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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C21H23N3O2S
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C20H20FN3O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-pentan-2-yl]acetamide —— C15H22N4O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-pentan-2-yl]acetamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propylpropanamide —— C16H21N3O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propylpropanamide
    —— (2S)-N-cycloheptyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C20H27N3O2S
    (2S)-N-cycloheptyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide —— C20H20FN3O2S
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-fluorophenyl)methyl]propanamide
    —— (2R)-N-(cyclopentylcarbamoyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C19H24N4O3S
    (2R)-N-(cyclopentylcarbamoyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide —— C21H23N3O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(4-methylphenyl)methyl]propanamide
    —— (2R)-N-(2-cyanoethyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C17H20N4O2S
    (2R)-N-(2-cyanoethyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— methyl N-[(2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate —— C15H17N3O4S
    methyl N-[(2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoyl]carbamate
    —— (2S)-N-tert-butyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C17H23N3O2S
    (2S)-N-tert-butyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— ethyl (2Z)-2-[3-[2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate —— C19H21N3O4S2
    ethyl (2Z)-2-[3-[2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-4-oxo-1,3-thiazolidin-2-ylidene]acetate
    —— (2R)-N-cycloheptyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C20H27N3O2S
    (2R)-N-cycloheptyl-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)propanamide —— C16H21N3O3S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2-methoxyethyl)propanamide
    —— [(3S)-1,1-dioxothiolan-3-yl] 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C16H18N2O5S2
    [(3S)-1,1-dioxothiolan-3-yl] 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— (2S)-3-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-2-methylpropanenitrile —— C18H25N5S
    (2S)-3-[[4-benzyl-5-[(1S)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-2-methylpropanenitrile
    —— N-[(2S)-butan-2-yl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C14H20N4O2S
    N-[(2S)-butan-2-yl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-N-(1-cyanocyclohexyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C21H26N4O2S
    (2R)-N-(1-cyanocyclohexyl)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— 2-(3,4-Dimethylphenyl)-5-[(3-thiophen-3-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole —— C17H14N4O2S2
    2-(3,4-Dimethylphenyl)-5-[(3-thiophen-3-yl-1,2,4-oxadiazol-5-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— 5-(4-Fluorophenyl)sulfanyl-2-methylpyrazolo[1,5-a]quinazoline —— C17H12FN3S
    5-(4-Fluorophenyl)sulfanyl-2-methylpyrazolo[1,5-a]quinazoline
    —— 4-benzyl-3-(furan-2-yl)-5-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazole —— C21H19N3OS
    4-benzyl-3-(furan-2-yl)-5-[(1S)-1-phenylethyl]sulfanyl-1,2,4-triazole
    —— [(1S)-1-[4-benzyl-5-[(2S)-2-cyanopropyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C18H26N5S+
    [(1S)-1-[4-benzyl-5-[(2S)-2-cyanopropyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— [(1R)-1-[4-benzyl-5-[(2R)-2-cyanopropyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium —— C18H26N5S+
    [(1R)-1-[4-benzyl-5-[(2R)-2-cyanopropyl]sulfanyl-1,2,4-triazol-3-yl]propyl]-dimethylazanium
    —— 2-Methyl-5-phenylsulfanylpyrazolo[1,5-a]quinazoline —— C17H13N3S
    2-Methyl-5-phenylsulfanylpyrazolo[1,5-a]quinazoline
    —— N-[(2R)-butan-2-yl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C14H20N4O2S
    N-[(2R)-butan-2-yl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide —— C19H21N5O2S
    N-[2-[(5-benzyl-4-ethyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-methylpyrrole-2-carboxamide
    —— 1-(1-Adamantyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone —— C20H22N2OS3
    1-(1-Adamantyl)-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]ethanone
    —— (2S)-3-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-2-methylpropanenitrile —— C18H25N5S
