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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecane-1-thiol 36879-93-3 C12H9F17S
    5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-heptadecafluorododecane-1-thiol
    —— 2-(phenylthio)-1-(trimethylsilyl)butan-3-one 61829-54-7 C13H20OSSi
    2-(phenylthio)-1-(trimethylsilyl)butan-3-one
    —— 6-Methyl-2-(3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one 53633-35-5 C17H10O2S2
    6-Methyl-2-(3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one
    —— (1E,3Z)-4-phenylthio-1-trimethylsilyl-1,3-butadiene 120764-58-1 C13H18SSi
    (1E,3Z)-4-phenylthio-1-trimethylsilyl-1,3-butadiene
    —— 4,7-Dimethyl-2-(3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one 68516-80-3 C18H12O2S2
    4,7-Dimethyl-2-(3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one
    —— (1E,3E)-4-phenylthio-1-trimethylsilyl-1,3-butadiene 120764-59-2 C13H18SSi
    (1E,3E)-4-phenylthio-1-trimethylsilyl-1,3-butadiene
    —— 4-(4-Chloroanilino)-2-methylsulfanylpyrimidine-5-carbaldehyde 1082600-08-5 C12H10ClN3OS
    4-(4-Chloroanilino)-2-methylsulfanylpyrimidine-5-carbaldehyde
    —— 3-(4-bromophenylthio)butanoic acid 226259-83-2 C10H11BrO2S
    3-(4-bromophenylthio)butanoic acid
    —— 3-bromo-4-(methylsulfanyl)pyridine 82257-12-3 C6H6BrNS
    3-bromo-4-(methylsulfanyl)pyridine
    —— 2-Ethenyl-5-phenylsulfanylpentanoic acid 884598-69-0 C13H16O2S
    2-Ethenyl-5-phenylsulfanylpentanoic acid
    —— (3R)-3-(2-chlorothiazol-5-yl)-2,3,7,8-tetrahydro-8-methyl-7-oxo-6-phenyl-[1,3]thiazolo[3,2-a]pyrimidin-4-io-5-olate 2413390-32-4 C16H12ClN3O2S2
    (3R)-3-(2-chlorothiazol-5-yl)-2,3,7,8-tetrahydro-8-methyl-7-oxo-6-phenyl-[1,3]thiazolo[3,2-a]pyrimidin-4-io-5-olate
    —— 6-Ethyl-4-isobutylimino-5-hydroxy-2,2-dimethyl-3,4-dihydro-2H-thiopyrano<2,3-b>pyridin-5,7-diol 82843-15-0 C16H24N2O2S
    6-Ethyl-4-isobutylimino-5-hydroxy-2,2-dimethyl-3,4-dihydro-2H-thiopyrano<2,3-b>pyridin-5,7-diol
    —— 6-Ethyl-5,7-dihydroxy-2,2-dimethyl-2H-thiopyrano<2,3-b>pyridin-4(3H)-on 88518-16-5 C12H15NO3S
    6-Ethyl-5,7-dihydroxy-2,2-dimethyl-2H-thiopyrano<2,3-b>pyridin-4(3H)-on
    —— 6-ethyl-2-ethylsulfanyl-[1,3,4]thiadiazolo[3,2-<i>a</i>]pyrimidine-5,7-dione 69395-58-0 C9H11N3O2S2
    6-ethyl-2-ethylsulfanyl-[1,3,4]thiadiazolo[3,2-<i>a</i>]pyrimidine-5,7-dione
    —— glyoxalbis(2-mercaptoanil) 19668-99-6 C16H16N2S2
    glyoxalbis(2-mercaptoanil)
