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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Δ<sup>1(7)</sup>-2,6-dithiabicyclo<5.4.0>undecene 114360-93-9 C9H14S2
    Δ<sup>1(7)</sup>-2,6-dithiabicyclo<5.4.0>undecene
    —— 4-(2-nitrophenylsulfanyl)-pyridine 91135-60-3 C11H8N2O2S
    4-(2-nitrophenylsulfanyl)-pyridine
    —— Bis<5-<2-(2'-nitrophenylthio)-1,3,4-thiadiazolyl>> 93269-46-6 C16H8N6O4S4
    Bis<5-<2-(2'-nitrophenylthio)-1,3,4-thiadiazolyl>>
    —— 3-(2-amino)phenylthiophenylamine 27332-24-7 C12H12N2S
    3-(2-amino)phenylthiophenylamine
    —— (3aR,7aS)-2-(4-(methylthio)phenyl)hexahydrobenzo-[d]-[1,3,2]dioxaborole 1310563-23-5 C13H17BO2S
    (3aR,7aS)-2-(4-(methylthio)phenyl)hexahydrobenzo-[d]-[1,3,2]dioxaborole
    —— N,N'-bis[3-(2-aminophenyl)sulfanylphenyl]pentanediamide 188058-58-4 C29H28N4O2S2
    N,N'-bis[3-(2-aminophenyl)sulfanylphenyl]pentanediamide
    —— N,N'-bis[2-(2-aminophenyl)sulfanylphenyl]pentanediamide 188058-57-3 C29H28N4O2S2
    N,N'-bis[2-(2-aminophenyl)sulfanylphenyl]pentanediamide
    —— 3-acetonylthio-5-methylthio-4-isothiazolecarbonitrile 24134-94-9 C8H8N2OS3
    3-acetonylthio-5-methylthio-4-isothiazolecarbonitrile
    —— N,N'-bis[4-(2-aminophenyl)sulfanylphenyl]pentanediamide 188058-59-5 C29H28N4O2S2
    N,N'-bis[4-(2-aminophenyl)sulfanylphenyl]pentanediamide
    —— N,N'-bis[3-(2-aminophenyl)sulfanylphenyl]propanediamide 188058-87-9 C27H24N4O2S2
    N,N'-bis[3-(2-aminophenyl)sulfanylphenyl]propanediamide
    —— 4-(6-methylsulfanylpyrimidin-4-yl)-1H-pyrazole-3,5-diamine 887365-61-9 C8H10N6S
    4-(6-methylsulfanylpyrimidin-4-yl)-1H-pyrazole-3,5-diamine
    —— 4-amino-2'-nitrodiphenyl sulfide 93352-49-9 C12H10N2O2S
    4-amino-2'-nitrodiphenyl sulfide
    —— 1-(1H-1,2,4-triazol-5-ylthio)-2-nitrobenzene 42986-83-4 C8H6N4O2S
    1-(1H-1,2,4-triazol-5-ylthio)-2-nitrobenzene
    —— 4-methyl-2-(2-nitrophenylthio)imidazole 88251-68-7 C10H9N3O2S
    4-methyl-2-(2-nitrophenylthio)imidazole
    —— PU-HZ151 1000999-96-1 C19H23IN6O2S
    PU-HZ151
    —— C12H9ClN2O2S 93075-13-9 C12H9ClN2O2S
    C12H9ClN2O2S
    —— 2,4'-diamino-3'-ethyldiphenylsulfide 76806-28-5 C14H16N2S
    2,4'-diamino-3'-ethyldiphenylsulfide
    —— 8-(5-methoxy-2-(thiophen-2-yl)phenylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine 1289544-78-0 C23H28N6OS2
    8-(5-methoxy-2-(thiophen-2-yl)phenylthio)-9-(2-(neopentylamino)ethyl)-9H-purin-6-amine
    —— 9-(3-(isopropylamino)propyl)-8-(6-(thiophen-2-yl)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-6-amine 1289543-78-7 C22H24N6O2S2
    9-(3-(isopropylamino)propyl)-8-(6-(thiophen-2-yl)benzo[d][1,3]dioxol-5-ylthio)-9H-purin-6-amine
    —— 2-tert-Butyl-4-methylsulfanyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile 96823-94-8 C10H13N3OS
    2-tert-Butyl-4-methylsulfanyl-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
    —— N,N-diethyl 2-thiophenylbenzamide 76279-45-3 C17H19NOS
    N,N-diethyl 2-thiophenylbenzamide
    —— 1,1,4,4-Tetramethyl-6-(2-nitrophenyl)sulfanyl-2,3-dihydronaphthalene 188845-35-4 C20H23NO2S
    1,1,4,4-Tetramethyl-6-(2-nitrophenyl)sulfanyl-2,3-dihydronaphthalene
    —— (Z)-2-(4-chlorobenzylidene)benzo[b]thiophen-3(2H)-one 101000-96-8 C15H9ClOS
    (Z)-2-(4-chlorobenzylidene)benzo[b]thiophen-3(2H)-one
    —— 2,2-Dimethyl-1,1-bis-(methylthio)propan 108593-16-4 C7H16S2
    2,2-Dimethyl-1,1-bis-(methylthio)propan
    —— 1-fluoro-2-(isopropylthio)benzene 138736-65-9 C9H11FS
    1-fluoro-2-(isopropylthio)benzene
