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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(p-tolylthio)succinic anhydride 91344-83-1 C11H10O3S
    3-(p-tolylthio)succinic anhydride
    —— 4,6-dichloro-2,8-bis(dimethylamino)-5-phenyl-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine 259654-07-4 C19H18Cl2N6S
    4,6-dichloro-2,8-bis(dimethylamino)-5-phenyl-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine
    —— 1-<Bis(phenylthio)methyl>-1-(trimethylsilyl)cyclopropane 91633-61-3 C19H24S2Si
    1-<Bis(phenylthio)methyl>-1-(trimethylsilyl)cyclopropane
    —— 4,6-dichloro-2,8-bis(dimethylamino)-5-(p-tolyl)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine 259654-11-0 C20H20Cl2N6S
    4,6-dichloro-2,8-bis(dimethylamino)-5-(p-tolyl)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine
    —— ω-(2,6-dimethylpyrimidinylthio)acetone 96304-19-7 C9H12N2OS
    ω-(2,6-dimethylpyrimidinylthio)acetone
    —— 4,6-dichloro-2,8-bis(dimethylamino)-5-(4-chlorophenyl)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine 259654-08-5 C19H17Cl3N6S
    4,6-dichloro-2,8-bis(dimethylamino)-5-(4-chlorophenyl)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine
    —— 4,6-dichloro-2,8-bis(dimethylamino)-5-(3,4-methylenedioxyphenyl)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine 259654-10-9 C20H18Cl2N6O2S
    4,6-dichloro-2,8-bis(dimethylamino)-5-(3,4-methylenedioxyphenyl)-5H-thiopyrano[2,3-d:6,5-d']dipyrimidine
    —— (Z)-3-(chloromethylene)-2H-thiopyrano[2,3-b]-pyridin-4(3H)-one 1251530-97-8 C9H6ClNOS
    (Z)-3-(chloromethylene)-2H-thiopyrano[2,3-b]-pyridin-4(3H)-one
    —— (E)-3-(chloromethylene)-2H-thiopyrano[2,3-b]-pyridin-4(3H)-one 1251531-06-2 C9H6ClNOS
    (E)-3-(chloromethylene)-2H-thiopyrano[2,3-b]-pyridin-4(3H)-one
    —— N,N'-bis<dimethyl(phenylthio)methyl>diazene 26307-20-0 C18H22N2S2
    N,N'-bis<dimethyl(phenylthio)methyl>diazene
    —— 3-(N,N-dimethylamino)methylene-2,3-dihydro-4-oxothiopyrano[2,3-b]pyridine 852202-84-7 C11H12N2OS
    3-(N,N-dimethylamino)methylene-2,3-dihydro-4-oxothiopyrano[2,3-b]pyridine
    —— 4-amino-2-(3-pyridylmethylthio)-6-hydroxypyrimidine 95016-50-5 C10H10N4OS
    4-amino-2-(3-pyridylmethylthio)-6-hydroxypyrimidine
    —— bis[4-(acryloyloxyethyl)thiophenyl]sulfide 133811-67-3 C22H22O4S3
    bis[4-(acryloyloxyethyl)thiophenyl]sulfide
    —— 3-[[4-Benzyl-5-(3-thienyl)-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine 1012073-84-5 C19H16N4S2
    3-[[4-Benzyl-5-(3-thienyl)-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine
    —— 2-methyltropothione 42604-47-7 C8H8S
    2-methyltropothione
    —— 3-[[4-Benzyl-5-(2-thienyl)-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine 1012073-57-2 C19H16N4S2
    3-[[4-Benzyl-5-(2-thienyl)-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine
    —— 21,21-Dioxo-15,27-dioxa-2,7,21lambda6,35-tetrathiaheptacyclo[34.2.2.23,6.217,20.222,25.09,14.028,33]hexatetraconta-1(38),3(46),4,6(45),9,11,13,17(44),18,20(43),22,24,28,30,32,36,39,41-octadecaene-8,34-dione 861224-35-3 C40H28O6S4
    21,21-Dioxo-15,27-dioxa-2,7,21lambda6,35-tetrathiaheptacyclo[34.2.2.23,6.217,20.222,25.09,14.028,33]hexatetraconta-1(38),3(46),4,6(45),9,11,13,17(44),18,20(43),22,24,28,30,32,36,39,41-octadecaene-8,34-dione
    —— bis[4-(4-methylbenzylthio)phenyl]sulfide 103677-20-9 C28H26S3
    bis[4-(4-methylbenzylthio)phenyl]sulfide
    —— bis(4-(benzylthio)phenyl)sulfide 103677-18-5 C26H22S3
    bis(4-(benzylthio)phenyl)sulfide
    —— 1-[(2,4,4-Trimethylpentan-2-YL)sulfanyl]octane 201731-72-8 C16H34S
    1-[(2,4,4-Trimethylpentan-2-YL)sulfanyl]octane
    —— 4,4'-bis(methacryloyloxyethylcarbamoylthio)diphenylsulfide 1048373-38-1 C26H28N2O6S3
    4,4'-bis(methacryloyloxyethylcarbamoylthio)diphenylsulfide
    —— Toluene-4-sulfonate3-(3,6-dihydroxy-tricyclo[6.2.2.0<sup>2,7</sup>]dodeca-2,4,6-trien-4-ylsulfanyl)-1,4,5-trimethyl-4H-[1,2,4]triazol-1-ium; 92627-68-4 C7H7O3S*C17H22N3O2S
    Toluene-4-sulfonate3-(3,6-dihydroxy-tricyclo[6.2.2.0<sup>2,7</sup>]dodeca-2,4,6-trien-4-ylsulfanyl)-1,4,5-trimethyl-4H-[1,2,4]triazol-1-ium;
    —— (R)-4,4-dimethyl-3-(p-tolylthio)cyclohexanone 1215843-35-8 C15H20OS
    (R)-4,4-dimethyl-3-(p-tolylthio)cyclohexanone
    —— (R)-3-(4-chlorophenylthio)-4,4-dimethylcyclohexanone 1215843-38-1 C14H17ClOS
    (R)-3-(4-chlorophenylthio)-4,4-dimethylcyclohexanone
    —— 4,4-dimethyl-3-(phenylthio)cyclohexan-1-one 174510-06-6 C14H18OS
    4,4-dimethyl-3-(phenylthio)cyclohexan-1-one
    —— (R)-4,4-dimethyl-3-(o-tolylthio)cyclohexanone 1215843-33-6 C15H20OS
    (R)-4,4-dimethyl-3-(o-tolylthio)cyclohexanone
    —— 8-(6-(2,3-dihydrofuran-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine 1289544-89-3 C22H26N6O3S
    8-(6-(2,3-dihydrofuran-3-yl)benzo[d][1,3]dioxol-5-ylthio)-9-(3-(isopropylamino)propyl)-9H-purin-6-amine
    —— 2-((3-methylbenzyl)thio)pyridine 646511-51-5 C13H13NS
    2-((3-methylbenzyl)thio)pyridine
    —— 2-(prop-2-enylsulfanyl)-1-methyl-1H-imidazole 63348-54-9 C7H10N2S
    2-(prop-2-enylsulfanyl)-1-methyl-1H-imidazole
    —— 2-methyl-4-({3-(pentafluoroethyl)-5-[(2,2,2-trifluoroethyl)thio]-1H-pyrazol-1-yl}methyl)aniline 1207089-83-5 C15H13F8N3S
    2-methyl-4-({3-(pentafluoroethyl)-5-[(2,2,2-trifluoroethyl)thio]-1H-pyrazol-1-yl}methyl)aniline
    —— 2-m-bromobenzylthio-1-m-bromobenzyl-5-piperidinomethyluracil 932379-58-3 C24H25Br2N3OS
