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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Ethylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one 129109-29-1 C14H14N2O3S
    5-Ethylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one
    —— 3-(3-methyl-allyl)-4-(4-phenylsulfanyl-hexa-3(E),5-dienyl)-2-cyclohexen-1-one 223103-66-0 C22H26OS
    3-(3-methyl-allyl)-4-(4-phenylsulfanyl-hexa-3(E),5-dienyl)-2-cyclohexen-1-one
    —— 3-isobutoxy-6-(4-phenylsulfanyl-hexa-3(E),5-dienyl)-2-cyclohexen-1-one 223103-62-6 C22H28O2S
    3-isobutoxy-6-(4-phenylsulfanyl-hexa-3(E),5-dienyl)-2-cyclohexen-1-one
    —— 5-bromo-2-[(2,4-dichlorophenyl)thio]benzaldehyde 311808-51-2 C13H7BrCl2OS
    5-bromo-2-[(2,4-dichlorophenyl)thio]benzaldehyde
    —— 3-[(2,4-dichlorophenyl)thio]benzoic acid 311808-47-6 C13H8Cl2O2S
    3-[(2,4-dichlorophenyl)thio]benzoic acid
    —— 5-n-Propylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one 129109-30-4 C15H16N2O3S
    5-n-Propylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one
    —— 4-(2,4-dichlorophenylthio)anisole 1426334-37-3 C13H10Cl2OS
    4-(2,4-dichlorophenylthio)anisole
    —— (2,5-dichloro-phenyl)-(4-nitro-phenyl)-sulfide 90309-44-7 C12H7Cl2NO2S
    (2,5-dichloro-phenyl)-(4-nitro-phenyl)-sulfide
    —— 1-[5-(2,4-dichlorophenylsulfanyl)-4-nitro-2-thienyl]ethanone 1247819-56-2 C12H7Cl2NO3S2
    1-[5-(2,4-dichlorophenylsulfanyl)-4-nitro-2-thienyl]ethanone
    —— 3-bromo-4-[(2,4-dichlorophenyl)thio]benzaldehyde 311808-49-8 C13H7BrCl2OS
    3-bromo-4-[(2,4-dichlorophenyl)thio]benzaldehyde
    —— 4-(4-chloro-phenylsulfanyl)-1-methyl-1<i>H</i>-pyrazolo[3,4-<i>d</i>]pyrimidine 100124-64-9 C12H9ClN4S
    4-(4-chloro-phenylsulfanyl)-1-methyl-1<i>H</i>-pyrazolo[3,4-<i>d</i>]pyrimidine
    —— 3-Chloro-4-trifluoromethyl-2,6-dinitro-2',4'-dichlorodiphenylthioether 67364-63-0 C13H4Cl3F3N2O4S
    3-Chloro-4-trifluoromethyl-2,6-dinitro-2',4'-dichlorodiphenylthioether
    —— 1-[5-(2,4-dichlorophenyl)sulfanyl-4-nitro-2-thienyl]-3-dimethylamino-propan-1-one 1247828-78-9 C15H14Cl2N2O3S2
    1-[5-(2,4-dichlorophenyl)sulfanyl-4-nitro-2-thienyl]-3-dimethylamino-propan-1-one
    —— 2-(2,5-Dichlorophenylthio)benzylalkohol 50900-35-1 C13H10Cl2OS
    2-(2,5-Dichlorophenylthio)benzylalkohol
    —— 2-(2,4-dichlorophenylthio)-5,7-dimethylquinoline-3-carbaldehyde 1309388-96-2 C18H13Cl2NOS
    2-(2,4-dichlorophenylthio)-5,7-dimethylquinoline-3-carbaldehyde
    —— 5-Methyl-2,3-dihydro-1-benzothiophene 14450-23-8 C9H10S
