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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-phenylthio-2-trimethylsilylheptane 85969-79-5 C16H28SSi
    2-phenylthio-2-trimethylsilylheptane
    —— 2-methylnonane-2-thiol 30174-58-4 C10H22S
    2-methylnonane-2-thiol
    —— 2-(2-aminophenylthio)-5-chlorobenzoic acid 81890-74-6 C13H10ClNO2S
    2-(2-aminophenylthio)-5-chlorobenzoic acid
    —— 1-phenylthio-2-nonanone 38793-75-8 C15H22OS
    1-phenylthio-2-nonanone
    —— 2-(2-{4-[3-(benzyloxy)phenylthio]-2-chlorophenyl}ethyl)-2-methylmalonic acid diethyl ester 676481-40-6 C29H31ClO5S
    2-(2-{4-[3-(benzyloxy)phenylthio]-2-chlorophenyl}ethyl)-2-methylmalonic acid diethyl ester
    —— 2,3-Bis-isobutylsulfanyl-propionaldehyde 132279-15-3 C11H22OS2
    2,3-Bis-isobutylsulfanyl-propionaldehyde
    —— 3-phenylthio-2-nonanone 1356922-69-4 C15H22OS
    3-phenylthio-2-nonanone
    —— 1-(3-chloro-1-bicyclo[1.1.1]pentanyl)-3-methylsulfonylbicyclo[1.1.1]pentane 127321-12-4 C11H15ClO2S
    1-(3-chloro-1-bicyclo[1.1.1]pentanyl)-3-methylsulfonylbicyclo[1.1.1]pentane
    —— (Z)-5-((pyridin-2-ylthio)methylene)thiophen-2(5H)-one 1415508-81-4 C10H7NOS2
    (Z)-5-((pyridin-2-ylthio)methylene)thiophen-2(5H)-one
    —— 1-chloro-3-methanesulfonylbicyclo[1.1.1]pentane 127321-11-3 C6H9ClO2S
    1-chloro-3-methanesulfonylbicyclo[1.1.1]pentane
    —— 2-Heptyl-2-methyl-1,3-dithian 68971-92-6 C12H24S2
    2-Heptyl-2-methyl-1,3-dithian
    —— (Z)-5-(((4-chlorophenyl)thio)methylene)thiophen-2(5H)-one 1415508-87-0 C11H7ClOS2
    (Z)-5-(((4-chlorophenyl)thio)methylene)thiophen-2(5H)-one
    —— (Z)-5-((pyrimidin-2-ylthio)methylene)thiophen-2(5H)-one 1415508-82-5 C9H6N2OS2
    (Z)-5-((pyrimidin-2-ylthio)methylene)thiophen-2(5H)-one
    —— 2-phenylsulfanyl-acetoacetic acid ethyl ester 27872-73-7 C12H14O3S
    2-phenylsulfanyl-acetoacetic acid ethyl ester
    —— 2-heptyl-2-methyl-1,3-dithiolane 147777-28-4 C11H22S2
    2-heptyl-2-methyl-1,3-dithiolane
    —— N-[2-(4-methoxyphenyl)sulfanyl-5-methyl-phenyl]-7-methyl-pyrido[2,3-d]pyrimidin-4-amine 1365920-98-4 C22H20N4OS
    N-[2-(4-methoxyphenyl)sulfanyl-5-methyl-phenyl]-7-methyl-pyrido[2,3-d]pyrimidin-4-amine
    —— 6-[2-Hydroxy-2-(4-methylsulfanyl-phenyl)-ethyl]-2-oxo-1,2-dihydro-pyridine-3-carbonitrile 88251-94-9 C15H14N2O2S
    6-[2-Hydroxy-2-(4-methylsulfanyl-phenyl)-ethyl]-2-oxo-1,2-dihydro-pyridine-3-carbonitrile
    —— (5-Methyl-2-phenylsulfanyl-phenyl)-(7-methyl-pyrido[2,3-d]pyrimidin-4-yl)-amine 944642-35-7 C21H18N4S
