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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-methyl 2-<1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-<(E)-2''''-oxotetrahydrofuran-3-ylidene>ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate 138175-72-1 C27H38O7S2Si
    (E)-methyl 2-<1'-<2''-(2''',2'''-dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-<(E)-2''''-oxotetrahydrofuran-3-ylidene>ethoxymethyl>-3-dimethyl(phenyl)silylprop-2-enoate
    —— (2S,4R)-1-[2-[2-(4-hydroxyphenyl)ethyl]-1,3-dithian-2-yl]heptadecane-2,4-diol 1056441-46-3 C29H50O3S2
    (2S,4R)-1-[2-[2-(4-hydroxyphenyl)ethyl]-1,3-dithian-2-yl]heptadecane-2,4-diol
    —— 2,2,6,6-Tetramethyl-4,4-bis(propylsulfanyl)piperidin-1-ol 112830-72-5 C15H31NOS2
    2,2,6,6-Tetramethyl-4,4-bis(propylsulfanyl)piperidin-1-ol
    —— 4-(Methylsulfonyl)-1-butanol 26981-51-1 C5H12O3S
    4-(Methylsulfonyl)-1-butanol
    —— 7-methylsulfonyl-1,1-dioxo-N-propan-2-yl-1lambda6,4,2-benzodithiazin-3-imine 1429321-55-0 C11H14N2O4S3
    7-methylsulfonyl-1,1-dioxo-N-propan-2-yl-1lambda6,4,2-benzodithiazin-3-imine
    —— N-isopropyl-N'-dodecylthiourea 62552-43-6 C16H34N2S
    N-isopropyl-N'-dodecylthiourea
    —— 4-[4-methyl-2-(1,4,7,9,9b-pentaaza-cyclopenta[a]naphthalen-6-ylamino)-phenylsulfanyl]-phenol 1076222-44-0 C21H16N6OS
    4-[4-methyl-2-(1,4,7,9,9b-pentaaza-cyclopenta[a]naphthalen-6-ylamino)-phenylsulfanyl]-phenol
    —— 4-methanesulfinyl-butan-1-ol 60270-06-6 C5H12O2S
    4-methanesulfinyl-butan-1-ol
    —— N<sup>1</sup>,N<sup>1</sup>,N<sup>2</sup>-Triisopropyl-thioharnstoff 24053-64-3 C10H22N2S
    N<sup>1</sup>,N<sup>1</sup>,N<sup>2</sup>-Triisopropyl-thioharnstoff
    —— 1-imido-2,μ-dithio-dicarbonic acid 1-amide 2-isopropylamide 60791-37-9 C5H11N3S2
    1-imido-2,μ-dithio-dicarbonic acid 1-amide 2-isopropylamide
    —— 3-Isopropylamino-7-nitro-1,4,2-benzothiadiazine 1,1-dioxide 638210-30-7 C10H11N3O4S2
    3-Isopropylamino-7-nitro-1,4,2-benzothiadiazine 1,1-dioxide
    —— t-Butyl-glyoxylsaeure-thionisopropylamid 5970-05-8 C9H17NOS
    t-Butyl-glyoxylsaeure-thionisopropylamid
    —— (α-bromoisopropyl)-isothiocyanate 71055-94-2 C4H6BrNS
    (α-bromoisopropyl)-isothiocyanate
    —— rac-O-cyclohept-2-enyl N-isopropylmonothiocarbamate 491880-00-3 C11H19NOS
    rac-O-cyclohept-2-enyl N-isopropylmonothiocarbamate
    —— 1,1-dioxo-N-propan-2-yl-7-(trifluoromethyl)-1lambda6,4,2-benzodithiazin-3-imine 1429321-50-5 C11H11F3N2O2S2
    1,1-dioxo-N-propan-2-yl-7-(trifluoromethyl)-1lambda6,4,2-benzodithiazin-3-imine