    5-Methyl-2,3-dihydro-1-benzothiophene
    —— 1,2-Dichloro-3-(2,4-dichlorophenyl)sulfanylbenzene 1046803-84-2 C12H6Cl4S
    1,2-Dichloro-3-(2,4-dichlorophenyl)sulfanylbenzene
    —— 4-(2,4-Dichlorophenyl)sulfanyl-2-(trichloromethyl)quinazoline 1336930-75-6 C15H7Cl5N2S
    4-(2,4-Dichlorophenyl)sulfanyl-2-(trichloromethyl)quinazoline
    —— 4,7,4',7'-tetrachloro-[2,2']bi[benzo[<i>b</i>]thiophenylidene]-3,3'-dione 14295-43-3 C16H4Cl4O2S2
    4,7,4',7'-tetrachloro-[2,2']bi[benzo[<i>b</i>]thiophenylidene]-3,3'-dione
    —— 2-(2,4-dichlorophenylthio)-8-methylquinoline-3-carbaldehyde 1309388-93-9 C17H11Cl2NOS
    2-(2,4-dichlorophenylthio)-8-methylquinoline-3-carbaldehyde
    —— 5-(2,4-dichlorophenylsulfanyl)-4-nitrothiophene-2-carbaldehyde 1247820-05-8 C11H5Cl2NO3S2
    5-(2,4-dichlorophenylsulfanyl)-4-nitrothiophene-2-carbaldehyde
    —— 2-(2,5-Dichlorophenyl)sulfanylpyridine-3-carbonyl chloride 1026959-06-7 C12H6Cl3NOS
    2-(2,5-Dichlorophenyl)sulfanylpyridine-3-carbonyl chloride
    —— 2-[4-[1-[5-Chloro-2-(2,5-dichlorophenyl)sulfanylphenyl]ethyl]piperazin-1-yl]ethanol 112446-38-5 C20H23Cl3N2OS
    2-[4-[1-[5-Chloro-2-(2,5-dichlorophenyl)sulfanylphenyl]ethyl]piperazin-1-yl]ethanol
    —— 2-(2,5-Dichlorophenylthio)phenylessigsaeure 51723-35-4 C14H10Cl2O2S
    2-(2,5-Dichlorophenylthio)phenylessigsaeure
    —— 1-(5-chloro-2-(2,5-dichlorophenylthio)phenyl)ethanol 112446-24-9 C14H11Cl3OS
    1-(5-chloro-2-(2,5-dichlorophenylthio)phenyl)ethanol
    —— 1-[1-[5-Chloro-2-(2,5-dichlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine 112446-34-1 C19H21Cl3N2S
    1-[1-[5-Chloro-2-(2,5-dichlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine
    —— 2-(2,5-Dichloro-phenylsulfanyl)-nicotinic acid 181527-55-9 C12H7Cl2NO2S
    2-(2,5-Dichloro-phenylsulfanyl)-nicotinic acid
    —— 1-methoxy-1-(phenylthio)cyclopropane 75697-56-2 C10H12OS
    1-methoxy-1-(phenylthio)cyclopropane
    —— 2-(2,5-Dichlorophenyl)sulfanyl-6-fluorobenzonitrile 348168-90-1 C13H6Cl2FNS
    2-(2,5-Dichlorophenyl)sulfanyl-6-fluorobenzonitrile
    —— 4-(2,5-dichlorophenylthio)-3-nitrobenzonitrile 1252681-83-6 C13H6Cl2N2O2S
    4-(2,5-dichlorophenylthio)-3-nitrobenzonitrile
    —— 1,2-Dichloro-3-(2,5-dichlorophenyl)sulfanylbenzene 1046803-85-3 C12H6Cl4S
    1,2-Dichloro-3-(2,5-dichlorophenyl)sulfanylbenzene
    —— Tert-butyl 4-(4-pyrido[3,2-b][1,4]benzothiazin-10-ylphenoxy)piperidine-1-carboxylate 1206478-95-6 C27H29N3O3S
    Tert-butyl 4-(4-pyrido[3,2-b][1,4]benzothiazin-10-ylphenoxy)piperidine-1-carboxylate
