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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-N-tert-butyl-2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C15H19ClN4OS2
    (2R)-N-tert-butyl-2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (5S,7S)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile —— C13H10N2OS2
    (5S,7S)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile
    —— (2R)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]-2-phenylacetic acid —— C13H9F3N2O3S
    (2R)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]-2-phenylacetic acid
    —— (5R,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile —— C13H10N2OS2
    (5R,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile
    —— (2S)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]-2-phenylacetic acid —— C13H9F3N2O3S
    (2S)-2-[[6-oxo-4-(trifluoromethyl)-1H-pyrimidin-2-yl]sulfanyl]-2-phenylacetic acid
    —— (5R,7S)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile —— C13H10N2OS2
    (5R,7S)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile
    —— [(2S)-1-oxo-1-(2-oxoimidazolidin-1-yl)propan-2-yl] (2R)-2-(4-methylphenyl)sulfanylpropanoate —— C16H20N2O4S
    [(2S)-1-oxo-1-(2-oxoimidazolidin-1-yl)propan-2-yl] (2R)-2-(4-methylphenyl)sulfanylpropanoate
    —— [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C15H21N3O4S
    [2-oxo-2-[[(2R)-oxolan-2-yl]methylamino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C16H23N3O4S
    [2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C18H21N3O3S
    [2-oxo-2-[[(1S)-1-phenylethyl]amino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C18H21N3O3S
    [2-oxo-2-[[(1R)-1-phenylethyl]amino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-oxo-2-[[(2S)-oxolan-2-yl]methylamino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C15H21N3O4S
    [2-oxo-2-[[(2S)-oxolan-2-yl]methylamino]ethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C16H23N3O4S
    [2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— [2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate —— C16H23N3O4S
    [2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl] 2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetate
    —— (Z)-1,4-bis(2-methylsulfonylethylsulfanyl)but-2-ene —— C10H20O4S4
    (Z)-1,4-bis(2-methylsulfonylethylsulfanyl)but-2-ene
    —— (Z)-N-[4-(2-chlorophenyl)sulfanylphenyl]-3-pyrazin-2-ylprop-2-enamide —— C19H14ClN3OS
    (Z)-N-[4-(2-chlorophenyl)sulfanylphenyl]-3-pyrazin-2-ylprop-2-enamide
    —— (Z)-3-pyridin-2-yl-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]prop-2-enamide —— C16H12N4OS2
    (Z)-3-pyridin-2-yl-N-[4-(1,3,4-thiadiazol-2-ylsulfanyl)phenyl]prop-2-enamide
    —— 1-propan-2-yl-5-[(Z)-4-(1-propan-2-yltetrazol-5-yl)sulfanylbut-2-enyl]sulfanyltetrazole —— C12H20N8S2
    1-propan-2-yl-5-[(Z)-4-(1-propan-2-yltetrazol-5-yl)sulfanylbut-2-enyl]sulfanyltetrazole
    —— (2Z,4Z)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide —— C16H17N3OS2
    (2Z,4Z)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide
    —— (2E,4Z)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide —— C16H17N3OS2
    (2E,4Z)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide
    —— (2Z,4E)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide —— C16H17N3OS2
    (2Z,4E)-N-[2-methyl-4-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]phenyl]hexa-2,4-dienamide
    —— 3-[(Z)-3-chloroprop-2-enyl]sulfanyl-6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepine —— C10H14ClN3S
    3-[(Z)-3-chloroprop-2-enyl]sulfanyl-6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepine
    —— [(2R)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 2-(2-fluorophenyl)sulfanylacetate —— C16H20FNO5S2
    [(2R)-1-[[(3R)-1,1-dioxothiolan-3-yl]-methylamino]-1-oxopropan-2-yl] 2-(2-fluorophenyl)sulfanylacetate
    —— (2R)-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)propanamide —— C14H17FN4O2S2
    (2R)-2-[[5-(3-fluoroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)propanamide
    —— 2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C15H18N4O2S
    2-[(4,5-dicyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— 3-[5-[2-(Cyclohexylamino)-2-oxoethyl]sulfanyl-4-(2-methylpropyl)-1,2,4-triazol-3-yl]propanamide —— C17H29N5O2S
