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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N,N-dimethyl-2-(3-hydroxyphenylthio)-4-methoxybenzylamine 134987-21-6 C16H19NO2S
    N,N-dimethyl-2-(3-hydroxyphenylthio)-4-methoxybenzylamine
    —— 5-methoxy-17-thia-2,12,13,15-tetrazatetracyclo[8.7.0.03,8.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaen-11-ol 144918-81-0 C13H10N4O2S
    5-methoxy-17-thia-2,12,13,15-tetrazatetracyclo[8.7.0.03,8.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaen-11-ol
    —— 11-ethoxy-5-methoxy-17-thia-2,12,13,15-tetrazatetracyclo[8.7.0.03,8.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaene 144918-87-6 C15H14N4O2S
    11-ethoxy-5-methoxy-17-thia-2,12,13,15-tetrazatetracyclo[8.7.0.03,8.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaene
    —— 7-amino-2-(furan-3-yl)-5-(methylsulfanyl)oxazolo[5,4-d]pyrimidine 884861-23-8 C10H8N4O2S
    7-amino-2-(furan-3-yl)-5-(methylsulfanyl)oxazolo[5,4-d]pyrimidine
    —— 7-azido-2-(furan-3-yl)-5-(methylsulfanyl)oxazolo[5,4-d]pyrimidine 884861-21-6 C10H6N6O2S
    7-azido-2-(furan-3-yl)-5-(methylsulfanyl)oxazolo[5,4-d]pyrimidine
    —— 4-methoxy-17-thia-2,12,13,15-tetrazatetracyclo[8.7.0.03,8.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaen-11-ol 144918-82-1 C13H10N4O2S
    4-methoxy-17-thia-2,12,13,15-tetrazatetracyclo[8.7.0.03,8.012,16]heptadeca-1(10),2,4,6,8,13,15-heptaen-11-ol
    —— S-<1-Methyl-pentyl>-thiophenol 13921-10-3 C12H18S
    S-<1-Methyl-pentyl>-thiophenol
    —— 3-bromo-4-methanesulfonyl-butan-2-ol 59059-88-0 C5H11BrO3S
    3-bromo-4-methanesulfonyl-butan-2-ol
    —— [(1-ethylpentyl)thio]benzene 13921-15-8 C13H20S
    [(1-ethylpentyl)thio]benzene
    —— Propyl carbonotrithioate 68060-07-1 C4H7S3-
    Propyl carbonotrithioate
    —— 2-(3'-Furyl)-2-<2-(tetrahydropyran-2-yloxy)ethyl>-1,3-dithiane 132912-31-3 C15H22O3S2
    2-(3'-Furyl)-2-<2-(tetrahydropyran-2-yloxy)ethyl>-1,3-dithiane
    —— 1,3,5-tris(4-pyridylsulfanylmethyl)-2,4,6-trimethylbenzene 588691-60-5 C27H27N3S3
    1,3,5-tris(4-pyridylsulfanylmethyl)-2,4,6-trimethylbenzene
    —— 5-Fluoro-3-phenylsulfanylmethyl-1H-pyrimidine-2,4-dione 90162-97-3 C11H9FN2O2S
    5-Fluoro-3-phenylsulfanylmethyl-1H-pyrimidine-2,4-dione
    —— tert-Butyl(dimethyl){[2-(phenylsulfanyl)furan-3-yl]methoxy}silane 89861-10-9 C17H24O2SSi
    tert-Butyl(dimethyl){[2-(phenylsulfanyl)furan-3-yl]methoxy}silane
    —— (3-Furyl)(phenylthio)methane 153498-17-0 C11H10OS
    (3-Furyl)(phenylthio)methane
    —— 1,1-bis(phenylsulfanyl)ethylbenzene 3462-50-8 C20H18S2
    1,1-bis(phenylsulfanyl)ethylbenzene
    —— S-methyl 2,2-bis(methylsulfanyl)-2-phenylethanethioate 195305-56-7 C11H14OS3
    S-methyl 2,2-bis(methylsulfanyl)-2-phenylethanethioate
    —— 4-tert-butyldimethylsilyloxymethyl-5-(methylthio)furan-2-yldimethylsilylmethanol 1258381-54-2 C15H30O3SSi2
    4-tert-butyldimethylsilyloxymethyl-5-(methylthio)furan-2-yldimethylsilylmethanol
    —— 5,7-Dimethyl-2-adamantanethione 122521-92-0 C12H18S
    5,7-Dimethyl-2-adamantanethione
    —— (Z,3R)-3-tert-butyldimethylsiloxy-1-nitro-3-phenyl-1-phenylsulfanylpropene 169137-45-5 C21H27NO3SSi
    (Z,3R)-3-tert-butyldimethylsiloxy-1-nitro-3-phenyl-1-phenylsulfanylpropene
    —— 3-(3-chlorophenyl)-2-methylthio-4(3H)-pyrimidinone 89069-23-8 C11H9ClN2OS
    3-(3-chlorophenyl)-2-methylthio-4(3H)-pyrimidinone
    —— 2-Phenylthio-3-methyl-cyclopentanon 63546-65-6 C12H14OS
    2-Phenylthio-3-methyl-cyclopentanon
    —— t-Butyl N-Heptanoyl-2-(4-(2-aminoethyl)phenylthio)-2-methylpropionate 247923-32-6 C23H37NO3S