    2-m-bromobenzylthio-1-m-bromobenzyl-5-piperidinomethyluracil
    —— (Dibrommethylen)sulfoxid 97314-84-6 CBr2OS
    (Dibrommethylen)sulfoxid
    —— 2-m-bromobenzylthio-5-piperidinomethyluracil 932379-64-1 C17H20BrN3OS
    2-m-bromobenzylthio-5-piperidinomethyluracil
    —— 2-Chloro-2-methyl-3-phenylthiopropionsaeure 61350-93-4 C10H11ClO2S
    2-Chloro-2-methyl-3-phenylthiopropionsaeure
    —— 5-(3-Methyl-benzylsulfanyl)-[1,3,4]thiadiazol-2-ylamine 299442-42-5 C10H11N3S2
    5-(3-Methyl-benzylsulfanyl)-[1,3,4]thiadiazol-2-ylamine
    —— 6-amino-2-ethoxycarbonylmethylthiopyrimidin-4(3H)-one 36162-16-0 C8H11N3O3S
    6-amino-2-ethoxycarbonylmethylthiopyrimidin-4(3H)-one
    —— 5-[2-(2-chlorophenylthio)phenyl]-1,3,4-oxadiazole-2(3H)-thione 1226870-85-4 C14H9ClN2OS2
    5-[2-(2-chlorophenylthio)phenyl]-1,3,4-oxadiazole-2(3H)-thione
    —— 4-Chlor-1-trifluormethylmercaptomethylmercapto-benzol 714-17-0 C8H6ClF3S2
    4-Chlor-1-trifluormethylmercaptomethylmercapto-benzol
    —— (2-butylsulfanylpyridin-3-yl)methanol 1609289-11-3 C10H15NOS
    (2-butylsulfanylpyridin-3-yl)methanol
    —— 3-chloromethyl-2-isopropylsulfanylpyridine 1214787-67-3 C9H12ClNS
    3-chloromethyl-2-isopropylsulfanylpyridine
    —— (2-isopropylsulfanylpyridin-3-yl)methanol 1030829-17-4 C9H13NOS
    (2-isopropylsulfanylpyridin-3-yl)methanol
    —— 3,5-dichloro-4-[(5-methylsulfonyl-3-nitro-2-thienyl)sulfanyl]pyridine 1247819-90-4 C10H6Cl2N2O4S3
    3,5-dichloro-4-[(5-methylsulfonyl-3-nitro-2-thienyl)sulfanyl]pyridine
    —— 2-(phenylthio)cyclopentanone 52190-40-6 C11H12OS
    2-(phenylthio)cyclopentanone
    —— 2-butylsulfanyl-3-chloromethylpyridine 1609289-12-4 C10H14ClNS
    2-butylsulfanyl-3-chloromethylpyridine
    —— (8R,9S,10S,10aR)-8,9,10-trihydroxy-8,9,10,10a-tetrahydro-5H,7H-dipyrido[2,1-b:3',2'-e][1,3]thiazin-5-one 1369914-03-3 C11H12N2O4S
    (8R,9S,10S,10aR)-8,9,10-trihydroxy-8,9,10,10a-tetrahydro-5H,7H-dipyrido[2,1-b:3',2'-e][1,3]thiazin-5-one
    —— N,N'-dicyclopentylthiourea 160712-65-2 C11H20N2S
    N,N'-dicyclopentylthiourea
    —— (8R,9S,10S,10aS)-8,9,10-trihydroxy-8,9,10,10a-tetrahydro-5H,7H-dipyrido[2,1-b:3',2'-e][1,3]thiazin-5-one 1369914-02-2 C11H12N2O4S
    (8R,9S,10S,10aS)-8,9,10-trihydroxy-8,9,10,10a-tetrahydro-5H,7H-dipyrido[2,1-b:3',2'-e][1,3]thiazin-5-one
    —— 2-(2-Nitro-phenylsulfanyl)-nicotinic acid 1016869-89-8 C12H8N2O4S
    2-(2-Nitro-phenylsulfanyl)-nicotinic acid
    —— 2-(3-cyanopropylthio)pyridine-3-carbonitrile 158581-24-9 C10H9N3S
    2-(3-cyanopropylthio)pyridine-3-carbonitrile
    —— 2-(3-bromomethylthio)-5-(pyrazin-2-yl)-1,3,4-thiadiazole 1404052-55-6 C13H9BrN4S2
    2-(3-bromomethylthio)-5-(pyrazin-2-yl)-1,3,4-thiadiazole