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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-<(4-chlorophenyl)thio>ethanimidic acid, ethyl ester 104856-94-2 C10H12ClNOS
    2-<(4-chlorophenyl)thio>ethanimidic acid, ethyl ester
    —— 4-[3-(4-Chlorophenyl)sulfanylbenzo[b][1,8]naphthyridin-2-yl]morpholine 112181-59-6 C22H18ClN3OS
    4-[3-(4-Chlorophenyl)sulfanylbenzo[b][1,8]naphthyridin-2-yl]morpholine
    —— 2-(4-bromophenylthio)acetamidoxime 50837-18-8 C8H9BrN2OS
    2-(4-bromophenylthio)acetamidoxime
    —— 3-<<(4-chlorophenyl)thio>methyl>-5-<(phenylmethyl)thio>pyrimido<5,4-e>-1,2,4-triazin-7-amine 104856-95-3 C19H15ClN6S2
    3-<<(4-chlorophenyl)thio>methyl>-5-<(phenylmethyl)thio>pyrimido<5,4-e>-1,2,4-triazin-7-amine
    —— 3-(4-Chlorophenyl)sulfanyl-2-piperidin-1-ylbenzo[b][1,8]naphthyridine 112181-58-5 C23H20ClN3S
    3-(4-Chlorophenyl)sulfanyl-2-piperidin-1-ylbenzo[b][1,8]naphthyridine
    —— 3-<<(4-chlorophenyl)thio>methyl>pyrimido<5,4-e>-1,2,4-triazine-5,7-diamine 104856-96-4 C12H10ClN7S
    3-<<(4-chlorophenyl)thio>methyl>pyrimido<5,4-e>-1,2,4-triazine-5,7-diamine
    —— N-{2-[(2-Chloro-6-nitrophenyl)sulfanyl]-4-methoxyphenyl}formamide 488085-90-1 C14H11ClN2O4S
    N-{2-[(2-Chloro-6-nitrophenyl)sulfanyl]-4-methoxyphenyl}formamide
    —— 1-Chlor-2,3-bis(methylthio)benzol 65516-83-8 C8H9ClS2
    1-Chlor-2,3-bis(methylthio)benzol
    —— 2-(4-chlorophenyl)sulfanyl-N'-hydroxyethanimidamide 58818-93-2 C8H9ClN2OS
    2-(4-chlorophenyl)sulfanyl-N'-hydroxyethanimidamide
    —— 2-<i>p</i>-tolylsulfanyl-thioacetamide 59865-83-7 C9H11NS2
    2-<i>p</i>-tolylsulfanyl-thioacetamide
    —— 2,2'-thiobis(4,5-dimethylphenol) 170962-07-9 C16H18O2S
    2,2'-thiobis(4,5-dimethylphenol)
    —— 2-[(2-Chloro-6-nitrophenyl)thio]-1-methyl-1H-imidazole 133303-62-5 C10H8ClN3O2S
    2-[(2-Chloro-6-nitrophenyl)thio]-1-methyl-1H-imidazole
    —— 1-cyano-1-(p-tolylthio)cyclobutane 85901-31-1 C12H13NS
    1-cyano-1-(p-tolylthio)cyclobutane
    —— (4S,5S)-2-<(4-Methylphenyl)sulfanylmethyl>-5-phenyl-4-(triisopropylsiloxymethyl)-4,5-dihydro-1,3-oxazole 175477-30-2 C27H39NO2SSi
    (4S,5S)-2-<(4-Methylphenyl)sulfanylmethyl>-5-phenyl-4-(triisopropylsiloxymethyl)-4,5-dihydro-1,3-oxazole
    —— 2-(p-tolylthio)cyclopentanone 84613-02-5 C12H14OS
    2-(p-tolylthio)cyclopentanone
    —— (4S,5S)-4-Hydroxymethyl-2-<(4-methylphenyl)sulfanylmethyl>-5-phenyl-4,5-dihydro-1,3-oxazole 175477-29-9 C18H19NO2S
    (4S,5S)-4-Hydroxymethyl-2-<(4-methylphenyl)sulfanylmethyl>-5-phenyl-4,5-dihydro-1,3-oxazole
    —— 2-Methyl-1-(4-methylphenyl)sulfanylcyclobutane-1-carbonitrile 85891-69-6 C13H15NS
    2-Methyl-1-(4-methylphenyl)sulfanylcyclobutane-1-carbonitrile
    —— 3-(2-Amino-6-chlorophenyl)sulfanylthiophene-2-carboxylic acid 104636-64-8 C11H8ClNO2S2
    3-(2-Amino-6-chlorophenyl)sulfanylthiophene-2-carboxylic acid