    3-[5-[2-(Cyclohexylamino)-2-oxoethyl]sulfanyl-4-(2-methylpropyl)-1,2,4-triazol-3-yl]propanamide
    —— 5-[(4-Cyclopropyl-5-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-3-thiophen-3-yl-1,2,4-oxadiazole —— C13H13N5OS2
    5-[(4-Cyclopropyl-5-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-3-thiophen-3-yl-1,2,4-oxadiazole
    —— (2S)-N-(2-methoxyethyl)-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C17H23N3O3S2
    (2S)-N-(2-methoxyethyl)-2-[[5-[(5S)-5-methyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-chlorophenyl)methyl]propanamide —— C12H14ClN5OS
    (2S)-2-[(4-amino-1,2,4-triazol-3-yl)sulfanyl]-N-[(2-chlorophenyl)methyl]propanamide
    —— (2R)-N-[(2-chlorophenyl)methyl]-2-[[4-ethyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C19H21ClN4O2S
    (2R)-N-[(2-chlorophenyl)methyl]-2-[[4-ethyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— N-[(2,4-dimethylphenyl)methyl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H21N3O3S
    N-[(2,4-dimethylphenyl)methyl]-N-methyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (5-Methyl-1,2-oxazol-3-yl)methyl 2-(2-cyanophenyl)sulfanylbenzoate —— C19H14N2O3S
    (5-Methyl-1,2-oxazol-3-yl)methyl 2-(2-cyanophenyl)sulfanylbenzoate
    —— N-[(1R)-2-(dimethylamino)-1-phenylethyl]-2-(2-methylphenyl)sulfanylacetamide —— C19H24N2OS
    N-[(1R)-2-(dimethylamino)-1-phenylethyl]-2-(2-methylphenyl)sulfanylacetamide
    —— (2R)-2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C14H18FN5OS
    (2R)-2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— 3-[(4-fluorophenyl)methyl]-5-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine —— C19H16F2N6OS
    3-[(4-fluorophenyl)methyl]-5-[(1R)-1-[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-1,2,4-triazol-4-amine
    —— (2S)-2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide —— C14H18FN5OS
    (2S)-2-[[4-amino-5-[(4-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-ethylpropanamide
    —— (2S)-2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide —— C13H15ClN4OS2
    (2S)-2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-ethylpropanamide
    —— (2R)-2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C13H15ClN4OS2
    (2R)-2-[[5-(3-chloroanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— [(2S)-1-(ethylamino)-1-oxopropan-2-yl] (2R)-2-(4-methylphenyl)sulfanylpropanoate —— C15H21NO3S
    [(2S)-1-(ethylamino)-1-oxopropan-2-yl] (2R)-2-(4-methylphenyl)sulfanylpropanoate
    —— (2S)-2-[[5-[(2R)-1-(dimethylamino)-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C12H20N4O2S3
    (2S)-2-[[5-[(2R)-1-(dimethylamino)-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 1-ethyl-2,5-dimethylpyrrole-3-carboxylate —— C20H26N2O3S
    [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 1-ethyl-2,5-dimethylpyrrole-3-carboxylate
    —— (2S)-2-[[5-[(2S)-1-(dimethylamino)-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide —— C12H20N4O2S3
    (2S)-2-[[5-[(2S)-1-(dimethylamino)-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N,N-dimethylpropanamide
    —— 2-[[5-(Propylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one —— C16H19N5OS3
    2-[[5-(Propylamino)-1,3,4-thiadiazol-2-yl]sulfanylmethyl]-6,7,8,9-tetrahydropyrimido[2,1-b][1,3]benzothiazol-4-one
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H19ClN4OS2
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C16H21FN4OS2
    (2S)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C16H24N4OS2
    1-(2,5-Dimethyl-1-propan-2-ylpyrrol-3-yl)-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C16H21FN4OS2
    (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 5-[(4-methylsulfanylphenyl)methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine —— C13H17N3S3
    5-[(4-methylsulfanylphenyl)methylsulfanyl]-N-propyl-1,3,4-thiadiazol-2-amine
    —— N-[(1S,2R)-2-methylcyclohexyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H24N4OS2
    N-[(1S,2R)-2-methylcyclohexyl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-[1-(Furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C18H22N4O2S2
    1-[1-(Furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[[5-(propylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone