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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,(3)N-diamino-3,4-dihydro-6-methylsulfanyl-4-oxopyrimidine-5-carbonitrile 886588-34-7 C6H7N5OS
    2,(3)N-diamino-3,4-dihydro-6-methylsulfanyl-4-oxopyrimidine-5-carbonitrile
    —— 2-(pentylthio)pyrimidine-4,6-diamine 70805-44-6 C9H16N4S
    2-(pentylthio)pyrimidine-4,6-diamine
    —— 2-(6-iodobenzo[d][1,3]dioxol-5-ylthio)-1-pentyl-1H-imidazo[4,5-c]pyridin-4-amine 1061316-65-1 C18H19IN4O2S
    2-(6-iodobenzo[d][1,3]dioxol-5-ylthio)-1-pentyl-1H-imidazo[4,5-c]pyridin-4-amine
    —— methyl 5-chloro-2,3-dihydrobenzothiophene-3-carboxylate 93670-23-6 C10H9ClO2S
    methyl 5-chloro-2,3-dihydrobenzothiophene-3-carboxylate
    —— 6-[2-(methylcarbamoyl)phenylsulfanyl]-3-[2-(pyridine-2-yl)ethynyl]indazole 885126-38-5 C22H16N4OS
    6-[2-(methylcarbamoyl)phenylsulfanyl]-3-[2-(pyridine-2-yl)ethynyl]indazole
    —— 2-octynyl 2'-propynyl sulfone 175439-09-5 C11H16O2S
    2-octynyl 2'-propynyl sulfone
    —— methyl (5S,6Z,8E)-5-hydroxy-11-[2-[(Z)-oct-2-enyl]-1,3-dithian-2-yl]undeca-6,8-dienoate 185202-27-1 C24H40O3S2
    methyl (5S,6Z,8E)-5-hydroxy-11-[2-[(Z)-oct-2-enyl]-1,3-dithian-2-yl]undeca-6,8-dienoate
    —— 3-[2-[(Z)-oct-2-enyl]-1,3-dithian-2-yl]propanal 162709-32-2 C15H26OS2
    3-[2-[(Z)-oct-2-enyl]-1,3-dithian-2-yl]propanal
    —— (E)-5-[2-[(Z)-oct-2-enyl]-1,3-dithian-2-yl]pent-2-en-1-ol 185202-24-8 C17H30OS2
    (E)-5-[2-[(Z)-oct-2-enyl]-1,3-dithian-2-yl]pent-2-en-1-ol
    —— methylthioacrylonitrile 51245-70-6 C4H5NS
    methylthioacrylonitrile
    —— 1-(Dichloracetyl)-4,5,6,7,8,9-hexahydro-3-(methylthio)cycloocta<c>furan 102435-90-5 C13H16Cl2O2S
    1-(Dichloracetyl)-4,5,6,7,8,9-hexahydro-3-(methylthio)cycloocta<c>furan
    —— 3-Methyl-5-(1-oxypyridin-2-yl)-8-(thien-2-ylthio)-1,2,3,4-tetrahydronaphthalen-1-one 256222-34-1 C20H17NO2S2
    3-Methyl-5-(1-oxypyridin-2-yl)-8-(thien-2-ylthio)-1,2,3,4-tetrahydronaphthalen-1-one
    —— 6-((4-phenyl-1,3-thiazol-2-yl)sulfanyl)hexan-1-ol 1101021-08-2 C15H19NOS2
    6-((4-phenyl-1,3-thiazol-2-yl)sulfanyl)hexan-1-ol
    —— ethyl 5-chloro-2,3-dihydrobenzothiophene-3-carboxylate 93670-24-7 C11H11ClO2S
    ethyl 5-chloro-2,3-dihydrobenzothiophene-3-carboxylate
    —— 2-butyl-2-(7,9-dioxadecyl)-1,3-dithiane 386223-56-9 C16H32O2S2
    2-butyl-2-(7,9-dioxadecyl)-1,3-dithiane
    —— N-(3-acetyl-5-cyano-2-methyl-6-methylsulfanyl-pyridin-4-yl)-formimidic acid ethyl ester 897926-00-0 C13H15N3O2S
    N-(3-acetyl-5-cyano-2-methyl-6-methylsulfanyl-pyridin-4-yl)-formimidic acid ethyl ester
    —— 3-(benzylsulfanyl)-7-chloro-1,5-dimethyl-1H-pyrimido[4,5-e][1,3,4]thiadiazine 938158-24-8 C14H13ClN4S2
    3-(benzylsulfanyl)-7-chloro-1,5-dimethyl-1H-pyrimido[4,5-e][1,3,4]thiadiazine
    —— 4-[(4-chloro-4-oxobutyl)disulfanyl]butanoyl chloride 1002-22-8 C8H12Cl2O2S2
    4-[(4-chloro-4-oxobutyl)disulfanyl]butanoyl chloride
    —— 4-hexylthio-5-(6-hydroxyhexylthio)-1,3-dithiole-2-thione 218150-21-1 C15H26OS5
    4-hexylthio-5-(6-hydroxyhexylthio)-1,3-dithiole-2-thione
    —— (E)-1-(phenylthio)cyclododecene 85894-83-3 C18H26S
    (E)-1-(phenylthio)cyclododecene
    —— 2,4,6-tris(methylthio)anilin 102093-65-2 C9H13NS3
    2,4,6-tris(methylthio)anilin
    —— 4-(6-hydroxyhexylthio)-5-(methylthio)-1,3-dithiole-2-thione 218149-86-1 C10H16OS5
    4-(6-hydroxyhexylthio)-5-(methylthio)-1,3-dithiole-2-thione
    —— 5-chloro-4-methyl-6-methylsulfanyl-pyrimidin-2-ylamine 36082-47-0 C6H8ClN3S
    5-chloro-4-methyl-6-methylsulfanyl-pyrimidin-2-ylamine
    —— 1-methyl-2-cyano-3-ethyl-4-thiophenylpiperidine 73657-77-9 C15H20N2S
    1-methyl-2-cyano-3-ethyl-4-thiophenylpiperidine
    —— 1,3-Dithiepane 1,1,3,3-tetraoxide 57542-77-5 C5H10O4S2
    1,3-Dithiepane 1,1,3,3-tetraoxide
    —— <i>D</i>-6-deoxy-glucose diethyl dithioacetal 111955-40-9 C10H22O4S2
    <i>D</i>-6-deoxy-glucose diethyl dithioacetal
    —— 6-(4-bromophenyl)-2-ethylsulfanyl-4H-thiopyran-4-one 500169-92-6 C13H11BrOS2
    6-(4-bromophenyl)-2-ethylsulfanyl-4H-thiopyran-4-one
    —— 3-Methylsulfanyl-6,7,8,9-tetrahydro-5H-pyridazino[3,4-b]azepine 108005-23-8 C9H13N3S
    3-Methylsulfanyl-6,7,8,9-tetrahydro-5H-pyridazino[3,4-b]azepine
    —— 2-methane sulfonyl-N-nonylacetamide 501334-08-3 C12H25NO3S
    2-methane sulfonyl-N-nonylacetamide
    —— 2-chloro-2-(phenylthio)acetyl chloride 137469-71-7 C8H6Cl2OS
    2-chloro-2-(phenylthio)acetyl chloride
    —— 4,5-bis(2-ethylsulfanyl)-1,3-dithiole-2-thione 59065-21-3 C7H10S5
    4,5-bis(2-ethylsulfanyl)-1,3-dithiole-2-thione
    —— N-propyl-4-(2,3-dihydro-1,4-benzoxathiin-5-yl)butanamide 214894-82-3 C15H21NO2S
    N-propyl-4-(2,3-dihydro-1,4-benzoxathiin-5-yl)butanamide
    —— Carbamothioic acid, hexyl-, S-phenyl ester 85966-68-3 C13H19NOS
    Carbamothioic acid, hexyl-, S-phenyl ester
    —— 4-(2,3-dihydro-1,4-benzoxathiin-5-yl)butyronitrile 214895-12-2 C12H13NOS
    4-(2,3-dihydro-1,4-benzoxathiin-5-yl)butyronitrile
    —— ethylthioethyl 2-hydroxyethynyl sulfide 112164-95-1 C6H10OS2
    ethylthioethyl 2-hydroxyethynyl sulfide
    —— 4,7-Dichloro-2-(4,7-dichloro-3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one 14295-43-3 C16H4Cl4O2S2
    4,7-Dichloro-2-(4,7-dichloro-3-oxobenzo[b]thien-2(3H)-ylidene)benzo[b]thiophene-3(2H)-one
    —— 1-methyl-2-cyano-2-methyl-3-ethyl-4-thiophenylpiperidine 73658-15-8 C16H22N2S
    1-methyl-2-cyano-2-methyl-3-ethyl-4-thiophenylpiperidine
    —— 1-methyl-2-cyano-2-deuterio-3-ethyl-4-thiophenylpiperidine 73658-14-7 C15H20N2S
    1-methyl-2-cyano-2-deuterio-3-ethyl-4-thiophenylpiperidine
    —— 2,5-diisobutyryloxy-2,5-dimethyl-1,4-dithiane 141279-89-2 C14H24O4S2
    2,5-diisobutyryloxy-2,5-dimethyl-1,4-dithiane
    —— 5-chloro-2-ethyl-4-(ethylthio)pyridazin-3(2H)-one 105651-67-0 C8H11ClN2OS
    5-chloro-2-ethyl-4-(ethylthio)pyridazin-3(2H)-one
    —— 5-Chloro-2-methyl-4-[(propan-2-yl)sulfanyl]pyridazin-3(2H)-one 105651-66-9 C8H11ClN2OS
    5-Chloro-2-methyl-4-[(propan-2-yl)sulfanyl]pyridazin-3(2H)-one
    —— 2,5-dimethyl-2,5-dipropionyloxy-1,4-dithiane 141261-91-8 C12H20O4S2
    2,5-dimethyl-2,5-dipropionyloxy-1,4-dithiane
    —— 2,5-dibutyryloxy-2,5-dimethyl-1,4-dithiane 141261-92-9 C14H24O4S2
    2,5-dibutyryloxy-2,5-dimethyl-1,4-dithiane
    —— 2,5-dimethyl-2,5-divaleryloxy-1,4-dithiane 141279-90-5 C16H28O4S2
    2,5-dimethyl-2,5-divaleryloxy-1,4-dithiane
    —— 5-methylsulfanyl-3-phenyl-3<i>H</i>-[1,3,4]thiadiazol-2-one 27434-26-0 C9H8N2OS2
    5-methylsulfanyl-3-phenyl-3<i>H</i>-[1,3,4]thiadiazol-2-one
    —— 1-(3-bromopropylsulfanyl)-3,5-difluorobenzene 1050646-87-1 C9H9BrF2S
    1-(3-bromopropylsulfanyl)-3,5-difluorobenzene
    —— (2S)-4-(1,3-dithian-2-yl)-1,2-epoxy-4-phenylbutane 259856-85-4 C13H16OS2
    (2S)-4-(1,3-dithian-2-yl)-1,2-epoxy-4-phenylbutane
    —— 9-((E)-1-Phenylsulfanyl-propenyloxy)-9-bora-bicyclo[3.3.1]nonane 73739-33-0 C17H23BOS
    9-((E)-1-Phenylsulfanyl-propenyloxy)-9-bora-bicyclo[3.3.1]nonane
    —— (3R)-5-(1,3-dithian-2-yl)-3-hydroxy-5-phenylpentanenitrile 259856-86-5 C14H17NOS2
    (3R)-5-(1,3-dithian-2-yl)-3-hydroxy-5-phenylpentanenitrile
    —— S-2-pyridyl hexanothioate 19337-35-0 C11H15NOS
    S-2-pyridyl hexanothioate