    —— 2-nitro-1-(4-methylsulfanylphenylsulfanyl)benzene 54957-08-3 C13H11NO2S2
    2-nitro-1-(4-methylsulfanylphenylsulfanyl)benzene
    —— (E)-methyl 3-(phenylthio)-4-(3-(trimethylsilyloxy)-2-methyl-2-cyclohexenyl)but-2-enoate 105090-20-8 C21H30O3SSi
    (E)-methyl 3-(phenylthio)-4-(3-(trimethylsilyloxy)-2-methyl-2-cyclohexenyl)but-2-enoate
    —— 3-(pyridyl-2-thio)-1-cyclohexene 112157-69-4 C11H13NS
    3-(pyridyl-2-thio)-1-cyclohexene
    —— 1-(5,5-Dimethyl-3-phenylsulfanyl-4,5-dihydro-[1,2,4]triazol-1-yl)-ethanone 118807-17-3 C12H15N3OS
    1-(5,5-Dimethyl-3-phenylsulfanyl-4,5-dihydro-[1,2,4]triazol-1-yl)-ethanone
    —— 6-Methyl-1-methylsulfanyl-heptane 112173-29-2 C9H20S
    6-Methyl-1-methylsulfanyl-heptane
    —— (S)-(-)-3-tolylthio-5-trimethylsilyl-2-cyclohexenone 127911-56-2 C16H22OSSi
    (S)-(-)-3-tolylthio-5-trimethylsilyl-2-cyclohexenone
    —— 4-Isothiazolecarbonitrile, 3-((cyanomethyl)thio)-5-(methylthio)- 24306-38-5 C7H5N3S3
    4-Isothiazolecarbonitrile, 3-((cyanomethyl)thio)-5-(methylthio)-
    —— ethyl <(4-cyano-5-methylthioisothiazol-3-yl)thio>acetate 24134-89-2 C9H10N2O2S3
    ethyl <(4-cyano-5-methylthioisothiazol-3-yl)thio>acetate
    —— (4-amino-3-pyridyl) N,N-diisopropylcarbamodithioate 116990-43-3 C12H19N3S2
    (4-amino-3-pyridyl) N,N-diisopropylcarbamodithioate
    —— 2-benzyl-4-(methylsulfanyl)-6-oxo-1,6-dihydro-5-pyrimidinecarbonitrile 96823-96-0 C13H11N3OS
    2-benzyl-4-(methylsulfanyl)-6-oxo-1,6-dihydro-5-pyrimidinecarbonitrile
    —— (2-Methylsulfanyl-ethyl)-cyclohexane 112173-30-5 C9H18S
    (2-Methylsulfanyl-ethyl)-cyclohexane
    —— ethyl <(4-cyano-3-methylthio-5-isothiazolyl)thio>acetate 74598-21-3 C9H10N2O2S3
    ethyl <(4-cyano-3-methylthio-5-isothiazolyl)thio>acetate
    —— 1,4-diacetyl-5-phenyl-3-phenylthio-4,5-dihydro-1H-1,2,4-triazole 118807-34-4 C18H17N3O2S
    1,4-diacetyl-5-phenyl-3-phenylthio-4,5-dihydro-1H-1,2,4-triazole
    —— 5-bromo-4-(1-methylhydrazineyl)-2-(methylthio)pyrimidine 691864-63-8 C6H9BrN4S
    5-bromo-4-(1-methylhydrazineyl)-2-(methylthio)pyrimidine
    —— 1-acetyl-5-phenyl-3-phenylthio-4,5-dihydro-1H-1,2,4-triazole 118807-13-9 C16H15N3OS
    1-acetyl-5-phenyl-3-phenylthio-4,5-dihydro-1H-1,2,4-triazole
    —— 2-benzylsulfanyl-3-chloro-aniline 107254-82-0 C13H12ClNS
    2-benzylsulfanyl-3-chloro-aniline
    —— 4-methoxy-3'-methylsulfinyl-3,4'-diquinolinyl sulfide 182943-73-3 C20H16N2O2S2
    4-methoxy-3'-methylsulfinyl-3,4'-diquinolinyl sulfide
    —— (2-chloro-6-nitrophenyl)(p-tolyl)sulfane 860241-04-9 C13H10ClNO2S
    (2-chloro-6-nitrophenyl)(p-tolyl)sulfane
    —— (bromomethyl)(4-chlorophenyl)sulfane 83767-73-1 C7H6BrClS
    (bromomethyl)(4-chlorophenyl)sulfane
    —— 8-nitro-4-methoxy-3'-methylsulfinyl-3,4'-diquinolinyl sulfide 182943-84-6 C20H15N3O4S2
    8-nitro-4-methoxy-3'-methylsulfinyl-3,4'-diquinolinyl sulfide
    —— 6-methylthio-5-phenyl-2H-thiopyran-2-one 61149-37-9 C12H10OS2
    6-methylthio-5-phenyl-2H-thiopyran-2-one
    —— α-chloro-α-p-chlorophenylthioacetonitrile 110123-87-0 C8H5Cl2NS
    α-chloro-α-p-chlorophenylthioacetonitrile
    —— 2-(bis(methylthio)methylene)-4-chloro-1,3-benzodithiole 129104-75-2 C10H9ClS4
    2-(bis(methylthio)methylene)-4-chloro-1,3-benzodithiole
    —— 3-Phenylsulfanylthiophene-2-carboxylic acid 81028-81-1 C11H8O2S2
    3-Phenylsulfanylthiophene-2-carboxylic acid
    —— 2-imino-6-methylthio-5-phenyl-2H-thiopyran-3-carbonitrile 90059-00-0 C13H10N2S2
    2-imino-6-methylthio-5-phenyl-2H-thiopyran-3-carbonitrile