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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 10H-9-Chloro-1-azaphenothiazine 93616-76-3 C11H7ClN2S
    10H-9-Chloro-1-azaphenothiazine
    —— 1-(5-tert-butylisoxazol-3-yl)-3-(3-(2-chloro-6,7-dimethoxyquinazolin-4-ylthio)phenyl)urea 1188907-91-6 C24H24ClN5O4S
    1-(5-tert-butylisoxazol-3-yl)-3-(3-(2-chloro-6,7-dimethoxyquinazolin-4-ylthio)phenyl)urea
    —— 2-(4-chlorobenzylthio)-5-(pyridin-4-yl)-1,3,4-oxadiazole 675827-49-3 C14H10ClN3OS
    2-(4-chlorobenzylthio)-5-(pyridin-4-yl)-1,3,4-oxadiazole
    —— 2-<(3-chlorophenyl)thio>nicotinic acid 151051-00-2 C12H8ClNO2S
    2-<(3-chlorophenyl)thio>nicotinic acid
    —— 1-(4-chlorobenzyl)-4-((phenylthio)methyl)-1H-1,2,3-triazole 1573118-99-6 C16H14ClN3S
    1-(4-chlorobenzyl)-4-((phenylthio)methyl)-1H-1,2,3-triazole
    —— 4-[(2,2-Dimethoxyethyl)sulfanyl]-4-methoxybutan-2-one 89055-50-5 C9H18O4S
    4-[(2,2-Dimethoxyethyl)sulfanyl]-4-methoxybutan-2-one
    —— 1-Chloro-3-(heptylsulfanyl)benzene 89165-40-2 C13H19ClS
    1-Chloro-3-(heptylsulfanyl)benzene
    —— trans-β-Cyanvinyl-p-tolyl-thioaether 34726-88-0 C10H9NS
    trans-β-Cyanvinyl-p-tolyl-thioaether
    —— bis(m-chlorophenyl) sulfide 5097-96-1 C12H8Cl2S
    bis(m-chlorophenyl) sulfide
    —— 1,2-bis((4-bromophenyl)thio)ethane 16181-18-3 C14H12Br2S2
    1,2-bis((4-bromophenyl)thio)ethane
    —— 1-[1-[5-Chloro-2-(3,4-dichlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine 112446-33-0 C19H21Cl3N2S
    1-[1-[5-Chloro-2-(3,4-dichlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine
    —— 1-[1-[5-Chloro-2-(3,4-dichlorophenyl)sulfanylphenyl]ethyl]-4-(2-methoxyethyl)piperazine 112446-39-6 C21H25Cl3N2OS
    1-[1-[5-Chloro-2-(3,4-dichlorophenyl)sulfanylphenyl]ethyl]-4-(2-methoxyethyl)piperazine
    —— 2-amino-5-[(3,4-dichlorophenyl)sulfanyl]-6-methylthieno[2,3-d]pyrimidin-4(3H)-one 1059126-65-6 C13H9Cl2N3OS2
    2-amino-5-[(3,4-dichlorophenyl)sulfanyl]-6-methylthieno[2,3-d]pyrimidin-4(3H)-one
    —— (4-((methoxymethoxy)methyl)-3-bromophenyl)(3,4-dichlorophenyl)sulfide 1222010-78-7 C15H13BrCl2O2S
    (4-((methoxymethoxy)methyl)-3-bromophenyl)(3,4-dichlorophenyl)sulfide
    —— 2-[4-[1-[5-Chloro-2-(3,4-dichlorophenyl)sulfanylphenyl]ethyl]piperazin-1-yl]ethanol 112446-37-4 C20H23Cl3N2OS
    2-[4-[1-[5-Chloro-2-(3,4-dichlorophenyl)sulfanylphenyl]ethyl]piperazin-1-yl]ethanol
    —— 6-(3',4'-dichlorophenyl)sulfanyl-1,3-dihydro-1-hydroxy-2,1-benzoxaborole 1222009-80-4 C13H9BCl2O2S
    6-(3',4'-dichlorophenyl)sulfanyl-1,3-dihydro-1-hydroxy-2,1-benzoxaborole
    —— 4-((3,4-dichlorophenyl)thio)-2-bromobenzyl alcohol 1222010-77-6 C13H9BrCl2OS
    4-((3,4-dichlorophenyl)thio)-2-bromobenzyl alcohol
