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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Phosphoroxy-isothiocyanat 24389-20-6 CNOPS
    Phosphoroxy-isothiocyanat
    —— 4-Pyridylthiolacetat 36875-66-8 C7H7NOS
    4-Pyridylthiolacetat
    —— Dithiocarbonic acid O-((2R,3R,8S)-2-ethyl-8-hexyl-oxocan-3-yl) ester S-methyl ester 799265-99-9 C17H32O2S2
    Dithiocarbonic acid O-((2R,3R,8S)-2-ethyl-8-hexyl-oxocan-3-yl) ester S-methyl ester
    —— 1-Ethyl-8-methyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine 97751-20-7 C12H18N4S
    1-Ethyl-8-methyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine
    —— 4-methylthiobenzylidenemethylamine N-oxide 107379-09-9 C9H11NOS
    4-methylthiobenzylidenemethylamine N-oxide
    —— 1-hydroxymethyl-3-methoxy-4-phenylthiobenzene 117411-53-7 C14H14O2S
    1-hydroxymethyl-3-methoxy-4-phenylthiobenzene
    —— 1-cyanomethyl-3-methoxy-4-phenylthiobenzene 117411-41-3 C15H13NOS
    1-cyanomethyl-3-methoxy-4-phenylthiobenzene
    —— 3-Methoxy-4-(phenylthio)benzaldehyde 122415-03-6 C14H12O2S
    3-Methoxy-4-(phenylthio)benzaldehyde
    —— 1-chloromethyl-3-methoxy-4-phenylthiobenzene 117411-40-2 C14H13ClOS
    1-chloromethyl-3-methoxy-4-phenylthiobenzene
    —— 1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-methylsulfanylpyrimidin-4-one 208513-26-2 C11H16N2O3S
    1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-methylsulfanylpyrimidin-4-one
    —— thiacyclooctan-3-one 1,1-dioxide 62827-50-3 C7H12O3S
    thiacyclooctan-3-one 1,1-dioxide
    —— 1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-5-methyl-2-methylsulfanylpyrimidin-4-one 208513-29-5 C12H18N2O3S
    1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-5-methyl-2-methylsulfanylpyrimidin-4-one
    —— 5-bromo-1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-methylsulfanylpyrimidin-4-one 208513-27-3 C11H15BrN2O3S
    5-bromo-1-[[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]methyl]-2-methylsulfanylpyrimidin-4-one
    —— 1,6,8-Trimethyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine 97751-27-4 C9H12N4S
    1,6,8-Trimethyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine
    —— 5-phenylsulfanyl-1,3-benzothiazol-2-amine 106695-49-2 C13H10N2S2
    5-phenylsulfanyl-1,3-benzothiazol-2-amine
    —— S-phenyl N-(5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-6-yl)carbamothioate 106695-58-3 C13H9N3O2S2
    S-phenyl N-(5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-6-yl)carbamothioate
    —— 2-Methyl-3-methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one 105246-07-9 C8H8N2OS
    2-Methyl-3-methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one
    —— 4-Allylsulfanyl-6-methoxymethyl-imidazo[1,5-d][1,2,4]triazine 97751-06-9 C10H12N4OS
    4-Allylsulfanyl-6-methoxymethyl-imidazo[1,5-d][1,2,4]triazine
    —— 3-Methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one 105246-02-4 C7H6N2OS
    3-Methylene-2,3-dihydro-thiazolo[3,2-c]pyrimidin-5-one
    —— 6-methoxymethyl-4-methylsulfanyl-imidazo[1,5-<i>d</i>][1,2,4]triazine 69195-48-8 C8H10N4OS
    6-methoxymethyl-4-methylsulfanyl-imidazo[1,5-<i>d</i>][1,2,4]triazine
    —— 1-Isopropyl-8-methyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine 97751-18-3 C13H20N4S
    1-Isopropyl-8-methyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine
    —— 6-chloro-3-(phenylsulfanylmethylidene)hexan-2-one 89118-10-5 C13H15ClOS
    6-chloro-3-(phenylsulfanylmethylidene)hexan-2-one
    —— 6-Chloro-3-phenylsulfanylmethyl-hexan-2-one 89118-11-6 C13H17ClOS
    6-Chloro-3-phenylsulfanylmethyl-hexan-2-one
    —— 6-Ethyl-8-methyl-4-methylsulfanyl-1-phenyl-imidazo[1,5-d][1,2,4]triazine 97751-24-1 C15H16N4S