    (2S)-3-[[4-benzyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]-2-methylpropanenitrile
    —— 1-methyl-N-[2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrole-2-carboxamide —— C15H15N5O3S2
    1-methyl-N-[2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetyl]pyrrole-2-carboxamide
    —— 2-(5-methyl-3-phenyl-1,2-oxazol-4-yl)-5-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-1,3,4-oxadiazole —— C20H20N6O2S
    2-(5-methyl-3-phenyl-1,2-oxazol-4-yl)-5-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— (7R)-6-(3,4-dimethylphenyl)-7-methyl-3-[(2R)-2-phenylpropyl]-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C22H24N4S
    (7R)-6-(3,4-dimethylphenyl)-7-methyl-3-[(2R)-2-phenylpropyl]-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (7S)-6-(3,4-dimethylphenyl)-7-methyl-3-[(2S)-2-phenylpropyl]-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C22H24N4S
    (7S)-6-(3,4-dimethylphenyl)-7-methyl-3-[(2S)-2-phenylpropyl]-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropan-1-one —— C18H23N3O2S
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-(4,5,6-trimethylpyrimidin-2-yl)sulfanylpropan-1-one
    —— methyl 2,4-dimethyl-5-[(2S)-2-phenylsulfanylpropanoyl]-1H-pyrrole-3-carboxylate —— C17H19NO3S
    methyl 2,4-dimethyl-5-[(2S)-2-phenylsulfanylpropanoyl]-1H-pyrrole-3-carboxylate
    —— N-(2-cyanoethyl)-2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide —— C21H27N5O2S
    N-(2-cyanoethyl)-2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-(furan-2-ylmethyl)acetamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide —— C19H20N4OS3
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methyl-N-[(4-methylsulfanylphenyl)methyl]acetamide
    —— methyl 2,4-dimethyl-5-[(2R)-2-phenylsulfanylpropanoyl]-1H-pyrrole-3-carboxylate —— C17H19NO3S
    methyl 2,4-dimethyl-5-[(2R)-2-phenylsulfanylpropanoyl]-1H-pyrrole-3-carboxylate
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2,4,4-trimethylpentan-2-yl)acetamide —— C18H26N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(2,4,4-trimethylpentan-2-yl)acetamide
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one —— C19H22N4O3S
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propan-1-one
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-5-methylhexan-2-yl]acetamide —— C17H24N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-5-methylhexan-2-yl]acetamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methyl-N-[(3-methylthiophen-2-yl)methyl]acetamide —— C17H18N4OS3
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-methyl-N-[(3-methylthiophen-2-yl)methyl]acetamide
    —— 5-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-N-phenyl-1,3,4-thiadiazol-2-amine —— C16H12N4O2S2
    5-[[5-(furan-2-yl)-1,2-oxazol-3-yl]methylsulfanyl]-N-phenyl-1,3,4-thiadiazol-2-amine
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-bis[(2R)-butan-2-yl]acetamide —— C18H26N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N,N-bis[(2R)-butan-2-yl]acetamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(2-methylphenyl)ethyl]acetamide —— C19H20N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[2-(2-methylphenyl)ethyl]acetamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-butan-2-yl]-N-[(2R)-butan-2-yl]acetamide —— C18H26N4OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(2S)-butan-2-yl]-N-[(2R)-butan-2-yl]acetamide
    —— 2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[[4-(dimethylamino)phenyl]methyl]-N-methylacetamide —— C20H23N5OS2
    2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[[4-(dimethylamino)phenyl]methyl]-N-methylacetamide
    —— 3-[2-[(5-Thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one —— C11H9N3O4S2
    3-[2-[(5-Thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetyl]-1,3-oxazolidin-2-one
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one —— C17H17N3O3S2
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propan-1-one
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one —— C20H21N3O3S
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propan-1-one
    —— ethyl 2-[2-[(2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl]sulfanyl-1,3-thiazol-4-yl]acetate —— C18H22N2O4S2
    ethyl 2-[2-[(2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-1-oxopropan-2-yl]sulfanyl-1,3-thiazol-4-yl]acetate