    —— N'-hydroxy-2-(4-methylphenyl)sulfanylethanimidamide 74955-69-4 C9H12N2OS
    N'-hydroxy-2-(4-methylphenyl)sulfanylethanimidamide
    —— 3-chloro-2-(2,4-dichlorophenylthio)-nitrobenzene 210823-44-2 C12H6Cl3NO2S
    3-chloro-2-(2,4-dichlorophenylthio)-nitrobenzene
    —— 3-(2-Chloro-6-nitrophenyl)sulfanylthiophene-2-carboxylic acid 104636-60-4 C11H6ClNO4S2
    3-(2-Chloro-6-nitrophenyl)sulfanylthiophene-2-carboxylic acid
    —— 2-(2-chloro-6-nitrophenylthio)imidazole 683276-68-8 C9H6ClN3O2S
    2-(2-chloro-6-nitrophenylthio)imidazole
    —— (2S)-1-[2-[[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methyl]-1,3-dithian-2-yl]-3-[(4S,6R)-6-[(2S)-1-[tert-butyl(dimethyl)silyl]oxypropan-2-yl]-2,2-dimethyl-1,3-dioxan-4-yl]propan-2-ol 281670-36-8 C30H56O7S2Si
    (2S)-1-[2-[[(3aR,5S,6aR)-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-5-yl]methyl]-1,3-dithian-2-yl]-3-[(4S,6R)-6-[(2S)-1-[tert-butyl(dimethyl)silyl]oxypropan-2-yl]-2,2-dimethyl-1,3-dioxan-4-yl]propan-2-ol
    —— (2S)-1-[2-[(2S)-1-[tert-butyl(dimethyl)silyl]oxypropan-2-yl]-1,3-dithian-2-yl]-3-[(2S)-oxiran-2-yl]propan-2-ol 281670-29-9 C18H36O3S2Si
    (2S)-1-[2-[(2S)-1-[tert-butyl(dimethyl)silyl]oxypropan-2-yl]-1,3-dithian-2-yl]-3-[(2S)-oxiran-2-yl]propan-2-ol
    —— (2S,3R,5R,7S)-7-methoxy-2-methyl-8-[2-[(2S,4R)-2,4,5-trihydroxypentyl]-1,3-dithian-2-yl]octane-1,3,5-triol 281670-37-9 C19H38O7S2
    (2S,3R,5R,7S)-7-methoxy-2-methyl-8-[2-[(2S,4R)-2,4,5-trihydroxypentyl]-1,3-dithian-2-yl]octane-1,3,5-triol
    —— 4-(N,N'-bis(4-chlorophenyl)guanidino-2methyl-5-methylthio-2H-1,2,4-triazole-3(4H)-thione 116088-24-5 C17H16Cl2N6S2
    4-(N,N'-bis(4-chlorophenyl)guanidino-2methyl-5-methylthio-2H-1,2,4-triazole-3(4H)-thione
    —— 3-ethyl-5-methylthiopyrazolo<3,4-e><1,3>oxazin-7-one 116992-51-9 C8H9N3O2S
    3-ethyl-5-methylthiopyrazolo<3,4-e><1,3>oxazin-7-one
    —— 4-isopropylthioaniline 2976-70-7 C9H13NS
    4-isopropylthioaniline
    —— 4-isopentylsulfanyl-aniline 861343-75-1 C11H17NS
    4-isopentylsulfanyl-aniline
    —— 1-(Phenylsulfanyl)bicyclo[4.1.0]heptan-2-one 113975-64-7 C13H14OS
    1-(Phenylsulfanyl)bicyclo[4.1.0]heptan-2-one
    —— 2-[(2-Pentadecyl-1,3-dithian-2-yl)methyl]propane-1,3-diol 798550-48-8 C23H46O2S2
    2-[(2-Pentadecyl-1,3-dithian-2-yl)methyl]propane-1,3-diol
    —— 5-Desoxy-6-S-phenyl-6-thiofructose 137396-19-1 C12H16O4S
    5-Desoxy-6-S-phenyl-6-thiofructose
    —— 4-(3-Methyl-2,5-dioxo-2,5-dihydro-1H-pyrrol-1-ylamino)-6-(methylthio)-2-phenylpyrimidine-5-carbonitrile 1055922-67-2 C17H13N5O2S
    4-(3-Methyl-2,5-dioxo-2,5-dihydro-1H-pyrrol-1-ylamino)-6-(methylthio)-2-phenylpyrimidine-5-carbonitrile
    —— 4-(4-methyl-3,6-dioxo-3,6-dihydropyridazin-1(2H)-yl)-6-(methylthio)-2-phenylpyrimidine-5-carbonitrile 1055923-50-6 C17H13N5O2S