    (5-Methyl-2-phenylsulfanyl-phenyl)-(7-methyl-pyrido[2,3-d]pyrimidin-4-yl)-amine
    —— 4-[4-methyl-2-(7-methyl-pyrido[2,3-d]pyrimidin-4-ylamino)-phenylsulfanyl]-phenol 944503-59-7 C21H18N4OS
    4-[4-methyl-2-(7-methyl-pyrido[2,3-d]pyrimidin-4-ylamino)-phenylsulfanyl]-phenol
    —— N-[2-(4-fluorophenyl)sulfanyl-5-methyl-phenyl]-7-methyl-pyrido[2,3-d]pyrimidin-4-amine 1365921-03-4 C21H17FN4S
    N-[2-(4-fluorophenyl)sulfanyl-5-methyl-phenyl]-7-methyl-pyrido[2,3-d]pyrimidin-4-amine
    —— 2-(But-3-ynyl)-2-phenyl-1,3-dithiane 126594-06-7 C14H16S2
    2-(But-3-ynyl)-2-phenyl-1,3-dithiane
    —— (3'aS,4'S,7'aS)-7'a-methyl-4'-prop-2-enylspiro[1,3-dithiolane-2,5'-2,3,3a,4,6,7-hexahydroindene]-1'-one 854759-80-1 C15H22OS2
    (3'aS,4'S,7'aS)-7'a-methyl-4'-prop-2-enylspiro[1,3-dithiolane-2,5'-2,3,3a,4,6,7-hexahydroindene]-1'-one
    —— (aminoiminomethyl)thioacetic acid ethyl ester hydrochloride 60263-46-9 C5H10N2O2S*ClH
    (aminoiminomethyl)thioacetic acid ethyl ester hydrochloride
    —— 2-[2-(Phenylsulfanyl)ethoxy]ethan-1-ol 95108-89-7 C10H14O2S
    2-[2-(Phenylsulfanyl)ethoxy]ethan-1-ol
    —— 1-((1R,2R)-2-Methyl-1-oxo-1λ<sup>4</sup>-[1,3]dithian-2-yl)-ethanone 131309-71-2 C7H12O2S2
    1-((1R,2R)-2-Methyl-1-oxo-1λ<sup>4</sup>-[1,3]dithian-2-yl)-ethanone
    —— 3-Chloro-2-isobutylsulfanyl-propionaldehyde 132279-11-9 C7H13ClOS
    3-Chloro-2-isobutylsulfanyl-propionaldehyde
    —— 4-chloro-2-{[2-(methylsulfanyl)benzyl]amino}pyrimidine-5-carbonitrile 1214727-96-4 C13H11ClN4S
    4-chloro-2-{[2-(methylsulfanyl)benzyl]amino}pyrimidine-5-carbonitrile
    —— 4-<<3-(ethoxycarbonyl)phenyl>thio>phenol 128950-15-2 C15H14O3S
    4-<<3-(ethoxycarbonyl)phenyl>thio>phenol
    —— thiosulfurous acid <i>O</i>-ethyl ester <i>S</i>-propyl ester 17796-39-3 C5H12O2S2
    thiosulfurous acid <i>O</i>-ethyl ester <i>S</i>-propyl ester
    —— <i>O</i>,<i>S</i>-Diaethyl-thiosulfit 68261-74-5 C4H10O2S2
    <i>O</i>,<i>S</i>-Diaethyl-thiosulfit
    —— 3-(4-Chloro-phenylsulfanyl)-2-(2,2,2-trifluoro-acetylamino)-imidazo[1,2-a]pyridine-6-carboxylic acid methyl ester 209971-61-9 C17H11ClF3N3O3S
    3-(4-Chloro-phenylsulfanyl)-2-(2,2,2-trifluoro-acetylamino)-imidazo[1,2-a]pyridine-6-carboxylic acid methyl ester
    —— Methyl 3-(4-fluorophenyl)sulfanyl-2-[(2,2,2-trifluoroacetyl)amino]imidazo[1,2-a]pyridine-6-carboxylate 209971-62-0 C17H11F4N3O3S
    Methyl 3-(4-fluorophenyl)sulfanyl-2-[(2,2,2-trifluoroacetyl)amino]imidazo[1,2-a]pyridine-6-carboxylate
    —— 3-[3-(2-Carboxy-ethyl)-4-(6-phenyl-hexyloxy)-phenylsulfanyl]-benzoic acid 128950-03-8 C28H30O5S