    —— (2S,5S)-2-(tert-butyl)-5-ethyl-5-methyl-4-[4-(methylthio) phenyl]-1,3-dioxolan-4-ol 224304-40-9 C17H26O3S
    (2S,5S)-2-(tert-butyl)-5-ethyl-5-methyl-4-[4-(methylthio) phenyl]-1,3-dioxolan-4-ol
    —— 4-(4-(methylthio)phenyl)but-3-yn-2-ol 387866-26-4 C11H12OS
    4-(4-(methylthio)phenyl)but-3-yn-2-ol
    —— (1R,2R)-N,N'-bis(2-(isopropylthio)benzylidene)-1,2-cyclohexanediamine 1383610-96-5 C26H34N2S2
    (1R,2R)-N,N'-bis(2-(isopropylthio)benzylidene)-1,2-cyclohexanediamine
    —— (1R,2R)-N,N'-bis(2-(cyclohexylthio)benzylidene)-1,2-cyclohexanediamine 1383611-02-6 C32H42N2S2
    (1R,2R)-N,N'-bis(2-(cyclohexylthio)benzylidene)-1,2-cyclohexanediamine
    —— (1R,2R)-N,N'-bis(2-(tert-butylthio)benzylidene)-1,2-cyclohexanediamine 1383611-07-1 C28H38N2S2
    (1R,2R)-N,N'-bis(2-(tert-butylthio)benzylidene)-1,2-cyclohexanediamine
    —— Adamantane-1-carbothioic acid hydrazide 109684-20-0 C11H18N2S
    Adamantane-1-carbothioic acid hydrazide
    —— (2,2-Bis-phenylsulfanyl-vinyl)-methyl-amine 1026582-21-7 C15H15NS2
    (2,2-Bis-phenylsulfanyl-vinyl)-methyl-amine
    —— 1,4,7-trithiacyclononane 1-oxide 188631-39-2 C6H12OS3
    1,4,7-trithiacyclononane 1-oxide
    —— N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]propanamide 332143-50-7 C24H22BrNOS2
    N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]propanamide
    —— ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate 332143-57-4 C24H22BrNO2S2
    ethyl N-(o-bromobenzyl)-N-[2,2-bis(phenylthio)ethenyl]carbamate
    —— 4-hydroxy-thiobutyramide 936850-78-1 C4H9NOS
    4-hydroxy-thiobutyramide
    —— 2-(2,4-dimethylphenylthio)cyclohexanone 89816-86-4 C14H18OS
    2-(2,4-dimethylphenylthio)cyclohexanone
    —— 2-Benzo[1,3]dithiol-2-ylidene-cyclohexanone 83785-23-3 C13H12OS2
    2-Benzo[1,3]dithiol-2-ylidene-cyclohexanone
    —— 2-(3,5-dimethylphenylthio)cyclohexanone 89816-87-5 C14H18OS
    2-(3,5-dimethylphenylthio)cyclohexanone
    —— 2-(diphenylphosphino)-N-(2-(methylthio)benzylidene)ethanamine 848491-61-2 C22H22NPS
    2-(diphenylphosphino)-N-(2-(methylthio)benzylidene)ethanamine
    —— (+)-3-(4-morpholinylmethyl)-5-methyl-6-phenylthio-2,3-dihydropyrrolo[1,2,3-de]-1,4-benzoxazine 131513-55-8 C22H24N2O2S
    (+)-3-(4-morpholinylmethyl)-5-methyl-6-phenylthio-2,3-dihydropyrrolo[1,2,3-de]-1,4-benzoxazine
    —— ethyl {4-[3-(3-phenylpropylamino)phenylsulphanyl]phenyl}acetate 735312-20-6 C25H27NO2S
    ethyl {4-[3-(3-phenylpropylamino)phenylsulphanyl]phenyl}acetate
    —— 1,2-Bis-<thienyl-(2)-mercapto>-aethan 6911-54-2 C10H10S4