    6-Ethyl-8-methyl-4-methylsulfanyl-1-phenyl-imidazo[1,5-d][1,2,4]triazine
    —— 6-Ethyl-8-methyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine 97751-23-0 C9H12N4S
    6-Ethyl-8-methyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine
    —— 2-Imino-4-oxothiolane-3-carbonitrile 90312-18-8 C5H4N2OS
    2-Imino-4-oxothiolane-3-carbonitrile
    —— 3-(2-Amino-5-chloro-phenylsulfanyl)-thiophene-2-carboxylic acid 104636-66-0 C11H8ClNO2S2
    3-(2-Amino-5-chloro-phenylsulfanyl)-thiophene-2-carboxylic acid
    —— 3-(Ethanesulfonyl)-2,2,3,3-tetrafluoropropanoyl fluoride 77705-90-9 C5H5F5O3S
    3-(Ethanesulfonyl)-2,2,3,3-tetrafluoropropanoyl fluoride
    —— [(5-Amino-2-chloro-4-fluorophenyl)sulfanyl]acetic acid 95635-41-9 C8H7ClFNO2S
    [(5-Amino-2-chloro-4-fluorophenyl)sulfanyl]acetic acid
    —— Methyl 3-(ethanesulfonyl)-2,2,3,3-tetrafluoropropanoate 77705-89-6 C6H8F4O4S
    Methyl 3-(ethanesulfonyl)-2,2,3,3-tetrafluoropropanoate
    —— 1,8-Dimethyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine 97751-17-2 C11H16N4S
    1,8-Dimethyl-4-methylsulfanyl-6-propyl-imidazo[1,5-d][1,2,4]triazine
    —— 6-Isopropyl-8-methyl-4-methylsulfanyl-1-phenyl-imidazo[1,5-d][1,2,4]triazine 97751-25-2 C16H18N4S
    6-Isopropyl-8-methyl-4-methylsulfanyl-1-phenyl-imidazo[1,5-d][1,2,4]triazine
    —— 2,2-bis(phenylthio)tetradecane 77815-61-3 C26H38S2
    2,2-bis(phenylthio)tetradecane
    —— 6-Isopropyl-8-methyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine 97751-22-9 C10H14N4S
    6-Isopropyl-8-methyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine
    —— 8-Methyl-4-methylsulfanyl-1,6-dipropyl-imidazo[1,5-d][1,2,4]triazine 97751-26-3 C13H20N4S
    8-Methyl-4-methylsulfanyl-1,6-dipropyl-imidazo[1,5-d][1,2,4]triazine
    —— 8-Isopropyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine 97751-15-0 C9H12N4S
    8-Isopropyl-4-methylsulfanyl-imidazo[1,5-d][1,2,4]triazine
    —— 5-decyl-2-dimethylamino-1,3-dithiolium-4-thiolate 677031-23-1 C15H27NS3
    5-decyl-2-dimethylamino-1,3-dithiolium-4-thiolate
    —— 3,6-Diphenyl-4-phenylsulfanyl-3-((E)-2-phenylsulfanyl-vinyl)-3,4-dihydro-[1,2]dithiine —— C30H24S4
    3,6-Diphenyl-4-phenylsulfanyl-3-((E)-2-phenylsulfanyl-vinyl)-3,4-dihydro-[1,2]dithiine
    —— 3,6-bis(methylthio)-5-carbomethoxy-1,2,4-triazine 104310-64-7 C7H9N3O2S2
    3,6-bis(methylthio)-5-carbomethoxy-1,2,4-triazine
    —— 2,2-bis(phenylthio)pentane 77815-59-9 C17H20S2
    2,2-bis(phenylthio)pentane
    —— 2,2-bis(phenylthio)pent-4-ene 77815-62-4 C17H18S2
    2,2-bis(phenylthio)pent-4-ene
    —— 6-hydroxy-2,3-dihydrobenzo[b]thiophene 343929-61-3 C8H8OS
    6-hydroxy-2,3-dihydrobenzo[b]thiophene
    —— 4-hydroxy-2,3-dihydrobenzo[b]thiophene 82194-96-5 C8H8OS
    4-hydroxy-2,3-dihydrobenzo[b]thiophene
    —— 2,3-dihydro-7-hydroxybenzo<b>thiophen 82194-97-6 C8H8OS
    2,3-dihydro-7-hydroxybenzo<b>thiophen
    —— 1-(5-amino-1,3,4-thiadiazole-2-ylthio)propan-2-ol 935289-76-2 C5H9N3OS2
    1-(5-amino-1,3,4-thiadiazole-2-ylthio)propan-2-ol
    —— 4-[4-(4-Ethoxyphenyl)-4-methylpentyl]-1-fluoro-2-(phenylsulfanyl)benzene 89764-77-2 C26H29FOS
    4-[4-(4-Ethoxyphenyl)-4-methylpentyl]-1-fluoro-2-(phenylsulfanyl)benzene
    —— 2,3-Dihydro-6-isopropyl-5H-thiazolo<2,3-c><1,2,4>-triazin-5-on 90516-89-5 C8H11N3OS
    2,3-Dihydro-6-isopropyl-5H-thiazolo<2,3-c><1,2,4>-triazin-5-on
    —— 4-(pyridin-4-ylthio)butanenitrile 88940-73-2 C9H10N2S
    4-(pyridin-4-ylthio)butanenitrile
    —— phenyl (2R)-3-(tert-butyldiphenylsilyl)oxy-2-methylpropyl sulfide 189223-93-6 C26H32OSSi
    phenyl (2R)-3-(tert-butyldiphenylsilyl)oxy-2-methylpropyl sulfide
    —— 4-thiapentane-1-thiol 26718-09-2 C4H10S2
    4-thiapentane-1-thiol