitro-4-(trifluoromethyl)phenyl]sulfanyl-5-phenyl-1,3,4-oxadiazole
    —— 2-[2-Nitro-4-(trifluoromethyl)phenyl]sulfanyl-5-thiophen-2-yl-1,3,4-oxadiazole —— C13H6F3N3O3S2
    2-[2-Nitro-4-(trifluoromethyl)phenyl]sulfanyl-5-thiophen-2-yl-1,3,4-oxadiazole
    —— ethyl 2-[2-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3-thiazol-4-yl]acetate —— C18H19N3O2S3
    ethyl 2-[2-[[(7R)-7-methyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-yl]sulfanyl]-1,3-thiazol-4-yl]acetate
    —— (2S)-2-(1-methyltetrazol-5-yl)sulfanyl-N-(2-thiophen-2-ylethyl)propanamide —— C11H15N5OS2
    (2S)-2-(1-methyltetrazol-5-yl)sulfanyl-N-(2-thiophen-2-ylethyl)propanamide
    —— N-cyclopropyl-N-[(2-fluorophenyl)methyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C14H16FN5OS
    N-cyclopropyl-N-[(2-fluorophenyl)methyl]-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— N-(2-cyanoethyl)-N-(furan-2-ylmethyl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C20H19N3O2S2
    N-(2-cyanoethyl)-N-(furan-2-ylmethyl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— 2-(1-Methyltetrazol-5-yl)sulfanyl-1-[4-(thiophen-2-ylmethyl)piperazin-4-ium-1-yl]ethanone —— C13H19N6OS2+
    2-(1-Methyltetrazol-5-yl)sulfanyl-1-[4-(thiophen-2-ylmethyl)piperazin-4-ium-1-yl]ethanone
    —— Ethyl 2-(2-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3-thiazol-4-yl)acetate —— C13H11N3O2S3
    Ethyl 2-(2-thieno[2,3-d]pyrimidin-4-ylsulfanyl-1,3-thiazol-4-yl)acetate
    —— N-methyl-N-[(5-methylfuran-2-yl)methyl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C19H20N2O2S2
    N-methyl-N-[(5-methylfuran-2-yl)methyl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— 2-(1-Methyltetrazol-5-yl)sulfanyl-1-[4-(thiophen-2-ylmethyl)piperazin-1-yl]ethanone —— C13H18N6OS2
    2-(1-Methyltetrazol-5-yl)sulfanyl-1-[4-(thiophen-2-ylmethyl)piperazin-1-yl]ethanone
    —— 1-[(R)-(4-chlorophenyl)-(1-methylimidazol-2-yl)methyl]-3-(2-phenylsulfanylethyl)thiourea —— C20H21ClN4S2
    1-[(R)-(4-chlorophenyl)-(1-methylimidazol-2-yl)methyl]-3-(2-phenylsulfanylethyl)thiourea
    —— 2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-methyl-N-(thiophen-3-ylmethyl)acetamide —— C15H13N5OS2
    2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-methyl-N-(thiophen-3-ylmethyl)acetamide
    —— 2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-[(2-methylphenyl)methyl]acetamide —— C17H15N5OS
    2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-[(2-methylphenyl)methyl]acetamide
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[(1R)-1-(furan-2-yl)ethyl]acetamide —— C15H14N5O2S+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-[(1R)-1-(furan-2-yl)ethyl]acetamide
    —— 2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-ethyl-N-[(3-fluorophenyl)methyl]acetamide —— C18H16FN5OS
    2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-ethyl-N-[(3-fluorophenyl)methyl]acetamide
    —— 2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-[4-(2-methylbutan-2-yl)cyclohexyl]acetamide —— C20H27N5OS
    2-(6-amino-3,5-dicyanopyridin-2-yl)sulfanyl-N-[4-(2-methylbutan-2-yl)cyclohexyl]acetamide
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-methyl-N-(thiophen-3-ylmethyl)acetamide —— C15H14N5OS2+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-methyl-N-(thiophen-3-ylmethyl)acetamide
    —— N-[(2-fluorophenyl)methyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide —— C18H20FNOS
    N-[(2-fluorophenyl)methyl]-2-(2,4,6-trimethylphenyl)sulfanylacetamide
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-ethyl-N-[(3-fluorophenyl)methyl]acetamide —— C18H17FN5OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-ethyl-N-[(3-fluorophenyl)methyl]acetamide
    —— (2S)-2-(1-methylpyrrol-2-yl)-N-(2-phenylsulfanylethyl)azepane-1-carbothioamide —— C20H27N3S2
    (2S)-2-(1-methylpyrrol-2-yl)-N-(2-phenylsulfanylethyl)azepane-1-carbothioamide
    —— N-[(2R)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-2-thiophen-3-ylacetamide —— C15H17NO2S2
    N-[(2R)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-2-thiophen-3-ylacetamide
    —— methyl N-[(2R)-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoyl]carbamate —— C11H11N3O4S2
    methyl N-[(2R)-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoyl]carbamate
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C13H15N3O4S3
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-[(2-chlorophenyl)methyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C16H14ClN3O2S2
    (2R)-N-[(2-chlorophenyl)methyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-N-prop-2-enyl-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C12H13N3O2S2
    (2R)-N-prop-2-enyl-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-[(4-methylphenyl)methyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C17H17N3O2S2
    (2S)-N-[(4-methylphenyl)methyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— 2-(2-chlorophenyl)sulfanyl-1-[4-[(3R)-1,1-dioxothiolan-3-yl]piperazin-4-ium-1-yl]ethanone —— C16H22ClN2O3S2+
    2-(2-chlorophenyl)sulfanyl-1-[4-[(3R)-1,1-dioxothiolan-3-yl]piperazin-4-ium-1-yl]ethanone
    —— (2R)-N-benzyl-2-(2-chlorophenyl)sulfanylpropanamide —— C16H16ClNOS
    (2R)-N-benzyl-2-(2-chlorophenyl)sulfanylpropanamide
    —— 2-(4-Methylphenyl)-5-[(3-thiophen-3-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole —— C16H12N4O2S2
    2-(4-Methylphenyl)-5-[(3-thiophen-3-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole