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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-((1-Phenylthio)butyl)-cyclohexanone 133188-88-2 C16H22OS
    3-((1-Phenylthio)butyl)-cyclohexanone
    —— 1-tri-n-butylstannyl-1-phenylthio-butane —— C22H40SSn
    1-tri-n-butylstannyl-1-phenylthio-butane
    —— 2,5-bis[2-(methylthio)anilino]-1,4-benzoquinone 1263574-64-6 C20H18N2O2S2
    2,5-bis[2-(methylthio)anilino]-1,4-benzoquinone
    —— Methyl 3-(phenylthio)-4-(methoxycarbonyl)but-2-enoate 72476-00-7 C13H14O4S
    Methyl 3-(phenylthio)-4-(methoxycarbonyl)but-2-enoate
    —— N-[2-(4-chlorophenylthio)-1,1-dimethylethyl]propionamide 1216-10-0 C13H18ClNOS
    N-[2-(4-chlorophenylthio)-1,1-dimethylethyl]propionamide
    —— 2-Acetyl-2-ethyl-4H-3,1-benzoxathiin 124921-64-8 C12H14O2S
    2-Acetyl-2-ethyl-4H-3,1-benzoxathiin
    —— cycloheptanethiol 27482-33-3 C7H14S
    cycloheptanethiol
    —— 2-(methylthio)-4-chloro-6-morpholin-4-ylpyrimidine-5-carboxaldehyde 587878-87-3 C10H12ClN3O2S
    2-(methylthio)-4-chloro-6-morpholin-4-ylpyrimidine-5-carboxaldehyde
    —— 2,2'-trisulfanediyl-bis-pentan-3-one 72771-08-5 C10H18O2S3
    2,2'-trisulfanediyl-bis-pentan-3-one
    —— 2-(2,3,4,5,6-pentafluorophenylthio)-pyrrole 32884-71-2 C10H4F5NS
    2-(2,3,4,5,6-pentafluorophenylthio)-pyrrole
    —— (6-Methoxy-cyclohex-1-enylsulfanyl)-benzene 114501-82-5 C13H16OS
    (6-Methoxy-cyclohex-1-enylsulfanyl)-benzene
    —— 1-(2-Ethyl-1,3-dithiolan-2-yl)ethanone 136062-28-7 C7H12OS2
    1-(2-Ethyl-1,3-dithiolan-2-yl)ethanone
    —— 1,2-dimethyl-4-(4'-methylphenyl)thio-5-nitroimidazole 113139-57-4 C12H13N3O2S
    1,2-dimethyl-4-(4'-methylphenyl)thio-5-nitroimidazole
    —— 1,2-dimethyl-5-(4'-methylphenyl)thio-4-nitroimidazole 113121-67-8 C12H13N3O2S
    1,2-dimethyl-5-(4'-methylphenyl)thio-4-nitroimidazole
    —— 1-Chloro-2,3,5,6-tetrafluoro-4-[(4-methylphenyl)sulfanyl]benzene 106241-31-0 C13H7ClF4S
    1-Chloro-2,3,5,6-tetrafluoro-4-[(4-methylphenyl)sulfanyl]benzene
    —— 2.3-Dihydro-5-methyl-6-athyl-1.4-dithiin 31962-33-1 C7H12S2
    2.3-Dihydro-5-methyl-6-athyl-1.4-dithiin
    —— 2-(ethylthio)-2-methoxy-3-pentanone 303186-57-4 C8H16O2S
    2-(ethylthio)-2-methoxy-3-pentanone
    —— 4-[(Trimethylsilyl)methylthio]-o-phenylenediamine 69958-11-8 C10H18N2SSi
    4-[(Trimethylsilyl)methylthio]-o-phenylenediamine
    —— 2-methylphenyl cyclooctyl sulfide 1616956-04-7 C15H22S
    2-methylphenyl cyclooctyl sulfide
    —— 3-methyl-2-(3-methyl-2-butenyl)furan 84735-63-7 C11H16OS
    3-methyl-2-(3-methyl-2-butenyl)furan
    —— (4-chlorophenyl)(cyclooctyl)sulfane 1616956-02-5 C14H19ClS
    (4-chlorophenyl)(cyclooctyl)sulfane
    —— 2,6-Dimethyl-3-(phenylthio)-1,5-heptadiene 79499-67-5 C15H20S
    2,6-Dimethyl-3-(phenylthio)-1,5-heptadiene
    —— 4-Methyl-2-(methylthio)furan 84735-62-6 C6H8OS
    4-Methyl-2-(methylthio)furan
    —— 2-methyl-4-nitro-5-phenylthioimidazole 113121-63-4 C10H9N3O2S
    2-methyl-4-nitro-5-phenylthioimidazole
    —— 2-vinyl-1-cyclopropyl phenyl sulfide 119379-59-8 C11H12S
    2-vinyl-1-cyclopropyl phenyl sulfide
    —— ethyl 2-(5-(4-methylphenyl)-1,3,4-oxadiazol-2-ylthio)acetate 84160-40-7 C13H14N2O3S
    ethyl 2-(5-(4-methylphenyl)-1,3,4-oxadiazol-2-ylthio)acetate
    —— N-((1S)-1-phenylethyl)-2-(2-pyridinylsulfanyl)-(4S)-4-(1H-pyrrol-1-yl)heptanamide 415696-81-0 C24H29N3OS
    N-((1S)-1-phenylethyl)-2-(2-pyridinylsulfanyl)-(4S)-4-(1H-pyrrol-1-yl)heptanamide
    —— 5-[(2-Methoxyethyl)sulfanyl]-1,3,4-thiadiazole-2(3H)-thione 89723-75-1 C5H8N2OS3
    5-[(2-Methoxyethyl)sulfanyl]-1,3,4-thiadiazole-2(3H)-thione
    —— cyclooctyl(phenyl)sulfane 13910-20-8 C14H20S
    cyclooctyl(phenyl)sulfane
    —— methyl 3-<2-(2-formylyhiophene-3-yl)>-3-thiapropionate 1723-29-1 C8H8O3S2
    methyl 3-<2-(2-formylyhiophene-3-yl)>-3-thiapropionate
    —— 2-methyl-5-(4'-methylphenyl)thio-4-nitroimidazole 113121-66-7 C11H11N3O2S
    2-methyl-5-(4'-methylphenyl)thio-4-nitroimidazole
    —— 3-(4-chloro-8,8-dimethyl-2-methylsulfanyl-5-oxo-7,8-dihydro-5H-9-oxa-1,3,6-triazabenzocyclohepten-6-yl)propionic acid tert-butyl ester 1448987-93-6 C17H24ClN3O4S
    3-(4-chloro-8,8-dimethyl-2-methylsulfanyl-5-oxo-7,8-dihydro-5H-9-oxa-1,3,6-triazabenzocyclohepten-6-yl)propionic acid tert-butyl ester
    —— 4,4-Dimethyl-5-(4-methylsulfanyl-phenyl)-2,4-dihydro-pyrazol-3-one 108818-83-3 C12H14N2OS
    4,4-Dimethyl-5-(4-methylsulfanyl-phenyl)-2,4-dihydro-pyrazol-3-one
    —— 2-(methylthio)-5-(trifluoromethyl)pyridine 650592-47-5 C7H6F3NS
    2-(methylthio)-5-(trifluoromethyl)pyridine
    —— hexyl imidothiocarbamate 44958-26-1 C7H16N2S
    hexyl imidothiocarbamate
    —— 4-bromomethyl-5-(3,5-dichlorophenylthio)-1-isopropyl-1H-pyrazole-3-carboxylic acid ethyl ester 478620-67-6 C16H17BrCl2N2O2S
    4-bromomethyl-5-(3,5-dichlorophenylthio)-1-isopropyl-1H-pyrazole-3-carboxylic acid ethyl ester
    —— 3-(4-Chlorophenyl)-3-phenylsulfanylpropanoyl chloride 1026511-99-8 C15H12Cl2OS
    3-(4-Chlorophenyl)-3-phenylsulfanylpropanoyl chloride
    —— 2-hexylsulfanyl-5-amino-1,3,4-thiadiazole 61516-63-0 C8H15N3S2
    2-hexylsulfanyl-5-amino-1,3,4-thiadiazole
    —— 5-(3,5-dichlorophenylthio)-4-hydroxymethyl-1-isopropyl-1H-pyrazole-3-carboxylic acid ethyl ester 478620-66-5 C16H18Cl2N2O3S
    5-(3,5-dichlorophenylthio)-4-hydroxymethyl-1-isopropyl-1H-pyrazole-3-carboxylic acid ethyl ester
    —— 5-{[2-(Methylsulfanyl)ethyl]sulfanyl}-1,3,4-thiadiazole-2(3H)-thione 105488-88-8 C5H8N2S4
    5-{[2-(Methylsulfanyl)ethyl]sulfanyl}-1,3,4-thiadiazole-2(3H)-thione
    —— 4-Amino-6-chloro-5-nitro-2-[(phenylmethyl)thio]pyrimidine 354582-78-8 C11H9ClN4O2S
    4-Amino-6-chloro-5-nitro-2-[(phenylmethyl)thio]pyrimidine
    —— 4,6-dichloro-5-nitro-2-((3,3,3-trifluoropropyl)thio)pyrimidine 187668-44-6 C7H4Cl2F3N3O2S
    4,6-dichloro-5-nitro-2-((3,3,3-trifluoropropyl)thio)pyrimidine
    —— (1S-cis)-2-[[4-[[6-Chloro-5-nitro-2-[(3,3,3-trifluoropropyl)thio]-4-pyrimidinyl]amino]-2-cyclopenten-1-yl]oxy]-acetic acid, ethyl ester 274693-41-3 C16H18ClF3N4O5S
    (1S-cis)-2-[[4-[[6-Chloro-5-nitro-2-[(3,3,3-trifluoropropyl)thio]-4-pyrimidinyl]amino]-2-cyclopenten-1-yl]oxy]-acetic acid, ethyl ester
    —— tert-butyl 2-(2-(benzylsulfanyl)-6-methylpyrimidin-4-yloxy)ethylmethylcarbamate 1035913-18-8 C20H27N3O3S
    tert-butyl 2-(2-(benzylsulfanyl)-6-methylpyrimidin-4-yloxy)ethylmethylcarbamate
    —— 2-[3]thienylmercapto-benzoic acid 22936-46-5 C11H8O2S2
    2-[3]thienylmercapto-benzoic acid
    —— 4-aminophenyl 3-thienyl sulfide 432050-13-0 C10H9NS2
    4-aminophenyl 3-thienyl sulfide
    —— 1-chloro-7,8-dimethoxy-3-methyl-10,11-dihydro-5-thia-2,4,11-triazadibenzo[a,d]cycloheptene 870258-03-0 C14H14ClN3O2S
    1-chloro-7,8-dimethoxy-3-methyl-10,11-dihydro-5-thia-2,4,11-triazadibenzo[a,d]cycloheptene
    —— 3-(hexylthio)thiophene 120186-61-0 C10H16S2
    3-(hexylthio)thiophene
    —— 2,2-Dimethyl-N-{4-[(6-methylpyridin-2-yl)sulfanyl]phenyl}propanamide 112954-83-3 C17H20N2OS
    2,2-Dimethyl-N-{4-[(6-methylpyridin-2-yl)sulfanyl]phenyl}propanamide
    —— 3-methylthio-6-[(1-methyl)-1H-4-pyrazolyl]-1,2,4-triazine 1380345-36-7 C8H9N5S
    3-methylthio-6-[(1-methyl)-1H-4-pyrazolyl]-1,2,4-triazine