    t-Butyl N-Heptanoyl-2-(4-(2-aminoethyl)phenylthio)-2-methylpropionate
    —— 4-Cyclohexylthio-1-butanol 1962-46-5 C10H20OS
    4-Cyclohexylthio-1-butanol
    —— 4-((4-bromophenyl)thio)butan-1-ol 14703-93-6 C10H13BrOS
    4-((4-bromophenyl)thio)butan-1-ol
    —— 2-ethyl-2,3-dihydro-5-methyl-1,4-dithiin 61947-23-7 C7H12S2
    2-ethyl-2,3-dihydro-5-methyl-1,4-dithiin
    —— (1-Dichloromethylene-butylsulfanyl)-benzene 88649-73-4 C11H12Cl2S
    (1-Dichloromethylene-butylsulfanyl)-benzene
    —— 4,4-Dibutyl-1,2,4-dithiagermolane 87993-96-2 C10H22GeS2
    4,4-Dibutyl-1,2,4-dithiagermolane
    —— 4-((2-Hydroxypropyl)thio)-2-methylpyrimidin-5-ol 91036-39-4 C8H12N2O2S
    4-((2-Hydroxypropyl)thio)-2-methylpyrimidin-5-ol
    —— 4-oxo-3,5-dimethyl-2,8,9,10-tetrathiabicyclo<5.3.0>dec-1(7)-ene-9-thione 162190-32-1 C8H8OS5
    4-oxo-3,5-dimethyl-2,8,9,10-tetrathiabicyclo<5.3.0>dec-1(7)-ene-9-thione
    —— 3-methylmercapto-5,6-bis[4-ethylphenyl]-1,2,4-triazine 88300-11-2 C20H21N3S
    3-methylmercapto-5,6-bis[4-ethylphenyl]-1,2,4-triazine
    —— 4,5-di(2,3,5,6-tetrafluorobenzylthio)-1,3-dithiole-2-thione 571970-60-0 C17H6F8S5
    4,5-di(2,3,5,6-tetrafluorobenzylthio)-1,3-dithiole-2-thione
    —— 3-(2,2-dimethoxyethylthio)phenol 71681-95-3 C10H14O3S
    3-(2,2-dimethoxyethylthio)phenol
    —— 4-oxo-3,5-diethyl-2,8,9,10-tetrathiabicyclo[5.3.0]dec-1(7)-ene-9-thione 162190-33-2 C10H12OS5
    4-oxo-3,5-diethyl-2,8,9,10-tetrathiabicyclo[5.3.0]dec-1(7)-ene-9-thione
    —— 4-methyl-3-(methylsulfanyl)-4,5-dihydro-1H-1,2,4-triazol-5-one 53065-38-6 C4H7N3OS
    4-methyl-3-(methylsulfanyl)-4,5-dihydro-1H-1,2,4-triazol-5-one
    —— 1-cyclohexylamino-carbonyl-3-methylthio-4-methyl-1,2,4-triazolin-5-one 118876-26-9 C11H18N4O2S
    1-cyclohexylamino-carbonyl-3-methylthio-4-methyl-1,2,4-triazolin-5-one
    —— 2-(Phenylsulfanyl)cyclohexan-1-amine 854728-39-5 C12H17NS
    2-(Phenylsulfanyl)cyclohexan-1-amine
    —— N-cyclohexyl-2-phenylthioacetamide 71433-02-8 C14H19NOS
    N-cyclohexyl-2-phenylthioacetamide
    —— ethyl {3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}acetate 735274-09-6 C27H36N2O3S
    ethyl {3-[4-(1-butyl-3-cyclohexylureido)phenylsulphanyl]phenyl}acetate
    —— Lithium 1,3-bis(phenylsulfanyl)cyclohex-2-en-1-ide 101185-20-0 C18H17LiS2
    Lithium 1,3-bis(phenylsulfanyl)cyclohex-2-en-1-ide
    —— 4-(Phenylsulfanyl)-4-[(propan-2-yl)oxy]butane-1,2,3-triol 91927-49-0 C13H20O4S
    4-(Phenylsulfanyl)-4-[(propan-2-yl)oxy]butane-1,2,3-triol
    —— 3-deoxy-[1,1-bis(ethylthio)]-5-O-pivaloyl-α-D-xylose 175445-21-3 C14H28O4S2
    3-deoxy-[1,1-bis(ethylthio)]-5-O-pivaloyl-α-D-xylose
    —— 1-methylethyl isopentyl disulfide 72437-50-4 C8H18S2
    1-methylethyl isopentyl disulfide
    —— O-butyl O-ethyl dithioimidodicarbonate 104709-68-4 C8H15NO2S2
    O-butyl O-ethyl dithioimidodicarbonate
    —— 4-Thiahepta-1,2-dien-5-yne 106113-42-2 C6H6S
    4-Thiahepta-1,2-dien-5-yne
    —— bis((4-fluorophenyl)thio)methane 370-82-1 C13H10F2S2
    bis((4-fluorophenyl)thio)methane
    —— bis(thiophen-2-ylthio)methane 131673-97-7 C9H8S4
    bis(thiophen-2-ylthio)methane
    —— 4-(methyloxy)-2-(methylthio)-6-(4-pyridinyl)pyrimidine 863328-29-4 C11H11N3OS
    4-(methyloxy)-2-(methylthio)-6-(4-pyridinyl)pyrimidine
    —— 2,4,4-trimethylhept-6-ene-3-thione S-oxide 109000-84-2 C10H18OS
    2,4,4-trimethylhept-6-ene-3-thione S-oxide
    —— <i>sec</i>-butyl-isopropyl-disulfane 67421-86-7 C7H16S2
    <i>sec</i>-butyl-isopropyl-disulfane