    —— N-isopropyl-2-oxohexanethioamide 95112-88-2 C9H17NOS
    N-isopropyl-2-oxohexanethioamide
    —— (R)-S-cyclohex-2-enyl N-isopropylmonothiocarbamate 255851-58-2 C10H17NOS
    (R)-S-cyclohex-2-enyl N-isopropylmonothiocarbamate
    —— 4-(4-Methyl-benzylsulfanyl)-phenol 102273-81-4 C14H14OS
    4-(4-Methyl-benzylsulfanyl)-phenol
    —— (<i>Z</i>)-2-methylsulfanyl-hex-2-en-4-yne 60813-85-6 C7H10S
    (<i>Z</i>)-2-methylsulfanyl-hex-2-en-4-yne
    —— 7-oxido-1,1-dioxo-N-propan-2-ylpyrido[4,3-e][1,4,2]dithiazin-7-ium-3-imine 1429321-61-8 C9H11N3O3S2
    7-oxido-1,1-dioxo-N-propan-2-ylpyrido[4,3-e][1,4,2]dithiazin-7-ium-3-imine
    —— (-)-(S)-O-cyclohex-2-enyl N-isopropylmonothiocarbamate 255851-57-1 C10H17NOS
    (-)-(S)-O-cyclohex-2-enyl N-isopropylmonothiocarbamate
    —— 1,1-dioxo-N-propan-2-ylpyrido[4,3-e][1,4,2]dithiazin-3-imine 1429321-60-7 C9H11N3O2S2
    1,1-dioxo-N-propan-2-ylpyrido[4,3-e][1,4,2]dithiazin-3-imine
    —— (+/-)-isopropyl-thiocarbamic acid O-(cyclohex-2-enyl) ester 405238-15-5 C10H17NOS
    (+/-)-isopropyl-thiocarbamic acid O-(cyclohex-2-enyl) ester
    —— 1,1-Dioxo-3-propan-2-ylimino-1lambda6,4,2-benzodithiazine-7-carbonitrile 1429321-58-3 C11H11N3O2S2
    1,1-Dioxo-3-propan-2-ylimino-1lambda6,4,2-benzodithiazine-7-carbonitrile
    —— isopropyl-thiocarbamic acid S-((S)-cyclohex-2-enyl) ester 255851-54-8 C10H17NOS
    isopropyl-thiocarbamic acid S-((S)-cyclohex-2-enyl) ester
    —— 3-isopropyl-1,1-dimethylthiourea 36600-03-0 C6H14N2S
    3-isopropyl-1,1-dimethylthiourea
    —— methyl N-isopropyl-2-methoxy-2,3-butadienimidothioate 918135-78-1 C9H15NOS
    methyl N-isopropyl-2-methoxy-2,3-butadienimidothioate
    —— iso-C3H7NHC(S)SSC(S)NHC3H7 2438-92-8 C8H16N2S4
    iso-C3H7NHC(S)SSC(S)NHC3H7
    —— rac-S-cyclohept-2-enyl N-isopropylmonothiocarbamate 491880-05-8 C11H19NOS
    rac-S-cyclohept-2-enyl N-isopropylmonothiocarbamate
    —— (+/-)-isopropyl-thiocarbamic acid O-((E)-1-ethyl-pent-2-enyl) ester 405238-11-1 C11H21NOS
    (+/-)-isopropyl-thiocarbamic acid O-((E)-1-ethyl-pent-2-enyl) ester
    —— Acetamide, 2-((4-cyano-5-(methylthio)-3-isothiazolyl)thio)- 24134-92-7 C7H7N3OS3
    Acetamide, 2-((4-cyano-5-(methylthio)-3-isothiazolyl)thio)-
    —— (4,4-dimethylcyclohex-1-enyl)phenylsulphide 99045-89-3 C14H18S
    (4,4-dimethylcyclohex-1-enyl)phenylsulphide
    —— 4,4-dimethyl-2-phenylsulfanylcyclohexanone 124992-53-6 C14H18OS
    4,4-dimethyl-2-phenylsulfanylcyclohexanone
