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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-[(2,5-Dimethylphenyl)methylsulfanyl]-1,3-dimethyl-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C21H26N4O2S
    5-[(2,5-Dimethylphenyl)methylsulfanyl]-1,3-dimethyl-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— methyl (2S)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate —— C16H22N4O4S
    methyl (2S)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate
    —— 1,3-Dimethyl-7-(2-methylphenyl)-5-(2-piperidin-1-ium-1-ylethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C22H28N5O2S+
    1,3-Dimethyl-7-(2-methylphenyl)-5-(2-piperidin-1-ium-1-ylethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 2-(1-benzylimidazol-2-yl)sulfanyl-N-propylacetamide —— C15H19N3OS
    2-(1-benzylimidazol-2-yl)sulfanyl-N-propylacetamide
    —— ethyl (2R)-2-[1,3-dimethyl-7-(4-methylphenyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate —— C20H22N4O4S
    ethyl (2R)-2-[1,3-dimethyl-7-(4-methylphenyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate
    —— (2S)-2-(7-cyclopentyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoate —— C17H21N4O4S-
    (2S)-2-(7-cyclopentyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylbutanoate
    —— 1,3-Dimethyl-7-(3-methylphenyl)-5-propylsulfanylpyrimido[4,5-d]pyrimidine-2,4-dione —— C18H20N4O2S
    1,3-Dimethyl-7-(3-methylphenyl)-5-propylsulfanylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— ethyl (2S)-2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate —— C17H24N4O4S
    ethyl (2S)-2-(7-butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylpropanoate
    —— (2R)-2-[1,3-dimethyl-7-(2-methylphenyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoic acid —— C19H20N4O4S
    (2R)-2-[1,3-dimethyl-7-(2-methylphenyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoic acid
    —— 7-Butyl-1,3-dimethyl-5-propylsulfanylpyrimido[4,5-d]pyrimidine-2,4-dione —— C15H22N4O2S
    7-Butyl-1,3-dimethyl-5-propylsulfanylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 7-Butyl-1,3-dimethyl-5-(2-piperidin-1-ium-1-ylethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C19H30N5O2S+
    7-Butyl-1,3-dimethyl-5-(2-piperidin-1-ium-1-ylethylsulfanyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 7-(Methoxymethyl)-1,3-dimethyl-5-[(4-methylphenyl)methylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione —— C18H20N4O3S
    7-(Methoxymethyl)-1,3-dimethyl-5-[(4-methylphenyl)methylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 2-(7-Butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylacetic acid —— C14H18N4O4S
    2-(7-Butyl-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl)sulfanylacetic acid
    —— ethyl (2R)-2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate —— C15H20N4O5S
    ethyl (2R)-2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate
    —— 1,3-Dimethyl-7-(2-methylphenyl)-5-[(4-methylphenyl)methylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione —— C23H22N4O2S
    1,3-Dimethyl-7-(2-methylphenyl)-5-[(4-methylphenyl)methylsulfanyl]pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 5-Butylsulfanyl-1,3-dimethyl-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione —— C16H24N4O2S
    5-Butylsulfanyl-1,3-dimethyl-7-(2-methylpropyl)pyrimido[4,5-d]pyrimidine-2,4-dione
    —— 1-(5-Methylthiophen-2-yl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C15H12N2OS4
    1-(5-Methylthiophen-2-yl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— Ethyl 2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanyl-2-methylpropanoate —— C16H22N4O5S
    Ethyl 2-[7-(methoxymethyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanyl-2-methylpropanoate
    —— 7-Cyclohexyl-5-(2-methoxyethylsulfanyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C17H24N4O3S
    7-Cyclohexyl-5-(2-methoxyethylsulfanyl)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— ethyl (2S)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate —— C17H24N4O4S
    ethyl (2S)-2-[1,3-dimethyl-7-(2-methylpropyl)-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylpropanoate
    —— 7-Butyl-5-[2-(diethylamino)ethylsulfanyl]-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione —— C18H29N5O2S
    7-Butyl-5-[2-(diethylamino)ethylsulfanyl]-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 7-cyclopentyl-5-((3-fluorobenzyl)thio)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione —— C20H21FN4O2S
    7-cyclopentyl-5-((3-fluorobenzyl)thio)-1,3-dimethylpyrimido[4,5-d]pyrimidine-2,4(1H,3H)-dione
    —— N-tert-butyl-2-[1-[(4-chlorophenyl)methyl]imidazol-2-yl]sulfanylacetamide —— C16H20ClN3OS
    N-tert-butyl-2-[1-[(4-chlorophenyl)methyl]imidazol-2-yl]sulfanylacetamide
