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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (3R)-3-[6-[(4-bromophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-(3,4-difluorophenyl)propanoate —— C22H17BrF2O5S
    methyl (3R)-3-[6-[(4-bromophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]-3-(3,4-difluorophenyl)propanoate
    —— methyl (3R)-3-(4-fluorophenyl)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate —— C22H18F2O5S
    methyl (3R)-3-(4-fluorophenyl)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate
    —— methyl (3S)-3-(4-chlorophenyl)-3-[6-[(2,4-difluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate —— C22H17ClF2O5S
    methyl (3S)-3-(4-chlorophenyl)-3-[6-[(2,4-difluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate
    —— methyl (3R)-3-(4-chlorophenyl)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate —— C22H18ClFO5S
    methyl (3R)-3-(4-chlorophenyl)-3-[6-[(4-fluorophenyl)sulfanylmethyl]-3-hydroxy-4-oxopyran-2-yl]propanoate
    —— 2-Oct-1-en-2-ylsulfanyloct-1-ene —— C16H30S
    2-Oct-1-en-2-ylsulfanyloct-1-ene
    —— [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] propanoate —— C13H16BrNO3S
    [2-[2-(4-Bromophenyl)sulfanylethylamino]-2-oxoethyl] propanoate
    —— 2-methyl-1-[2-methyl-4-(2-methylpropyl)phenyl]sulfanyl-4-(2-methylpropyl)benzene —— C22H30S
    2-methyl-1-[2-methyl-4-(2-methylpropyl)phenyl]sulfanyl-4-(2-methylpropyl)benzene
    —— 2,3-dimethyl-5-(methylthio)furan —— C7H10OS
    2,3-dimethyl-5-(methylthio)furan
    —— (2S)-2-chlorothiirane 1,1-dioxide —— C2H3ClO2S
    (2S)-2-chlorothiirane 1,1-dioxide
    —— (1S)-N-[(4-phenylsulfanyloxan-4-yl)methyl]cyclohex-3-ene-1-carboxamide —— C19H25NO2S
    (1S)-N-[(4-phenylsulfanyloxan-4-yl)methyl]cyclohex-3-ene-1-carboxamide
    —— (1R)-N-[(4-phenylsulfanyloxan-4-yl)methyl]cyclohex-3-ene-1-carboxamide —— C19H25NO2S
    (1R)-N-[(4-phenylsulfanyloxan-4-yl)methyl]cyclohex-3-ene-1-carboxamide
    —— (3R)-3-[(3S)-1-hydroxynonan-3-yl]sulfanylnonan-1-ol —— C18H38O2S
    (3R)-3-[(3S)-1-hydroxynonan-3-yl]sulfanylnonan-1-ol
    —— (3S)-3-[(3S)-1-hydroxynonan-3-yl]sulfanylnonan-1-ol —— C18H38O2S
    (3S)-3-[(3S)-1-hydroxynonan-3-yl]sulfanylnonan-1-ol
    —— O-[(2S)-butan-2-yl] N-(2-butylsulfanylcarbonylsulfanylethyl)carbamothioate —— C12H23NO2S3
    O-[(2S)-butan-2-yl] N-(2-butylsulfanylcarbonylsulfanylethyl)carbamothioate
    —— O-[(2R)-butan-2-yl] N-(2-butylsulfanylcarbonylsulfanylethyl)carbamothioate —— C12H23NO2S3
    O-[(2R)-butan-2-yl] N-(2-butylsulfanylcarbonylsulfanylethyl)carbamothioate
    —— (3R)-3-[(3R)-1-hydroxynonan-3-yl]sulfanylnonan-1-ol —— C18H38O2S
    (3R)-3-[(3R)-1-hydroxynonan-3-yl]sulfanylnonan-1-ol
    —— N-benzyl-2-(4-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide —— C19H18ClNO3S2
    N-benzyl-2-(4-chlorophenyl)sulfanyl-N-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide
    —— N-benzyl-2-(4-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide —— C19H18ClNO3S2
    N-benzyl-2-(4-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetamide
    —— [(2S)-undec-10-en-2-yl] carbamimidothioate —— C12H24N2S
    [(2S)-undec-10-en-2-yl] carbamimidothioate
    —— [(2R)-undec-10-en-2-yl] carbamimidothioate —— C12H24N2S
    [(2R)-undec-10-en-2-yl] carbamimidothioate
    —— 2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)propyl]acetamide —— C18H22N4O4S
    2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)propyl]acetamide
    —— 2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)propyl]acetamide —— C18H22N4O4S
    2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1R)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)propyl]acetamide
    —— 4-[(Z)-3-chloroprop-2-enyl]sulfanylphenol —— C9H9ClOS
    4-[(Z)-3-chloroprop-2-enyl]sulfanylphenol
    —— (6S,7S)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C15H13NO6S2
    (6S,7S)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— methyl (Z)-4-[[5-(dimethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-methylbut-2-enoate —— C10H15N3O2S2
    methyl (Z)-4-[[5-(dimethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-2-methylbut-2-enoate
    —— (6S,7R)-6-(carboxymethyl)-7-[4-(dimethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C17H18N2O5S2
