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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3,5-bis-benzylsulfanyl-isothiazole-4-carbonitrile 4886-07-1 C18H14N2S3
    3,5-bis-benzylsulfanyl-isothiazole-4-carbonitrile
    —— (4-cyano-isothiazole-3,5-diylbissulfanyl)-bis-acetic acid 4886-09-3 C8H6N2O4S3
    (4-cyano-isothiazole-3,5-diylbissulfanyl)-bis-acetic acid
    —— S-propan-2-yl 2-diazo-4-methylsulfanylbutanethioate 1380511-66-9 C8H14N2OS2
    S-propan-2-yl 2-diazo-4-methylsulfanylbutanethioate
    —— (E)-Methyl 2-<1'-<2''-(1'''-Formylmethyl)-1'',3''-dithian-2''-yl>-4'-oxopent-2'-enyloxymethyl>propenoate 145746-18-5 C16H22O5S2
    (E)-Methyl 2-<1'-<2''-(1'''-Formylmethyl)-1'',3''-dithian-2''-yl>-4'-oxopent-2'-enyloxymethyl>propenoate
    —— (Z)-Methyl 2-<1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-(2''''-oxotetrahydrofuran-3''''-ylidene)ethoxymethyl>propenoate 145746-24-3 C19H28O7S2
    (Z)-Methyl 2-<1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-(2''''-oxotetrahydrofuran-3''''-ylidene)ethoxymethyl>propenoate
    —— Methyl 2-<<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>formylmethoxymethyl>propenoate 145746-23-2 C15H24O6S2
    Methyl 2-<<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>formylmethoxymethyl>propenoate
    —— Methyl 2-<1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-hydroxyethoxymethyl>propenoate 145746-22-1 C15H26O6S2
    Methyl 2-<1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-hydroxyethoxymethyl>propenoate
    —— (E)-Methyl 2-<1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-(2''''-oxotetrahydrofuran-3''''-ylidene)ethoxymethyl>propenoate 145746-25-4 C19H28O7S2
    (E)-Methyl 2-<1'-<2''-(2''',2'''-Dimethoxyethyl)-1'',3''-dithian-2''-yl>-2'-(2''''-oxotetrahydrofuran-3''''-ylidene)ethoxymethyl>propenoate
    —— (R)-2-cyclohexylsulfinyl-N,N-dimethylethanethioamide 226709-30-4 C10H19NOS2
    (R)-2-cyclohexylsulfinyl-N,N-dimethylethanethioamide
    —— 6-trifluoromethyl-1,3-dithiolo-{4,5-b}thiazolo-{4,5-e}pyrazin-2-ylidene-propanedinitrile 66492-43-1 C10F3N5S3
    6-trifluoromethyl-1,3-dithiolo-{4,5-b}thiazolo-{4,5-e}pyrazin-2-ylidene-propanedinitrile
    —— 1-[(Methoxymethyl)sulfanyl]-2-methylbenzene 64846-49-7 C9H12OS
    1-[(Methoxymethyl)sulfanyl]-2-methylbenzene
    —— 2-(4-phenylsulfanylbut-2-ynyloxymethyl)acylic acid methyl ester 591769-41-4 C15H16O3S
    2-(4-phenylsulfanylbut-2-ynyloxymethyl)acylic acid methyl ester
    —— 2,6-Bis(dicyanomethylidene)-[1,3]dithiolo[4,5-f][1,3]benzodithiole-4,8-dicarbonitrile 1118625-82-3 C16N6S4
    2,6-Bis(dicyanomethylidene)-[1,3]dithiolo[4,5-f][1,3]benzodithiole-4,8-dicarbonitrile
    —— N,N-diethylthiocarbamic acid S-o-tolyl ester 82125-34-6 C12H17NOS
    N,N-diethylthiocarbamic acid S-o-tolyl ester
