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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N'-acetyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetohydrazide —— C13H15N5O2S2
    N'-acetyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetohydrazide
    —— N-(3-methoxypropyl)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H20N4O2S2
    N-(3-methoxypropyl)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[4-(4-bromophenyl)sulfanylphenyl]-6-oxo-4,5-dihydro-1H-pyridazine-3-carboxamide —— C17H14BrN3O2S
    N-[4-(4-bromophenyl)sulfanylphenyl]-6-oxo-4,5-dihydro-1H-pyridazine-3-carboxamide
    —— N-(2-cyanoethyl)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H15N5OS2
    N-(2-cyanoethyl)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-(cycloheptylideneamino)-2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]acetamide —— C14H21N5O3S
    N-(cycloheptylideneamino)-2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]acetamide
    —— 2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-pyridin-3-ylmethylideneamino]acetamide —— C13H14N6O3S
    2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-pyridin-3-ylmethylideneamino]acetamide
    —— N-benzyl-N-ethyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H22N4OS2
    N-benzyl-N-ethyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H23N5OS2
    (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— N-[(4-fluorophenyl)methyl]-N-methyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H19FN4OS2
    N-[(4-fluorophenyl)methyl]-N-methyl-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-[(5S)-3,3,5-trimethylcyclohexylidene]amino]acetamide —— C16H25N5O3S
    2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-[(5S)-3,3,5-trimethylcyclohexylidene]amino]acetamide
    —— methyl (2R)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C13H15N3O2S2
    methyl (2R)-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— (2S)-N-[2-(4-fluorophenyl)ethyl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H21FN4OS2
    (2S)-N-[2-(4-fluorophenyl)ethyl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-[(5R)-3,3,5-trimethylcyclohexylidene]amino]acetamide —— C16H25N5O3S
    2-[(2,4-dimethyl-3,5-dioxo-1,2,4-triazin-6-yl)sulfanyl]-N-[(Z)-[(5R)-3,3,5-trimethylcyclohexylidene]amino]acetamide
    —— 2-(2,5-difluorophenyl)sulfanyl-N-[(2-fluorophenyl)methyl]acetamide —— C15H12F3NOS
    2-(2,5-difluorophenyl)sulfanyl-N-[(2-fluorophenyl)methyl]acetamide
    —— 2-pyrimidin-2-ylsulfanyl-N-(2-thiophen-2-ylethyl)acetamide —— C12H13N3OS2
    2-pyrimidin-2-ylsulfanyl-N-(2-thiophen-2-ylethyl)acetamide
    —— 2-pyrimidin-2-ylsulfanyl-N-[2-(thiophen-2-ylmethylsulfanyl)ethyl]acetamide —— C13H15N3OS3
    2-pyrimidin-2-ylsulfanyl-N-[2-(thiophen-2-ylmethylsulfanyl)ethyl]acetamide
    —— 2-(2,5-difluorophenyl)sulfanyl-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide —— C18H19F2NOS
    2-(2,5-difluorophenyl)sulfanyl-N-[(1S)-1-(3,4-dimethylphenyl)ethyl]acetamide
    —— 2-(2,5-difluorophenyl)sulfanyl-1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-1-yl]ethanone —— C16H20F2N2O3S2
    2-(2,5-difluorophenyl)sulfanyl-1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-1-yl]ethanone
    —— N-[(3S,4R)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,5-difluorophenyl)sulfanylacetamide —— C12H12ClF2NO3S2
    N-[(3S,4R)-4-chloro-1,1-dioxothiolan-3-yl]-2-(2,5-difluorophenyl)sulfanylacetamide
    —— 2-(2,5-difluorophenyl)sulfanyl-1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-4-ium-1-yl]ethanone —— C16H21F2N2O3S2+
    2-(2,5-difluorophenyl)sulfanyl-1-[4-[(3S)-1,1-dioxothiolan-3-yl]piperazin-4-ium-1-yl]ethanone
    —— 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide —— C18H20N4OS3
    2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide
    —— N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2,5-difluorophenyl)sulfanylacetamide —— C14H16F2N2OS
    N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-(2,5-difluorophenyl)sulfanylacetamide
    —— N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(2,5-difluorophenyl)sulfanylacetamide —— C14H16F2N2OS
    N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-(2,5-difluorophenyl)sulfanylacetamide
