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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-methyl-3-phenylthio-6,10-dithiaspiro<4.5>dec-2-en-1-one 88791-32-6 C15H16OS3
    2-methyl-3-phenylthio-6,10-dithiaspiro<4.5>dec-2-en-1-one
    —— 1-amino-3-(2-chloro-phenylsulfanyl)-propan-2-ol 35550-45-9 C9H12ClNOS
    1-amino-3-(2-chloro-phenylsulfanyl)-propan-2-ol
    —— (R)-tert-butyldimethylsiloxy(2-pyridyl)methyl 4-methylpheny sulfide 161151-92-4 C19H27NOSSi
    (R)-tert-butyldimethylsiloxy(2-pyridyl)methyl 4-methylpheny sulfide
    —— 2-[1-Phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-furan 89863-49-0 C18H11F13O3S2
    2-[1-Phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-furan
    —— 2-(2-(2-chlorophenylthio)-3-(trimethylsilyl)propyl)cyclohexanone 1046204-46-9 C18H27ClOSSi
    2-(2-(2-chlorophenylthio)-3-(trimethylsilyl)propyl)cyclohexanone
    —— 13-phenyl-5<i>H</i>,11<i>H</i>-5,11-epiazano-[1,5]dithiocino[2,3-<i>b</i>;6,7-<i>b</i>']dipyridine 72397-25-2 C18H13N3S2
    13-phenyl-5<i>H</i>,11<i>H</i>-5,11-epiazano-[1,5]dithiocino[2,3-<i>b</i>;6,7-<i>b</i>']dipyridine
    —— 5-ethylthio-3-phenyl-1,2,3,4-oxatriazolium ion 60078-21-9 C9H10N3OS
    5-ethylthio-3-phenyl-1,2,3,4-oxatriazolium ion
    —— 3-[2-(tert-butyldiphenylsilanyloxy)ethyl]-6-methylsulfanylimidazo[2,1-f ][1,2,4]triazine 1097624-35-5 C24H28N4OSSi
    3-[2-(tert-butyldiphenylsilanyloxy)ethyl]-6-methylsulfanylimidazo[2,1-f ][1,2,4]triazine
    —— (2-chlorophenyl)(cyclohexyl)sulfane 1610363-64-8 C12H15ClS
    (2-chlorophenyl)(cyclohexyl)sulfane
    —— bis<2-<(6-aminohexyl)oxy>ethyl> disulfide 108296-15-7 C16H36N2O2S2
    bis<2-<(6-aminohexyl)oxy>ethyl> disulfide
    —— 2-[1-Phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-thiophene 89863-48-9 C18H11F13O2S3
    2-[1-Phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-thiophene
    —— 1-Methyl-4-[1-phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-benzene 89863-50-3 C21H15F13O2S2
    1-Methyl-4-[1-phenylsulfanyl-2-(tridecafluorohexane-1-sulfonyl)-ethyl]-benzene
    —— 1-phenyl-1-phenylthio-1-trimethylsilylethane 77815-44-2 C17H22SSi
    1-phenyl-1-phenylthio-1-trimethylsilylethane
    —— bis(2-methyl-6-methylthiopyrimidin-4-yl) disulfide 88317-69-5 C12H14N4S4
    bis(2-methyl-6-methylthiopyrimidin-4-yl) disulfide
    —— N-[2-chloro-4-(4-mesylaminophenylsulphanyl)phenyl]-2-hydroxy-2-methylpropanamide 252016-97-0 C17H19ClN2O4S2
    N-[2-chloro-4-(4-mesylaminophenylsulphanyl)phenyl]-2-hydroxy-2-methylpropanamide
    —— 1-Cyclohexyl-4-[1-[4-(4-methoxyphenyl)sulfanylphenyl]ethyl]piperazine 182135-90-6 C25H34N2OS
    1-Cyclohexyl-4-[1-[4-(4-methoxyphenyl)sulfanylphenyl]ethyl]piperazine
    —— N-Carbamothioyl-2-cyclopentylacetamide 572923-99-0 C8H14N2OS
    N-Carbamothioyl-2-cyclopentylacetamide