    —— 1-{5-[(3,4-dichlorophenyl)thio]-4-nitrothiophen-2-yl}ethanone 1247819-67-5 C12H7Cl2NO3S2
    1-{5-[(3,4-dichlorophenyl)thio]-4-nitrothiophen-2-yl}ethanone
    —— 6-(3,4-Dichloro-phenylsulfanyl)-pyrido[3,2-d]pyrimidine-2,4-diamine 95095-94-6 C13H9Cl2N5S
    6-(3,4-Dichloro-phenylsulfanyl)-pyrido[3,2-d]pyrimidine-2,4-diamine
    —— 2-(3-(3,4-dichlorophenylthio)-1H-indol-4-yloxy)-N-(4,5-dichlorothiophen-2-ylsulfonyl)acetamide 1057256-10-6 C20H12Cl4N2O4S3
    2-(3-(3,4-dichlorophenylthio)-1H-indol-4-yloxy)-N-(4,5-dichlorothiophen-2-ylsulfonyl)acetamide
    —— 6-<(3,4-dichlorophenyl)thio>-2,4-pteridinediamine 77900-95-9 C12H8Cl2N6S
    6-<(3,4-dichlorophenyl)thio>-2,4-pteridinediamine
    —— Di(2-chloro-2-phenylethyl) sulfide 29713-21-1 C16H16Cl2S
    Di(2-chloro-2-phenylethyl) sulfide
    —— 5,7-dinitro-3-phenyl-2-(3,4-dichlorophenylthio)quinoxaline 1148020-94-3 C20H10Cl2N4O4S
    5,7-dinitro-3-phenyl-2-(3,4-dichlorophenylthio)quinoxaline
    —— 2,4-diamino-5-isopropyl-6-(3',4'-dichlorophenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine 1043925-22-9 C15H15Cl2N5S
    2,4-diamino-5-isopropyl-6-(3',4'-dichlorophenylsulfanyl)-7H-pyrrolo[2,3-d]pyrimidine
    —— 6-(3-(3,4-dichlorophenylsulfanyl)indol-1-yl)-1,3-dihydro-1-hydroxy-2,1-benzoxaborole 1309068-61-8 C21H14BCl2NO2S
    6-(3-(3,4-dichlorophenylsulfanyl)indol-1-yl)-1,3-dihydro-1-hydroxy-2,1-benzoxaborole
    —— 2-amino-5-[(3,4-dichlorophenyl)thio]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one 1178542-68-1 C14H11Cl2N3OS2
    2-amino-5-[(3,4-dichlorophenyl)thio]-6-ethylthieno[2,3-d]pyrimidin-4(3H)-one
    —— 2-bromo-4-(3,4-dichlorophenylthio)benzaldehyde 1222010-76-5 C13H7BrCl2OS
    2-bromo-4-(3,4-dichlorophenylthio)benzaldehyde
    —— 5-(Dimethylamino)-2-phenyl-1,3-dithiane-2-carbonitrile 90938-19-5 C13H16N2S2
    5-(Dimethylamino)-2-phenyl-1,3-dithiane-2-carbonitrile
    —— [7-(Phenylsulfanylmethyl)-1,4-dioxaspiro[4.5]decan-7-yl]methanamine 178207-85-7 C16H23NO2S
    [7-(Phenylsulfanylmethyl)-1,4-dioxaspiro[4.5]decan-7-yl]methanamine
    —— 5-n-Butylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one 129109-32-6 C16H18N2O3S
    5-n-Butylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one
    —— 5-(2,4-Dichlorophenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane] 1027262-76-5 C17H13Cl2NO4S
    5-(2,4-Dichlorophenyl)sulfanyl-6-nitrospiro[1,2-dihydroindene-3,2'-1,3-dioxolane]
    —— 3-[(2,4-dichlorophenyl)thio]benzaldehyde 311808-48-7 C13H8Cl2OS
    3-[(2,4-dichlorophenyl)thio]benzaldehyde
    —— N-[[7-(phenylsulfanylmethyl)-1,4-dioxaspiro[4.5]decan-7-yl]methyl]acetamide 178207-86-8 C18H25NO3S
    N-[[7-(phenylsulfanylmethyl)-1,4-dioxaspiro[4.5]decan-7-yl]methyl]acetamide
    —— 3-Oxo-1-(phenylsulfanylmethyl)cyclohexane-1-carbonitrile 178207-84-6 C14H15NOS
    3-Oxo-1-(phenylsulfanylmethyl)cyclohexane-1-carbonitrile
    —— 2-[(2,4-dichlorophenyl)sulfanyl]-1,3-dinitro-5-(trifluoromethyl)benzene 1137560-30-5 C13H5Cl2F3N2O4S
    2-[(2,4-dichlorophenyl)sulfanyl]-1,3-dinitro-5-(trifluoromethyl)benzene
    —— 5-Chloro-2-{[(2-chloro-6-fluorophenyl)methyl]sulfanyl}-1-oxo-1lambda~5~-pyridine 88965-56-4 C12H8Cl2FNOS
    5-Chloro-2-{[(2-chloro-6-fluorophenyl)methyl]sulfanyl}-1-oxo-1lambda~5~-pyridine
    —— N-[[3-oxo-1-(phenylsulfanylmethyl)cyclohexyl]methyl]acetamide 178207-73-3 C16H21NO2S
    N-[[3-oxo-1-(phenylsulfanylmethyl)cyclohexyl]methyl]acetamide
    —— 2-(3-(2,4-dichlorophenylthio)-1H-indol-4-yloxy)-N-(4,5-dichlorothiophen-2-ylsulfonyl)acetamide 1057256-23-1 C20H12Cl4N2O4S3
    2-(3-(2,4-dichlorophenylthio)-1H-indol-4-yloxy)-N-(4,5-dichlorothiophen-2-ylsulfonyl)acetamide
    —— 1-<(phenylthio)methyl>-2-cyclohexen-1-ol 148119-94-2 C13H16OS
    1-<(phenylthio)methyl>-2-cyclohexen-1-ol
    —— 5-(4-Chloro-phenylsulfanyl)-furan-2-carbonitrile 93105-05-6 C11H6ClNOS
    5-(4-Chloro-phenylsulfanyl)-furan-2-carbonitrile
    —— 2,4-Dichlorphenyl-2-aminophenylsulfid 33253-19-9 C12H9Cl2NS
    2,4-Dichlorphenyl-2-aminophenylsulfid
    —— 6-(4-tolylthio)-3-pyridinecarbonitrile 501378-62-7 C13H10N2S
    6-(4-tolylthio)-3-pyridinecarbonitrile
    —— 5-Phenylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one 129109-36-0 C18H14N2O3S
    5-Phenylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one
    —— 5-Benzylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one 129109-35-9 C19H16N2O3S
    5-Benzylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one
    —— 5-t-Butylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one 129109-33-7 C16H18N2O3S
    5-t-Butylthio-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one
    —— 6-(2,4-Dichlorophenylthio)purine 1020397-61-8 C11H6Cl2N4S
    6-(2,4-Dichlorophenylthio)purine
    —— 2-[(2,4-dichlorophenyl)thio](2-acrylamido)benzene 311808-46-5 C15H11Cl2NOS
    2-[(2,4-dichlorophenyl)thio](2-acrylamido)benzene
    —— 6-oxo-1-phenyl-4-phenylsulfanyl-1,6-dihydro-pyridazine-3-carboxamide 1398117-76-4 C17H13N3O2S
    6-oxo-1-phenyl-4-phenylsulfanyl-1,6-dihydro-pyridazine-3-carboxamide
    —— 7-[(2,4-dichlorophenyl)thio]thieno[3,2-b]pyridine-6-carbonitrile 700844-44-6 C14H6Cl2N2S2
    7-[(2,4-dichlorophenyl)thio]thieno[3,2-b]pyridine-6-carbonitrile
    —— 5-(2-Hydroxyethylthio)-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one 129109-37-1 C14H14N2O4S
    5-(2-Hydroxyethylthio)-6-methoxycarbonyl-2-phenylpyridazin-3(2H)-one