    —— (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C19H25N5OS2
    (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-N-[(2-fluorophenyl)methyl]-2-phenylsulfanylpropanamide —— C16H16FNOS
    (2R)-N-[(2-fluorophenyl)methyl]-2-phenylsulfanylpropanamide
    —— N-(3,4-dimethylphenyl)-5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C15H19N3O2S2
    N-(3,4-dimethylphenyl)-5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N'-acetyl-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetohydrazide —— C14H17N5O2S2
    N'-acetyl-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetohydrazide
    —— methyl (2R)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C14H17N3O2S2
    methyl (2R)-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C14H15F3N4OS2
    2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— N-(3,4-dimethylphenyl)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C17H15N5O2S2
    N-(3,4-dimethylphenyl)-5-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— (2R)-N-(furan-2-ylmethyl)-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C17H18N4O2S2
    (2R)-N-(furan-2-ylmethyl)-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide —— C17H21FN4OS2
    2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2-fluorophenyl)methyl]acetamide
    —— (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C20H21FN4OS2
    (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 5-[[(2R)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C11H21N4OS2+
    5-[[(2R)-4-(2-methylpropyl)morpholin-4-ium-2-yl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— N,N-diethyl-4-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C17H24N4OS2
    N,N-diethyl-4-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— 5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine —— C14H17N3O2S2
    5-[[(4S)-1,3-dioxan-4-yl]methylsulfanyl]-N-(2-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— methyl (2R)-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate —— C13H15N3O2S2
    methyl (2R)-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoate
    —— 2-(2-chlorophenyl)sulfanyl-N-[2-(thiophen-2-ylmethylsulfanyl)ethyl]acetamide —— C15H16ClNOS3
    2-(2-chlorophenyl)sulfanyl-N-[2-(thiophen-2-ylmethylsulfanyl)ethyl]acetamide
    —— 2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C17H18N4OS3
    2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C18H23N5OS2
    (2S)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C12H15N5OS2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— 2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide —— C13H17N5OS2
    2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[2-(4-methylphenyl)sulfanylethyl]acetamide
    —— 2-(4-chlorophenyl)sulfanylethyl N,N'-dimethylcarbamimidothioate —— C11H15ClN2S2
    2-(4-chlorophenyl)sulfanylethyl N,N'-dimethylcarbamimidothioate
    —— 2-[(3S)-1,1-dioxothiolan-3-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C14H18N2O3S2
    2-[(3S)-1,1-dioxothiolan-3-yl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— (E)-N-[(1S)-1-phenylethyl]-3-phenylsulfanylprop-2-enamide —— C17H17NOS
    (E)-N-[(1S)-1-phenylethyl]-3-phenylsulfanylprop-2-enamide
    —— 1-O-ethyl 4-O-[2-oxo-2-(2-phenylsulfanylethylamino)ethyl] (E)-but-2-enedioate —— C16H19NO5S
    1-O-ethyl 4-O-[2-oxo-2-(2-phenylsulfanylethylamino)ethyl] (E)-but-2-enedioate
    —— (2S)-2-(4-methyl-1,3-thiazol-2-yl)-3-oxo-4-phenylsulfanylbutanenitrile —— C14H12N2OS2
    (2S)-2-(4-methyl-1,3-thiazol-2-yl)-3-oxo-4-phenylsulfanylbutanenitrile
    —— N-[2-(4-chlorophenyl)sulfanylphenyl]-2-[4-(dimethylamino)pyridin-1-ium-1-yl]acetamide —— C21H21ClN3OS+
    N-[2-(4-chlorophenyl)sulfanylphenyl]-2-[4-(dimethylamino)pyridin-1-ium-1-yl]acetamide
    —— 2-[(5E)-3-(2-ethylphenyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]propanedinitrile —— C22H17N3OS2
    2-[(5E)-3-(2-ethylphenyl)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]propanedinitrile
    —— 2-[(5Z)-3-[(4-fluorophenyl)methyl]-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]propanedinitrile —— C21H14FN3OS2
    2-[(5Z)-3-[(4-fluorophenyl)methyl]-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1,3-thiazolidin-2-ylidene]propanedinitrile