    3-[3-(2-Carboxy-ethyl)-4-(6-phenyl-hexyloxy)-phenylsulfanyl]-benzoic acid
    —— 3-cyano-2-(3-hydroxy-1H-pyrazol-5-ylmethylthio)-4,6-dimethylpyridine 750593-45-4 C12H12N4OS
    3-cyano-2-(3-hydroxy-1H-pyrazol-5-ylmethylthio)-4,6-dimethylpyridine
    —— S-allyl O-ethyl carbonothioate 116423-17-7 C6H10O2S
    S-allyl O-ethyl carbonothioate
    —— O-methyl S-phenyl carbonodithioate 6047-46-7 C8H8OS2
    O-methyl S-phenyl carbonodithioate
    —— N-<1,2,3,4-tetrahydro-8-methoxy-5-(phenylthio)-2-naphthalenyl>acetamide 80270-83-3 C19H21NO2S
    N-<1,2,3,4-tetrahydro-8-methoxy-5-(phenylthio)-2-naphthalenyl>acetamide
    —— ethyl 2-{6-amino-3,5-dicyano-4-(2-thiophene)pyridyl}thioacetate 136633-83-5 C15H12N4O2S2
    ethyl 2-{6-amino-3,5-dicyano-4-(2-thiophene)pyridyl}thioacetate
    —— Propan-2-yl 4-[(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl]-3-oxobutanoate 327167-61-3 C16H20N2O3S
    Propan-2-yl 4-[(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl]-3-oxobutanoate
    —— 2-(Benzofuran-5-ylthio)-1-(4-methoxybenzyl)-1H-imidazo[4,5-c]pyridin-4-amine 1061316-74-2 C22H18N4O2S
    2-(Benzofuran-5-ylthio)-1-(4-methoxybenzyl)-1H-imidazo[4,5-c]pyridin-4-amine
    —— 2,5-bis-phenylsulfanyl-[1,3,4]thiadiazole 21398-13-0 C14H10N2S3
    2,5-bis-phenylsulfanyl-[1,3,4]thiadiazole
    —— 2,4,6-Trimethyl-dithio-benzoesaeure-phenylester 20876-79-3 C16H16S2
    2,4,6-Trimethyl-dithio-benzoesaeure-phenylester
    —— S-Methyl-S'-phenyl-trithiocarbonat-S,S-dioxid 53271-53-7 C8H8O2S3
    S-Methyl-S'-phenyl-trithiocarbonat-S,S-dioxid
    —— 4-(3,5-Dibromobenzylthio)Aniline 1314034-15-5 C13H11Br2NS
    4-(3,5-Dibromobenzylthio)Aniline
    —— phenyl N-phenyl-N-methyldithiocarbamate 21168-04-7 C14H13NS2
    phenyl N-phenyl-N-methyldithiocarbamate
    —— ethyl 2-phenylsulphanylthiazole-5-carboxylate 56355-60-3 C12H11NO2S2
    ethyl 2-phenylsulphanylthiazole-5-carboxylate
    —— 1,6-anhydro-2,4-dideoxy-4-methyl-2-(phenylthiomethyl)-β-D-glucopyranose 100757-48-0 C14H18O3S
    1,6-anhydro-2,4-dideoxy-4-methyl-2-(phenylthiomethyl)-β-D-glucopyranose
    —— N,N-dimethyl-2-(6'-methyl-2'-phenylpyrimidin-4'-ylthio)ethylamine 90185-66-3 C15H19N3S
    N,N-dimethyl-2-(6'-methyl-2'-phenylpyrimidin-4'-ylthio)ethylamine
    —— N,N-Diethyl-α,α-dichlor-thioacetamid 89582-80-9 C6H11Cl2NS
    N,N-Diethyl-α,α-dichlor-thioacetamid
    —— 3-amino-6-phenylthioimidazo [1,2-a] pyridine 64064-73-9 C13H11N3S
    3-amino-6-phenylthioimidazo [1,2-a] pyridine