    4-(4-methyl-3,6-dioxo-3,6-dihydropyridazin-1(2H)-yl)-6-(methylthio)-2-phenylpyrimidine-5-carbonitrile
    —— 4-amino-3-methylthio-6-phenyl-4H-1,2,4-triazin-5-one 21087-63-8 C10H10N4OS
    4-amino-3-methylthio-6-phenyl-4H-1,2,4-triazin-5-one
    —— methyl 4-(methylthio)-2-oxo-6-(4-fluorophenyl)-2H-pyran-3-carboxylate 174467-64-2 C14H11FO4S
    methyl 4-(methylthio)-2-oxo-6-(4-fluorophenyl)-2H-pyran-3-carboxylate
    —— Methyl 6-(3-chloro-4-fluorophenyl)-4-methylsulfanyl-2-oxopyran-3-carboxylate 205124-82-9 C14H10ClFO4S
    Methyl 6-(3-chloro-4-fluorophenyl)-4-methylsulfanyl-2-oxopyran-3-carboxylate
    —— Methyl 6-(1-methylpyrrol-2-yl)-4-methylsulfanyl-2-oxopyran-3-carboxylate 115411-48-8 C13H13NO4S
    Methyl 6-(1-methylpyrrol-2-yl)-4-methylsulfanyl-2-oxopyran-3-carboxylate
    —— methyl 4-methylsulfanyl-2-oxo-6-pyrid-3-yl-2H-pyran-3-carboxylate 92118-46-2 C13H11NO4S
    methyl 4-methylsulfanyl-2-oxo-6-pyrid-3-yl-2H-pyran-3-carboxylate
    —— <(Z)-(5,6-Dihydro-6-hydroxy-6-methylthiazolo<3,2-b><1,2,4>-triazol-5-yliden)methyl>phosphonsaeure-diisopropylester 113250-19-4 C12H20N3O4PS
    <(Z)-(5,6-Dihydro-6-hydroxy-6-methylthiazolo<3,2-b><1,2,4>-triazol-5-yliden)methyl>phosphonsaeure-diisopropylester
    —— methyl 4-methylsulfanyl-2-oxo-6-pyrid-2-yl-2H-pyran-3-carboxylate 115411-47-7 C13H11NO4S
    methyl 4-methylsulfanyl-2-oxo-6-pyrid-2-yl-2H-pyran-3-carboxylate
    —— 2-methylsulfonyl-3-ethoxy acrylonitrile 104007-26-3 C6H9NO3S
    2-methylsulfonyl-3-ethoxy acrylonitrile
    —— 1-((2-fluorophenyl)thio)propan-2-one 2968-12-9 C9H9FOS
    1-((2-fluorophenyl)thio)propan-2-one
    —— 2,2,2-trifluoro-N-[5-[[2-(2-fluorophenyl)sulfanyl-4-(trifluoromethoxy)phenyl]-hydroxymethyl]-2,3-dihydro-1H-inden-1-yl]acetamide 701268-28-2 C25H18F7NO3S
    2,2,2-trifluoro-N-[5-[[2-(2-fluorophenyl)sulfanyl-4-(trifluoromethoxy)phenyl]-hydroxymethyl]-2,3-dihydro-1H-inden-1-yl]acetamide
    —— 4-bromo-2-fluoro-1-[(2-fluorophenyl)thio]benzene 933062-74-9 C12H7BrF2S
    4-bromo-2-fluoro-1-[(2-fluorophenyl)thio]benzene
    —— 3-((2-fluorophenyl)thio)-1H-indole 530116-20-2 C14H10FNS
    3-((2-fluorophenyl)thio)-1H-indole
    —— 2-(2-Fluoro-phenylsulfanyl)-4-trifluoromethoxy-benzaldehyde 447460-19-7 C14H8F4O2S
    2-(2-Fluoro-phenylsulfanyl)-4-trifluoromethoxy-benzaldehyde
    —— 3-(benzylthio)-2-methylfuran 61720-54-5 C12H12OS
    3-(benzylthio)-2-methylfuran
    —— 3-(2,4-Dinitrophenyl)sulfanyl-5-[2-[5-(2,4-dinitrophenyl)sulfanyl-4-(2-methylphenyl)-1,2,4-triazol-3-yl]ethyl]-4-(2-methylphenyl)-1,2,4-triazole 116987-02-1 C32H24N10O8S2
    3-(2,4-Dinitrophenyl)sulfanyl-5-[2-[5-(2,4-dinitrophenyl)sulfanyl-4-(2-methylphenyl)-1,2,4-triazol-3-yl]ethyl]-4-(2-methylphenyl)-1,2,4-triazole
    —— methyl N-[(1-methylthio-1-phenylthio)methylideneaminosulfonyl]carbamate 184427-52-9 C10H12N2O4S3
    methyl N-[(1-methylthio-1-phenylthio)methylideneaminosulfonyl]carbamate