    —— S-pentyl 2-diazo-4-methylsulfanylbutanethioate 1380511-64-7 C10H18N2OS2
    S-pentyl 2-diazo-4-methylsulfanylbutanethioate
    —— S-cyclohexyl 2-diazo-4-methylsulfanylbutanethioate 1380511-67-0 C11H18N2OS2
    S-cyclohexyl 2-diazo-4-methylsulfanylbutanethioate
    —— 2-((methylsulfonyl)methyl)propenoic acid methyl ester 143224-94-6 C6H10O4S
    2-((methylsulfonyl)methyl)propenoic acid methyl ester
    —— (E)-methyl 2-(3-methyl-4-oxo-1-<2-(2-oxoethyl)-1,3-dithian-2-yl>pent-2-enyloxymethyl)prop-2-enoate 121362-97-8 C17H24O5S2
    (E)-methyl 2-(3-methyl-4-oxo-1-<2-(2-oxoethyl)-1,3-dithian-2-yl>pent-2-enyloxymethyl)prop-2-enoate
    —— (E)-1-<2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl>3-(2-methyl-1,3-dioxolan-2-yl)but-2-en-1-ol 121362-95-6 C16H28O5S2
    (E)-1-<2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl>3-(2-methyl-1,3-dioxolan-2-yl)but-2-en-1-ol
    —— (E)-methyl 2-(1-<2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl>3-(2-methyl-1,3-dioxolan-2-yl)but-2-enyloxymethyl)prop-2-enoate 121362-96-7 C21H34O7S2
    (E)-methyl 2-(1-<2-(2,2-dimethoxyethyl)-1,3-dithian-2-yl>3-(2-methyl-1,3-dioxolan-2-yl)but-2-enyloxymethyl)prop-2-enoate
    —— thiomyristamide 159458-37-4 C14H29NS
    thiomyristamide
    —— (4-Amino-2-(butylthio)pyrimidin-5-yl)methanol 62671-92-5 C9H15N3OS
    (4-Amino-2-(butylthio)pyrimidin-5-yl)methanol
    —— 5,6-diamino-2-ethylthiopyrimidin-4(3H)-one 290370-88-6 C6H10N4OS
    5,6-diamino-2-ethylthiopyrimidin-4(3H)-one
    —— 4-(mesyloxymethyl)-6-methyl-5-phenylthio-1,2,3,4-tetrahydropyrimidin-2-one 1353137-38-8 C13H16N2O4S2
    4-(mesyloxymethyl)-6-methyl-5-phenylthio-1,2,3,4-tetrahydropyrimidin-2-one
    —— 5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carboxylic acid butylamide 116986-32-4 C8H15N5OS
    5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carboxylic acid butylamide
    —— N-(2-benzylthiobenzyl)succinimide 226088-31-9 C18H17NO2S
    N-(2-benzylthiobenzyl)succinimide
    —— 4-(mesyloxymethyl)-6-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimidin-2-one 1353137-39-9 C18H18N2O4S2
    4-(mesyloxymethyl)-6-phenyl-5-phenylthio-1,2,3,4-tetrahydropyrimidin-2-one
    —— 1,2,7,8-tetra(methylthio)octane 105836-03-1 C12H26S4
    1,2,7,8-tetra(methylthio)octane
    —— 7-methyl-6-phenylthio-4-succinimido-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-53-7 C16H17N3O3S
    7-methyl-6-phenylthio-4-succinimido-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— 1-[(phenylthio)[13C]methyl]-2,5-pyrrolidinedione 1071435-36-3 C11H11NO2S
    1-[(phenylthio)[13C]methyl]-2,5-pyrrolidinedione
    —— 7-phenyl-6-phenylthio-4-succinimido-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one 1353137-54-8 C21H19N3O3S
    7-phenyl-6-phenylthio-4-succinimido-2,3,4,5-tetrahydro-1H-1,3-diazepin-2-one