    —— (2S)-2-[(4R,6R)-6-[(2R,3R)-3-[2-[(Z,3S,5R,7S,10R)-10-[[tert-butyl(diphenyl)silyl]oxymethyl]-7-hydroxy-5-methoxy-3-(methoxymethoxy)-2,8-dimethyldodec-8-en-2-yl]-1,3-dithian-2-yl]-3-hydroxy-2-methoxypropyl]-2,2-dimethyl-1,3-dioxan-4-yl]-2-(2-trimethylsilylethoxymethoxy)acetic acid 1092070-91-1 C56H94O13S2Si2
    (2S)-2-[(4R,6R)-6-[(2R,3R)-3-[2-[(Z,3S,5R,7S,10R)-10-[[tert-butyl(diphenyl)silyl]oxymethyl]-7-hydroxy-5-methoxy-3-(methoxymethoxy)-2,8-dimethyldodec-8-en-2-yl]-1,3-dithian-2-yl]-3-hydroxy-2-methoxypropyl]-2,2-dimethyl-1,3-dioxan-4-yl]-2-(2-trimethylsilylethoxymethoxy)acetic acid
    —— (R)-2-phenyl-2-(phenylthio)acetic acid 13136-48-6 C14H12O2S
    (R)-2-phenyl-2-(phenylthio)acetic acid
    —— isopropylidene 1,4-dithiaspiro<4.5>decan-8-ylidene malonate 66607-07-6 C14H18O4S2
    isopropylidene 1,4-dithiaspiro<4.5>decan-8-ylidene malonate
    —— (S)-2-phenyl-2-(phenylthio)acetic acid 321038-73-7 C14H12O2S
    (S)-2-phenyl-2-(phenylthio)acetic acid
    —— 4-phenyl-4-(phenylthio)-1-butene 21213-27-4 C16H16S
    4-phenyl-4-(phenylthio)-1-butene
    —— 5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-{[2-(trifluoromethyl)phenyl]thio}aniline 1100794-92-0 C21H25ClF3N3S
    5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-{[2-(trifluoromethyl)phenyl]thio}aniline
    —— 1-isothiocyanatohex-2-yne 17620-80-3 C7H9NS
    1-isothiocyanatohex-2-yne
    —— 10,10-ethylenedithio-3,3,16-trimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,15-trione 66607-11-2 C19H26O5S2
    10,10-ethylenedithio-3,3,16-trimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,15-trione
    —— ethyl-5-(3-methyl-4-nitropyrazolyl)sulphide 76143-55-0 C6H9N3O2S
    ethyl-5-(3-methyl-4-nitropyrazolyl)sulphide
    —— methyl 9,9-ethylenedithio-5-methyl-4-oxadispiro(5.5)undecane-1-carboxylate 108643-44-3 C16H24O3S2
    methyl 9,9-ethylenedithio-5-methyl-4-oxadispiro(5.5)undecane-1-carboxylate
    —— 2-phenylsulfanylmethylene-malonic acid diethyl ester 72798-17-5 C14H16O4S
    2-phenylsulfanylmethylene-malonic acid diethyl ester
    —— Ethyl 3-[3-amino-5-[(4-chlorophenyl)methylsulfanyl]-4-cyanothiophen-2-yl]-3-oxopropanoate 1043384-27-5 C17H15ClN2O3S2
    Ethyl 3-[3-amino-5-[(4-chlorophenyl)methylsulfanyl]-4-cyanothiophen-2-yl]-3-oxopropanoate
    —— 10,10-ethylenedithio-3,3,13-trimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,14-trione 66607-10-1 C19H26O5S2
    10,10-ethylenedithio-3,3,13-trimethyl-2,4-dioxadispiro(5.0.5.4)hexadecane-1,5,14-trione
    —— N-[1-(Phenylsulfanyl)-3-(trimethylsilyl)prop-2-yn-1-yl]aniline 90261-26-0 C18H21NSSi
    N-[1-(Phenylsulfanyl)-3-(trimethylsilyl)prop-2-yn-1-yl]aniline
    —— 2-methyl-6-methylthiopyrimidine-4-thiol 88317-62-8 C6H8N2S2
    2-methyl-6-methylthiopyrimidine-4-thiol
    —— N,N-dimethyl-2<5'-(pyridin-4''-yl)-1',3',4'-oxadiazol-2'-ylthio>ethylamine 88317-55-9 C11H14N4OS