    1,2-Bis-<thienyl-(2)-mercapto>-aethan
    —— 2-Dimethoxymethyl-5-(thiophen-2-ylsulfanyl)-thiophene 192990-66-2 C11H12O2S3
    2-Dimethoxymethyl-5-(thiophen-2-ylsulfanyl)-thiophene
    —— S-thiophen-2-yl ethanethioate 87947-35-1 C6H6OS2
    S-thiophen-2-yl ethanethioate
    —— 3-(thiophen-2-ylthio)-1H-pyrrolo[2,3-b]pyridine 918514-25-7 C11H8N2S2
    3-(thiophen-2-ylthio)-1H-pyrrolo[2,3-b]pyridine
    —— 3-(Bromomethyl)-5,7-dimethyl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyridin-4-ium-8-carbonitrile;bromide 112629-80-8 Br*C11H12BrN2S
    3-(Bromomethyl)-5,7-dimethyl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyridin-4-ium-8-carbonitrile;bromide
    —— 3-thio-n-butyl-5,6-diphenyl-1,2,4-triazine 108957-67-1 C19H19N3S
    3-thio-n-butyl-5,6-diphenyl-1,2,4-triazine
    —— 1-(5-Amino-3-methylsulfanyl-[1,2,4]triazol-1-yl)-2-methyl-propan-1-one 110984-23-1 C7H12N4OS
    1-(5-Amino-3-methylsulfanyl-[1,2,4]triazol-1-yl)-2-methyl-propan-1-one
    —— 1-(5-bromo-2-(phenylthio)phenyl)ethanol 112446-25-0 C14H13BrOS
    1-(5-bromo-2-(phenylthio)phenyl)ethanol
    —— N-benzyl-N'-[4-[5-[(4-chlorobenzyl)thio]-1,3,4-oxadiazol-2-yl]-2-pyridyl]urea 1005202-15-2 C22H18ClN5O2S
    N-benzyl-N'-[4-[5-[(4-chlorobenzyl)thio]-1,3,4-oxadiazol-2-yl]-2-pyridyl]urea
    —— 2-Benzo[1,3]dithiol-2-yl-cycloheptanone 112146-02-8 C14H16OS2
    2-Benzo[1,3]dithiol-2-yl-cycloheptanone
    —— 1-(5-Amino-3-methylsulfanyl-[1,2,4]triazol-1-yl)-propan-1-one 110984-22-0 C6H10N4OS
    1-(5-Amino-3-methylsulfanyl-[1,2,4]triazol-1-yl)-propan-1-one
    —— (E)-5-phenylsulfanylpent-3-en-2-one 1442469-88-6 C11H12OS
    (E)-5-phenylsulfanylpent-3-en-2-one
    —— 3-Benzyl-5-phenyl-5-phenylsulfanyl-1,3-oxazolidine-2,4-dione 86530-96-3 C22H17NO3S
    3-Benzyl-5-phenyl-5-phenylsulfanyl-1,3-oxazolidine-2,4-dione
    —— 1-(4-aminophenyl)-9-phenylthiononane 257289-19-3 C21H29NS
    1-(4-aminophenyl)-9-phenylthiononane
    —— 3-Methoxy-5H-dibenzo<b,g>thiocin-5,7(6H)-dion 108059-98-9 C16H12O3S
    3-Methoxy-5H-dibenzo<b,g>thiocin-5,7(6H)-dion
    —— 1-(5-Amino-3-methylsulfanyl-[1,2,4]triazol-1-yl)-ethanone 110984-21-9 C5H8N4OS
    1-(5-Amino-3-methylsulfanyl-[1,2,4]triazol-1-yl)-ethanone
    —— 1,8-Bis-ethylsulfanyl-octane 115412-49-2 C12H26S2
    1,8-Bis-ethylsulfanyl-octane
    —— (3-Ethylsulfanyl-5-oxo-4,5-dihydro-[1,2,4]triazin-6-yl)-acetic acid 112081-01-3 C7H9N3O3S
    (3-Ethylsulfanyl-5-oxo-4,5-dihydro-[1,2,4]triazin-6-yl)-acetic acid