    (6S,7R)-6-(carboxymethyl)-7-[4-(dimethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— (6R,7R)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C15H13NO6S2
    (6R,7R)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— dimethyl (5S)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C10H9NO5S2
    dimethyl (5S)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— dimethyl (5R)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C10H9NO5S2
    dimethyl (5R)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— (6S,7R)-6-(carboxymethyl)-7-[4-(diethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C19H22N2O5S2
    (6S,7R)-6-(carboxymethyl)-7-[4-(diethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— (6R,7S)-6-(carboxymethyl)-7-[4-(diethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C19H22N2O5S2
    (6R,7S)-6-(carboxymethyl)-7-[4-(diethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— (7S)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C13H9NO4S2
    (7S)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— (7R)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C13H9NO4S2
    (7R)-7-(2-hydroxyphenyl)-2-oxo-3,7-dihydrothiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— diethyl (5R)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C12H13NO5S2
    diethyl (5R)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— (6R,7S)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C15H13NO6S2
    (6R,7S)-6-(carboxymethyl)-7-(2-hydroxyphenyl)-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— diethyl (5S)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate —— C12H13NO5S2
    diethyl (5S)-2-oxo-3,5-dihydrothiopyrano[2,3-d][1,3]thiazole-5,6-dicarboxylate
    —— (6R,7S)-6-(carboxymethyl)-7-[4-(dimethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid —— C17H18N2O5S2
    (6R,7S)-6-(carboxymethyl)-7-[4-(dimethylamino)phenyl]-2-oxo-5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6-carboxylic acid
    —— N-[2-(N-ethyl-3-methylanilino)ethyl]-2-phenylsulfanylacetamide —— C19H24N2OS
    N-[2-(N-ethyl-3-methylanilino)ethyl]-2-phenylsulfanylacetamide
    —— (Z)-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-3-(1,3-thiazol-2-yl)prop-2-enamide —— C15H13N5OS2
    (Z)-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-3-(1,3-thiazol-2-yl)prop-2-enamide
    —— methyl (2Z)-2-[4-oxo-3-(3-pyridin-2-ylsulfanylpropyl)-1,3-thiazolidin-2-ylidene]acetate —— C14H16N2O3S2
    methyl (2Z)-2-[4-oxo-3-(3-pyridin-2-ylsulfanylpropyl)-1,3-thiazolidin-2-ylidene]acetate
    —— [(2R)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C16H15F2NO3S2
    [(2R)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2S)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C15H19F2NO3S
    [(2S)-1-(2-methylpropylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-(tert-butylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C15H19F2NO3S
    [(2R)-1-(tert-butylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2S)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C14H17F2NO4S
    [(2S)-1-(2-methoxyethylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2S)-1-[(2-chlorophenyl)methylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C18H16ClF2NO3S
    [(2S)-1-[(2-chlorophenyl)methylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C18H23F2NO3S
    [(2R)-1-(cycloheptylamino)-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2S)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C16H15F2NO3S2
    [(2S)-1-oxo-1-(thiophen-2-ylmethylamino)propan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— [(2R)-1-[(1-cyanocyclohexyl)-methylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate —— C19H22F2N2O3S
    [(2R)-1-[(1-cyanocyclohexyl)-methylamino]-1-oxopropan-2-yl] 2-(2,5-difluorophenyl)sulfanylacetate
    —— (2S)-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]-N-(propan-2-ylcarbamoyl)propanamide —— C17H30N6O3S
    (2S)-2-[[4-(2-methylpropyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]-N-(propan-2-ylcarbamoyl)propanamide
    —— (5S,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile —— C13H10N2OS2
    (5S,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-5-carbonitrile