    N,N-dimethyl-2<5'-(pyridin-4''-yl)-1',3',4'-oxadiazol-2'-ylthio>ethylamine
    —— ethyl 4-methylthio-3-phenyl-2-thioxo-2,3-dihydro-1,3-oxazole-5-carboxylate 153648-49-8 C13H13NO3S2
    ethyl 4-methylthio-3-phenyl-2-thioxo-2,3-dihydro-1,3-oxazole-5-carboxylate
    —— Ethyl 3-[3-amino-4-cyano-5-[(4-methylphenyl)methylsulfanyl]thiophen-2-yl]-3-oxopropanoate 1043384-47-9 C18H18N2O3S2
    Ethyl 3-[3-amino-4-cyano-5-[(4-methylphenyl)methylsulfanyl]thiophen-2-yl]-3-oxopropanoate
    —— (1-Phenylsulfanyl-3-trimethylsilanyl-prop-2-ynyl)-o-tolyl-amine 90261-27-1 C19H23NSSi
    (1-Phenylsulfanyl-3-trimethylsilanyl-prop-2-ynyl)-o-tolyl-amine
    —— Ethyl 3-{3-amino-5-[(4-bromobenzyl)sulfanyl]-4-cyanothiophen-2-yl}-3-oxopropanoate 1043384-22-0 C17H15BrN2O3S2
    Ethyl 3-{3-amino-5-[(4-bromobenzyl)sulfanyl]-4-cyanothiophen-2-yl}-3-oxopropanoate
    —— 5-Phenyl-3-phenylsulfanylpentan-2-one 111036-67-0 C17H18OS
    5-Phenyl-3-phenylsulfanylpentan-2-one
    —— Ethyl 3-[3-amino-4-cyano-5-[(4-fluorophenyl)methylsulfanyl]thiophen-2-yl]-3-oxopropanoate 1043384-57-1 C17H15FN2O3S2
    Ethyl 3-[3-amino-4-cyano-5-[(4-fluorophenyl)methylsulfanyl]thiophen-2-yl]-3-oxopropanoate
    —— 4-methanesulfonyl-butyryl chloride 631910-85-5 C5H9ClO3S
    4-methanesulfonyl-butyryl chloride
    —— 1-phenyl-4,4-propylenedithio-3-pentanol 126884-76-2 C14H20OS2
    1-phenyl-4,4-propylenedithio-3-pentanol
    —— 4,4,7,7-Tetramethyl-2,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,8-dien 83569-35-1 C21H22N2S2
    4,4,7,7-Tetramethyl-2,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,8-dien
    —— 2,2,7,7-Tetramethyl-4,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-3,8-dien 84938-38-5 C21H22N2S2
    2,2,7,7-Tetramethyl-4,9-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-3,8-dien
    —— 2-cyano-3-(5-(4-chlorphenyl)thio-2-thienyl)acrylonitrile 76100-19-1 C14H7ClN2S2
    2-cyano-3-(5-(4-chlorphenyl)thio-2-thienyl)acrylonitrile
    —— 4,4,9,9-Tetramethyl-2,7-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,7-dien 52755-69-8 C21H22N2S2
    4,4,9,9-Tetramethyl-2,7-diphenyl-1,6-dithia-3,8-diazaspiro<4,4>nona-2,7-dien
    —— 1-Methyl-5-phenylthio-2-pyrrolecarboxaldehyde 94008-38-5 C12H11NOS
    1-Methyl-5-phenylthio-2-pyrrolecarboxaldehyde
    —— 2-[4-[S-(N-ethylcarbamoyl)thio]pheny]-5,5-dimethyl-1,3-dioxane 251989-46-5 C15H21NO3S
    2-[4-[S-(N-ethylcarbamoyl)thio]pheny]-5,5-dimethyl-1,3-dioxane
    —— (Z)-2-(2-(pyridin-4-yl)vinylthio)aniline 1088706-79-9 C13H12N2S
    (Z)-2-(2-(pyridin-4-yl)vinylthio)aniline
    —— 5,5-dimethyl-2-(4-methylsulfanylphenyl)-1,3-dioxane 251989-43-2 C13H18O2S
    5,5-dimethyl-2-(4-methylsulfanylphenyl)-1,3-dioxane
    —— 2-Cyano-3-(1-methyl-5-phenylthio-2-pyrrolyl)acrylonitrile 94033-70-2 C15H11N3S
    2-Cyano-3-(1-methyl-5-phenylthio-2-pyrrolyl)acrylonitrile