    —— 1,4-Pentandithiol 54812-88-3 C5H12S2
    1,4-Pentandithiol
    —— ethyl 2-(4,6-diphenethoxypyrimidin-2-ylthio)acetate 1231733-88-2 C24H26N2O4S
    ethyl 2-(4,6-diphenethoxypyrimidin-2-ylthio)acetate
    —— 2-<3-hydroxy-3-(p-methylthiophenyl)propyl>-1,3-dioxane 138793-02-9 C14H20O3S
    2-<3-hydroxy-3-(p-methylthiophenyl)propyl>-1,3-dioxane
    —— 5-(1',3'-dioxan-2'-yl)-1-(phenylthio)pentan-3-one 108643-96-5 C15H20O3S
    5-(1',3'-dioxan-2'-yl)-1-(phenylthio)pentan-3-one
    —— (E)-5-(1',3'-dioxan-2'-yl)-1-(phenylthio)pent-1-en-3-one 108643-97-6 C15H18O3S
    (E)-5-(1',3'-dioxan-2'-yl)-1-(phenylthio)pent-1-en-3-one
    —— 5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-(pyridin-2-ylthio)aniline 1100794-91-9 C19H25ClN4S
    5-chloro-N-[3-(4-methylpiperazin-1-yl)propyl]-2-(pyridin-2-ylthio)aniline
    —— (Z)-5-(1',3'-dioxan-2'-yl)-1-(phenylthio)pent-1-en-3-one 108662-08-4 C15H18O3S
    (Z)-5-(1',3'-dioxan-2'-yl)-1-(phenylthio)pent-1-en-3-one
    —— 4-((5E,7Z)-undeca-5,7-dienylthio)butan-1-ol 1116649-43-4 C15H28OS
    4-((5E,7Z)-undeca-5,7-dienylthio)butan-1-ol
    —— 2-(R,S)-methyl-3-methylsulfonyl propionic acid 143224-95-7 C5H10O4S
    2-(R,S)-methyl-3-methylsulfonyl propionic acid
    —— tris(8-carboxy-2,2,6,6-tetramethylbenzo[1,2-d;4,5-d']bis[1,3]dithiol-4-yl)methanol 910912-09-3 C40H40O7S12
    tris(8-carboxy-2,2,6,6-tetramethylbenzo[1,2-d;4,5-d']bis[1,3]dithiol-4-yl)methanol
    —— 5H-[1,3]dithiolo[4,5-b][1,4]dithiepine-2,6(7H)-dione 129993-54-0 C6H4O2S4
    5H-[1,3]dithiolo[4,5-b][1,4]dithiepine-2,6(7H)-dione
    —— 2-((4-methylphenyl)thio)benzene-1,4-diol 18231-97-5 C13H12O2S
    2-((4-methylphenyl)thio)benzene-1,4-diol
    —— tetramethylene-1,4-bis-(2-mercaptoethylphosphine) 84274-61-3 C8H20P2S2
    tetramethylene-1,4-bis-(2-mercaptoethylphosphine)
    —— 2-decylsulfanyl-5-[(5-decylsulfanyl-1H-pyrrol-2-yl)-(2,3,4,5,6-pentafluorophenyl)methyl]-1H-pyrrole 943225-77-2 C35H49F5N2S2
    2-decylsulfanyl-5-[(5-decylsulfanyl-1H-pyrrol-2-yl)-(2,3,4,5,6-pentafluorophenyl)methyl]-1H-pyrrole
    —— (2E)-3-(3-Amino-4-cyan-5-methylthio-2-thienyl)acrylsaeure-methylester 123624-79-3 C10H10N2O2S2
    (2E)-3-(3-Amino-4-cyan-5-methylthio-2-thienyl)acrylsaeure-methylester
    —— 1,3-Dibromo-2-(methylthio)propane 86823-46-3 C4H8Br2S
    1,3-Dibromo-2-(methylthio)propane
    —— 2-deoxy-3,4;5,6-di-O-isopropylidene-2-C-nitromethyl-1-S-phenyl-1-thio-D-glucitol 116386-28-8 C19H27NO6S
    2-deoxy-3,4;5,6-di-O-isopropylidene-2-C-nitromethyl-1-S-phenyl-1-thio-D-glucitol