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-[2-(dimethylamino)ethyl]thiourea —— C14H19ClN6S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-[2-(dimethylamino)ethyl]thiourea
    —— 1-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-[[(2S)-oxolan-2-yl]methyl]thiourea —— C15H18ClN5OS2
    1-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-[[(2S)-oxolan-2-yl]methyl]thiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-prop-2-enylthiourea —— C13H14ClN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-prop-2-enylthiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-propan-2-ylthiourea —— C13H16ClN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-propan-2-ylthiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(2-methylprop-2-enyl)thiourea —— C14H16ClN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(2-methylprop-2-enyl)thiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-cyclohexylthiourea —— C16H20ClN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-cyclohexylthiourea
    —— 1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(4-fluorophenyl)thiourea —— C16H13ClFN5S2
    1-[3-[(4-Chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-3-(4-fluorophenyl)thiourea
    —— 2-[[5-(2-Methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone —— C17H17N3O2S2
    2-[[5-(2-Methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-1-(5-methylthiophen-2-yl)ethanone
    —— 3-(4-fluorophenyl)sulfanyl-N'-thiophen-2-ylsulfonylpropanehydrazide —— C13H13FN2O3S3
    3-(4-fluorophenyl)sulfanyl-N'-thiophen-2-ylsulfonylpropanehydrazide
    —— 1-(5-Ethylthiophen-2-yl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C15H14N2O3S2
    1-(5-Ethylthiophen-2-yl)-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— N'-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]-3-(4-fluorophenyl)sulfanylpropanehydrazide —— C14H16FN3O4S2
    N'-[(3,5-dimethyl-1,2-oxazol-4-yl)sulfonyl]-3-(4-fluorophenyl)sulfanylpropanehydrazide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-propan-2-yloxypropyl)acetamide —— C18H25N3O3S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(3-propan-2-yloxypropyl)acetamide
    —— N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H24N4O3S2
    N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(5-chlorothiophen-2-yl)methyl]-N-ethyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C12H15ClN4OS3
    N-[(5-chlorothiophen-2-yl)methyl]-N-ethyl-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 3-[5-[2-[(2-Fluorophenyl)methylamino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide —— C15H18FN5O2S
    3-[5-[2-[(2-Fluorophenyl)methylamino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide —— C13H21N5O2S
    3-[5-[2-[[(1S)-1-cyclopropylethyl]amino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[5-[2-[(4-Ethylphenyl)methyl-methylamino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide —— C18H25N5O2S
    3-[5-[2-[(4-Ethylphenyl)methyl-methylamino]-2-oxoethyl]sulfanyl-4-methyl-1,2,4-triazol-3-yl]propanamide
    —— 3-[4-methyl-5-[2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide —— C19H23N5O2S
    3-[4-methyl-5-[2-oxo-2-(4-phenyl-3,6-dihydro-2H-pyridin-1-yl)ethyl]sulfanyl-1,2,4-triazol-3-yl]propanamide
    —— N-benzyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H18N4O3S3
    N-benzyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2-methylphenyl)methyl]acetamide —— C13H16N4OS2
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2-methylphenyl)methyl]acetamide
    —— 3-(5-Butylsulfanyl-4-methyl-1,2,4-triazol-3-yl)propanamide —— C10H18N4OS
    3-(5-Butylsulfanyl-4-methyl-1,2,4-triazol-3-yl)propanamide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-5-methylhexan-2-yl]acetamide —— C19H27N3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-5-methylhexan-2-yl]acetamide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide —— C19H18FN3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide
    —— N-[(1R)-1-cyclopropylethyl]-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C17H21N3O2S
    N-[(1R)-1-cyclopropylethyl]-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[4-(2-methylbutan-2-yl)cyclohexyl]acetamide —— C16H28N4OS2
    2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[4-(2-methylbutan-2-yl)cyclohexyl]acetamide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-ethylhexyl]acetamide —— C20H29N3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-ethylhexyl]acetamide
    —— N-benzyl-N-(furan-2-ylmethyl)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C17H18N4O2S2
    N-benzyl-N-(furan-2-ylmethyl)-2-[[5-(methylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide