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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N,N-dimethyl-2-(2'-nitrophenylthio)benzamide 853180-69-5 C15H14N2O3S
    N,N-dimethyl-2-(2'-nitrophenylthio)benzamide
    —— 2,3-Bis(1,1,2,2-Tetrahydroperfluorodecylthio)-butane-1,4-diol 57216-74-7 C24H16F34O2S2
    2,3-Bis(1,1,2,2-Tetrahydroperfluorodecylthio)-butane-1,4-diol
    —— 1-Chloro-2-[(2-chloro-2-methoxyethyl)disulfanyl]-1-methoxyethane 89055-38-9 C6H12Cl2O2S2
    1-Chloro-2-[(2-chloro-2-methoxyethyl)disulfanyl]-1-methoxyethane
    —— Toluene-4-sulfonate3-(2,5-dihydroxy-3,4-dimethyl-phenylsulfanyl)-1,4,5-trimethyl-4H-[1,2,4]triazol-1-ium; 88305-31-1 C7H7O3S*C13H18N3O2S
    Toluene-4-sulfonate3-(2,5-dihydroxy-3,4-dimethyl-phenylsulfanyl)-1,4,5-trimethyl-4H-[1,2,4]triazol-1-ium;
    —— 5-(2-benzylsulfanylphenyl)-3H-1,3,4-oxadiazole-2-thione 861215-49-8 C15H12N2OS2
    5-(2-benzylsulfanylphenyl)-3H-1,3,4-oxadiazole-2-thione
    —— 4-[(p-methoxy)phenylthio]-1,2-phenylenediamine 201748-77-8 C13H14N2OS
    4-[(p-methoxy)phenylthio]-1,2-phenylenediamine
    —— 4-Methyl-2-{[(2,4,6-trimethylphenyl)methyl]sulfanyl}pyridine 88496-51-9 C16H19NS
    4-Methyl-2-{[(2,4,6-trimethylphenyl)methyl]sulfanyl}pyridine
    —— N-Methyl-2-[(5-sulfanylidene-2,5-dihydro-1,2,4-thiadiazol-3-yl)sulfanyl]acetamide 95115-09-6 C5H7N3OS3
    N-Methyl-2-[(5-sulfanylidene-2,5-dihydro-1,2,4-thiadiazol-3-yl)sulfanyl]acetamide
    —— 2-methylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile 226092-67-7 C11H8N4OS
    2-methylthio-4-oxo-6-(4-pyridyl)-3,4-dihydropyrimidine-5-carbonitrile
    —— 1,2-bis(phenylthio)maleic anhydride 77736-68-6 C16H10O3S2
    1,2-bis(phenylthio)maleic anhydride
    —— 2-{[(2,5-Dimethylphenyl)methyl]sulfanyl}-4-methylpyridine 81167-55-7 C15H17NS
    2-{[(2,5-Dimethylphenyl)methyl]sulfanyl}-4-methylpyridine
    —— 2-{[1-(2,5-Dimethylphenyl)ethyl]sulfanyl}-4-methylpyridine 88496-48-4 C16H19NS
    2-{[1-(2,5-Dimethylphenyl)ethyl]sulfanyl}-4-methylpyridine
    —— 4-amino-6-(4-methylbenzyl)-3-methylthio-4,5-dihydro-1,2,4-triazin-5-one 858780-41-3 C12H14N4OS
    4-amino-6-(4-methylbenzyl)-3-methylthio-4,5-dihydro-1,2,4-triazin-5-one
    —— 3-(n-propyl)-5-methylthio-7-methoxyimidazo[1,5-c]-pyrimidine 94694-43-6 C11H15N3OS
    3-(n-propyl)-5-methylthio-7-methoxyimidazo[1,5-c]-pyrimidine
    —— 4-{[(1-isopropyl-1H-imidazol-5-yl)methyl]sulfanyl}aniline 497851-79-3 C13H17N3S
    4-{[(1-isopropyl-1H-imidazol-5-yl)methyl]sulfanyl}aniline
    —— (4S,5S)-5-amino-2,2-dimethyl-4-(4-(methylthio)phenyl)-1,3-dioxane 855595-18-5 C13H19NO2S
    (4S,5S)-5-amino-2,2-dimethyl-4-(4-(methylthio)phenyl)-1,3-dioxane
    —— (4-bromophenyl)(4-fluorophenyl)sulfane 30427-78-2 C12H8BrFS
    (4-bromophenyl)(4-fluorophenyl)sulfane
    —— octyl prop-2-ene-1-sulfinate 1235334-81-2 C11H22O2S
    octyl prop-2-ene-1-sulfinate
    —— 2-methanesulfonyl-3-methylimino-acrylic acid ethyl ester 502187-12-4 C7H11NO4S
    2-methanesulfonyl-3-methylimino-acrylic acid ethyl ester
    —— 3-(4-Chlorophenyl)sulfanylpentanedioic acid 86628-16-2 C11H11ClO4S
    3-(4-Chlorophenyl)sulfanylpentanedioic acid
    —— 3-Nitro-4-(2,5-dimethyl-phenylmercapto)-benzolsulfonsaeure-methylamid 101113-23-9 C15H16N2O4S2
    3-Nitro-4-(2,5-dimethyl-phenylmercapto)-benzolsulfonsaeure-methylamid
    —— 4,5,4',5'-tetrachloro-2,2'-sulfanediyl-di-phenol 5136-30-1 C12H6Cl4O2S
    4,5,4',5'-tetrachloro-2,2'-sulfanediyl-di-phenol
    —— 3-Nitro-4-(4-chlor-phenylmercapto)-benzolsulfonsaeure-methylamid 100375-34-6 C13H11ClN2O4S2
    3-Nitro-4-(4-chlor-phenylmercapto)-benzolsulfonsaeure-methylamid
    —— 1,2,4,5-tetrakis-(phenylthiomethyl)benzene 810-97-9 C34H30S4
    1,2,4,5-tetrakis-(phenylthiomethyl)benzene
    —— 4-((2-aminophenyl)thio)benzonitrile 151079-70-8 C13H10N2S
    4-((2-aminophenyl)thio)benzonitrile
    —— 2-(2-(phenylthio)quinolin-8-yl)-6,7-dihydro-1H-pyrrolo[3,2-c]pyridin-4(5H)-one 1453792-30-7 C22H17N3OS
    2-(2-(phenylthio)quinolin-8-yl)-6,7-dihydro-1H-pyrrolo[3,2-c]pyridin-4(5H)-one
    —— 6-furan-2-yl-3-methylsulfanyl-4<i>H</i>-[1,2,4]triazin-5-one 26234-02-6 C8H7N3O2S
    6-furan-2-yl-3-methylsulfanyl-4<i>H</i>-[1,2,4]triazin-5-one
    —— 4-[(2,4-diamino-5-methyl-7H-pyrrolo[2,3-d]pyrimidin-6-yl)sulfanyl]-N-[2-(pyridin-3-yl)ethyl]benzamide 1258401-05-6 C21H21N7OS
    4-[(2,4-diamino-5-methyl-7H-pyrrolo[2,3-d]pyrimidin-6-yl)sulfanyl]-N-[2-(pyridin-3-yl)ethyl]benzamide
    —— 5-Chloro-2-{[(2,6-difluorophenyl)methyl]sulfanyl}-1-oxo-1lambda~5~-pyridine 88965-58-6 C12H8ClF2NOS
    5-Chloro-2-{[(2,6-difluorophenyl)methyl]sulfanyl}-1-oxo-1lambda~5~-pyridine
    —— 1-(2,2-dimethylpropanethioyl)azetidin-3-yl pivalate 1418564-21-2 C13H23NO2S
    1-(2,2-dimethylpropanethioyl)azetidin-3-yl pivalate
    —— (E)-methyl 3-(phenylthio)-4-(3-oxo-6,6-dimethylcyclohexyl)but-2-enoate 105090-09-3 C19H24O3S
    (E)-methyl 3-(phenylthio)-4-(3-oxo-6,6-dimethylcyclohexyl)but-2-enoate
    —— 4-((2-aminophenyl)thio)-3-fluorobenzonitrile 214483-59-7 C13H9FN2S
    4-((2-aminophenyl)thio)-3-fluorobenzonitrile
    —— 3-hydroxybutanedithioate de phenyle 137021-71-7 C10H12OS2
    3-hydroxybutanedithioate de phenyle
    —— O-[(1R,2S,4S)-5,5-dimethyl-7-oxo-2-bicyclo[2.2.2]octanyl] methylsulfanylmethanethioate 173914-09-5 C12H18O2S2
    O-[(1R,2S,4S)-5,5-dimethyl-7-oxo-2-bicyclo[2.2.2]octanyl] methylsulfanylmethanethioate
    —— 5-(6-chloropyrazin-2-yl)-2-methylthio[1,3,4]thiadiazole 717847-98-8 C7H5ClN4S2
    5-(6-chloropyrazin-2-yl)-2-methylthio[1,3,4]thiadiazole
    —— 6-ethyl-2-methylthio-4-oxo-3,4-dihydropyrimidine-5-carbonitrile 137447-05-3 C8H9N3OS
    6-ethyl-2-methylthio-4-oxo-3,4-dihydropyrimidine-5-carbonitrile
    —— ethyl N-[4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-yl]carbamodithioate 717122-90-2 C18H16N2S4
    ethyl N-[4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-yl]carbamodithioate
    —— 1-benzyl-7-(methylthio)-2H-pyrimido[4,5-d][1,3]oxazine-2,4(1H)-dione 686267-35-6 C14H11N3O3S
    1-benzyl-7-(methylthio)-2H-pyrimido[4,5-d][1,3]oxazine-2,4(1H)-dione
    —— 2-[(4-chlorophenyl)methylsulfanyl]-4-ethyl-6-oxo-1H-pyrimidine-5-carbonitrile 137447-06-4 C14H12ClN3OS
    2-[(4-chlorophenyl)methylsulfanyl]-4-ethyl-6-oxo-1H-pyrimidine-5-carbonitrile
    —— 2,3-dihydro-7-ethyl-5-oxothiazolo<3,2-a>pyrimidine-6-carbonitrile 137446-99-2 C9H9N3OS
    2,3-dihydro-7-ethyl-5-oxothiazolo<3,2-a>pyrimidine-6-carbonitrile
    —— 4,4-dimethyl-3-(phenylthio)cyclohex-2-en-1-one 147426-05-9 C14H16OS
    4,4-dimethyl-3-(phenylthio)cyclohex-2-en-1-one
    —— (Z)-methyl 3-(phenylthio)-4-(3-oxo-6,6-dimethylcyclohexyl)but-2-enoate 105090-10-6 C19H24O3S
    (Z)-methyl 3-(phenylthio)-4-(3-oxo-6,6-dimethylcyclohexyl)but-2-enoate
    —— (S)-3-(2,6-dimethylphenylthio)-4,4-dimethylcyclohexanone 1207593-85-8 C16H22OS
    (S)-3-(2,6-dimethylphenylthio)-4,4-dimethylcyclohexanone
    —— 3-(phenylthio)-5,6,4a,8a-tetrahydro-5,5-dimethylnaphthalene-1,8-(4H,7H)-dione 105090-18-4 C18H20O2S
    3-(phenylthio)-5,6,4a,8a-tetrahydro-5,5-dimethylnaphthalene-1,8-(4H,7H)-dione
    —— Toluene-4-sulfonate3-(3,6-dihydroxy-tricyclo[6.2.2.0<sup>2,7</sup>]dodeca-2,4,6,9-tetraen-4-ylsulfanyl)-1,4,5-trimethyl-4H-[1,2,4]triazol-1-ium; 92593-55-0 C7H7O3S*C17H20N3O2S
    Toluene-4-sulfonate3-(3,6-dihydroxy-tricyclo[6.2.2.0<sup>2,7</sup>]dodeca-2,4,6,9-tetraen-4-ylsulfanyl)-1,4,5-trimethyl-4H-[1,2,4]triazol-1-ium;
    —— 1,1-bis(ethylsulfanyl)-N-[4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-yl]methanimine 717122-92-4 C20H20N2S4
    1,1-bis(ethylsulfanyl)-N-[4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-yl]methanimine
    —— 3-(Phenylsulfanyl)thiophen-2(5H)-one 96490-43-6 C10H8OS2
    3-(Phenylsulfanyl)thiophen-2(5H)-one
    —— 2-(4-pyridylsulfanylmethyl)pyridine 83782-86-9 C11H10N2S
    2-(4-pyridylsulfanylmethyl)pyridine
    —— (2R)-2-[[2-amino-5-[(3-bromophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol 463953-96-0 C18H22BrN5OS2
    (2R)-2-[[2-amino-5-[(3-bromophenyl)methylsulfanyl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]amino]-4-methylpentan-1-ol
    —— 10,11-dihydro-10,10,11,11-tetramethyldibenzo<b,f><1,4,5>thiadisilepin 77599-01-0 C16H20SSi2
    10,11-dihydro-10,10,11,11-tetramethyldibenzo<b,f><1,4,5>thiadisilepin