    —— 2-((4-chlorophenyl)thio)propanenitrile 18527-14-5 C9H8ClNS
    2-((4-chlorophenyl)thio)propanenitrile
    —— Methyl-5-<(E,2R,4S)-2-methoxy-5-(2-phenylsulfanylethylidene)tetrahydro-2H-pyran-4-yl>-3-oxopentanoate 172702-43-1 C20H26O5S
    Methyl-5-<(E,2R,4S)-2-methoxy-5-(2-phenylsulfanylethylidene)tetrahydro-2H-pyran-4-yl>-3-oxopentanoate
    —— 2-chloro-3-(phenylthio)-1H-indole 98508-68-0 C14H10ClNS
    2-chloro-3-(phenylthio)-1H-indole
    —— 2-(N-methylcarbamoyl)phenyl 2-chlorophenyl sulfide 343869-25-0 C14H12ClNOS
    2-(N-methylcarbamoyl)phenyl 2-chlorophenyl sulfide
    —— 1-ethynyl-2-trifluoromethylsulfanyl-benzene 1214756-22-5 C9H5F3S
    1-ethynyl-2-trifluoromethylsulfanyl-benzene
    —— N-(2-((2,4-dinitrophenyl)thio)phenyl)acetamide 2227-87-4 C14H11N3O5S
    N-(2-((2,4-dinitrophenyl)thio)phenyl)acetamide
    —— 1-bromo-4-(2-chlorophenylsulfanyl)-benzene 1451092-97-9 C12H8BrClS
    1-bromo-4-(2-chlorophenylsulfanyl)-benzene
    —— 2-((2-chlorophenyl)thio)-1H-imidazole 133328-78-6 C9H7ClN2S
    2-((2-chlorophenyl)thio)-1H-imidazole
    —— 4-methylthiothymine 55040-79-4 C6H8N2OS
    4-methylthiothymine
    —— 1-Brom-2,3,4,5-tetrakis(trifluormethylthio)pyrrol 100596-66-5 C8BrF12NS4
    1-Brom-2,3,4,5-tetrakis(trifluormethylthio)pyrrol
    —— 2,3,4,5-Tetrakis(trifluormethylthio)-1-pyrrolthiol 100596-65-4 C8HF12NS5
    2,3,4,5-Tetrakis(trifluormethylthio)-1-pyrrolthiol
    —— N-chloro-2,3,4,5-tetrakis(trifluoromethylthio)pyrrole 100596-74-5 C8ClF12NS4
    N-chloro-2,3,4,5-tetrakis(trifluoromethylthio)pyrrole
    —— 2,3,8,9-Tetrakis(tert-butylsulfonyl)-1,4,5,6,7,10,11,12-octahydrotetracene 170302-63-3 C34H52O8S4
    2,3,8,9-Tetrakis(tert-butylsulfonyl)-1,4,5,6,7,10,11,12-octahydrotetracene
    —— 2-methoxycarbonyl-4-methylthio-1-methylpyrrole 86186-83-6 C8H11NO2S
    2-methoxycarbonyl-4-methylthio-1-methylpyrrole
    —— 2,3-Bis-(2-methyl-propane-2-sulfonyl)-bicyclo[2.2.1]hepta-2,5-diene 129760-77-6 C15H24O4S2
    2,3-Bis-(2-methyl-propane-2-sulfonyl)-bicyclo[2.2.1]hepta-2,5-diene
    —— 5-bromo-2-(3-fluoro-phenylsulfanyl)-1-methoxybenzene 905815-85-2 C13H10BrFOS
    5-bromo-2-(3-fluoro-phenylsulfanyl)-1-methoxybenzene
    —— 2-Methyl-3-(2-methyl-propane-2-sulfonyl)-bicyclo[2.2.1]hepta-2,5-diene 129760-85-6 C12H18O2S
    2-Methyl-3-(2-methyl-propane-2-sulfonyl)-bicyclo[2.2.1]hepta-2,5-diene
    —— 2-<2-(methylthio)phenyl>-4,4-dimethyloxazoline 86065-02-3 C12H15NOS
    2-<2-(methylthio)phenyl>-4,4-dimethyloxazoline