    —— (13C)chloromethyl phenyl sulfide 92136-61-3 C7H7ClS
    (13C)chloromethyl phenyl sulfide
    —— 1-Phenylsulfanylpent-4-en-2-ol 72728-97-3 C11H14OS
    1-Phenylsulfanylpent-4-en-2-ol
    —— (1,3-Dithian-2-yl)(2-methyl-1,3-dithian-2-yl)methane 19451-21-9 C10H18S4
    (1,3-Dithian-2-yl)(2-methyl-1,3-dithian-2-yl)methane
    —— dithiocarbonic acid O-ethyl S-(2-(trifluoromethyl)pyridin-4-yl) diester 147149-99-3 C9H8F3NOS2
    dithiocarbonic acid O-ethyl S-(2-(trifluoromethyl)pyridin-4-yl) diester
    —— 5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carboxylic acid amide 116986-31-3 C4H7N5OS
    5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carboxylic acid amide
    —— 1H-Imidazol-2-amine, 4,5-dihydro-N-[3-[(4-methoxyphenyl)thio]phenyl]- 677343-23-6 C16H17N3OS
    1H-Imidazol-2-amine, 4,5-dihydro-N-[3-[(4-methoxyphenyl)thio]phenyl]-
    —— 5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carboxylic acid ethylamide 117007-16-6 C6H11N5OS
    5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carboxylic acid ethylamide
    —— (2E)-3-(3-Amino-4-cyan-5-methylthio-2-thienyl)acrylonitril 123624-80-6 C9H7N3S2
    (2E)-3-(3-Amino-4-cyan-5-methylthio-2-thienyl)acrylonitril
    —— N-(3-methylthio-1H-1,2,4-triazole-5-yl)-N-methylthiourea 116986-61-9 C5H9N5S2
    N-(3-methylthio-1H-1,2,4-triazole-5-yl)-N-methylthiourea
    —— 7-amino-2,3-dihydro-5-oxo-5H-thiazolo<3,2-a>pyrimidine-3-acetonitrile 126856-96-0 C8H8N4OS
    7-amino-2,3-dihydro-5-oxo-5H-thiazolo<3,2-a>pyrimidine-3-acetonitrile
    —— 5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carboxylic acid cyclohexylamide 116986-34-6 C10H17N5OS
    5-Amino-3-methylsulfanyl-[1,2,4]triazole-1-carboxylic acid cyclohexylamide
    —— N-tert-butyl-2-(thiophen-2-ylthio)benzamide 1002760-00-0 C15H17NOS2
    N-tert-butyl-2-(thiophen-2-ylthio)benzamide
    —— 5-Butyl-4-phenylsulfanyl-5H-furan-2-one 117621-21-3 C14H16O2S
    5-Butyl-4-phenylsulfanyl-5H-furan-2-one
    —— (2,5-Dimethoxy-3-thienylthio)-acetic Acid 58386-21-3 C8H10O4S2
    (2,5-Dimethoxy-3-thienylthio)-acetic Acid
    —— 3-Acetyl-4-tert-butylsulfanyl-6-methylpyran-2-one 144425-55-8 C12H16O3S
    3-Acetyl-4-tert-butylsulfanyl-6-methylpyran-2-one
    —— 6-hydroxy-1,4-dithiaspiro<4.5>decane 59780-98-2 C8H14OS2
    6-hydroxy-1,4-dithiaspiro<4.5>decane
    —— 2,3,5,6,7,8-hexahydro-1λ<sup>6</sup>,4λ<sup>6</sup>-benzodithiine-1,1,4,4-tetrone 55789-62-3 C8H12O4S2
    2,3,5,6,7,8-hexahydro-1λ<sup>6</sup>,4λ<sup>6</sup>-benzodithiine-1,1,4,4-tetrone
    —— Δ<sup>1(6)</sup>-2,5-dithiabicyclo<4.4.0>decene 23285-17-8 C8H12S2
    Δ<sup>1(6)</sup>-2,5-dithiabicyclo<4.4.0>decene
    —— (E)-3-chloro-2-perfluoronutanesulfinyl-1-ethoxyprop-1-ene 1184977-59-0 C9H8ClF9O2S
    (E)-3-chloro-2-perfluoronutanesulfinyl-1-ethoxyprop-1-ene