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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [5-(4-Azocan-1-yl-but-2-ynylsulfanyl)-[1,3,4]thiadiazol-2-yl]-carbamic acid allyl ester 141992-76-9 C17H24N4O2S2
    [5-(4-Azocan-1-yl-but-2-ynylsulfanyl)-[1,3,4]thiadiazol-2-yl]-carbamic acid allyl ester
    —— [5-(4-Azocan-1-yl-but-2-ynylsulfanyl)-[1,3,4]thiadiazol-2-yl]-carbamic acid ethyl ester 141992-71-4 C16H24N4O2S2
    [5-(4-Azocan-1-yl-but-2-ynylsulfanyl)-[1,3,4]thiadiazol-2-yl]-carbamic acid ethyl ester
    —— N,N-Dimethylthiocarbamoylisothiocyanat 30013-32-2 C4H6N2S2
    N,N-Dimethylthiocarbamoylisothiocyanat
    —— trichloroethoxycarbonylisothiocyanate 56539-09-4 C4H2Cl3NO2S
    trichloroethoxycarbonylisothiocyanate
    —— 5-butyl-3-[1-hydroxy-4,4-bis(phenylsulfanyl)butyl]-3-(phenylselanyl)oxolan-2-one 1432519-03-3 C30H34O3S2Se
    5-butyl-3-[1-hydroxy-4,4-bis(phenylsulfanyl)butyl]-3-(phenylselanyl)oxolan-2-one
    —— bis-(propane-2-sulfonyl)-methane 6330-39-8 C7H16O4S2
    bis-(propane-2-sulfonyl)-methane
    —— 1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate 1432519-06-6 C32H36O4S2Se
    1-[5-butyl-2-oxo-3-(phenylselanyl)oxolan-3-yl]-4,4-bis-(phenylsulfanyl)butyl acetate
    —— 2-(p-tolylthio)benzaldehyde 62351-50-2 C14H12OS
    2-(p-tolylthio)benzaldehyde
    —— 4-Pyridyl-n-dodecylthioether 10351-15-2 C17H29NS
    4-Pyridyl-n-dodecylthioether
    —— 3,6,10,13-Tetrathiapentadecane-1,15-dithiol 88458-57-5 C11H24S6
    3,6,10,13-Tetrathiapentadecane-1,15-dithiol
    —— N,N'-(methylethylene)-2,2'-thiodibenzamide 1393085-58-9 C17H16N2O2S
    N,N'-(methylethylene)-2,2'-thiodibenzamide
    —— 2-[(4-bromophenyl)sulfanyl]benzaldehyde 139009-34-0 C13H9BrOS
    2-[(4-bromophenyl)sulfanyl]benzaldehyde
    —— 2-((4-fluorophenyl)thio)benzaldehyde 643763-14-8 C13H9FOS
    2-((4-fluorophenyl)thio)benzaldehyde
    —— (naphthalen-3-yl)(naphthalen-4-yl)sulfane 62393-34-4 C20H14S
    (naphthalen-3-yl)(naphthalen-4-yl)sulfane
    —— ethyl 2-methyl-2-(4-pyridylsulfanyl)propanoate 125305-74-0 C11H15NO2S
    ethyl 2-methyl-2-(4-pyridylsulfanyl)propanoate
    —— 2-Methyl-but-1-ene-1-thione 131136-78-2 C5H8S
    2-Methyl-but-1-ene-1-thione
    —— 1-Amino-2-methylbutane-2-thiol--hydrogen chloride (1/1) 32047-54-4 C5H14ClNS
    1-Amino-2-methylbutane-2-thiol--hydrogen chloride (1/1)
    —— ω-(Ethylthio)-1-pentanthiol 36044-04-9 C7H16S2
    ω-(Ethylthio)-1-pentanthiol
    —— 1,2-Diphenyl-4-γ-phenylthiopropyl-pyrazolidin-3,5-dion 58813-42-6 C24H22N2O2S
    1,2-Diphenyl-4-γ-phenylthiopropyl-pyrazolidin-3,5-dion
    —— N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)cyclobutanecarboxamide 820975-33-5 C21H19F2NOS2
    N-(2-(5-fluoro-2-(4-fluorophenylthio)benzo[b]thiophen-3-yl)ethyl)cyclobutanecarboxamide
    —— O-(1-methoxy-2,2-dimethylvinyl) S-propyl dithiocarbonate 123311-26-2 C9H16O2S2
    O-(1-methoxy-2,2-dimethylvinyl) S-propyl dithiocarbonate
    —— 4-[3-[4-(2-Methylimidazol-1-ylmethyl)phenylthio]phenyl]-3,4,5,6-tetrahydro-2H-pyran-4carboxylic acid 179420-58-7 C23H24N2O3S
    4-[3-[4-(2-Methylimidazol-1-ylmethyl)phenylthio]phenyl]-3,4,5,6-tetrahydro-2H-pyran-4carboxylic acid
    —— 4-Methyl-2-(phenylsulfanyl)pentanal 127941-11-1 C12H16OS
    4-Methyl-2-(phenylsulfanyl)pentanal
    —— 2,6-Dichloro-3-bromo-5-benzylthiopyridine 129836-62-0 C12H8BrCl2NS
    2,6-Dichloro-3-bromo-5-benzylthiopyridine
    —— 1-(2-Methyl-[1,3]dithiolan-2-yl)-butan-1-one 61784-42-7 C8H14OS2
    1-(2-Methyl-[1,3]dithiolan-2-yl)-butan-1-one
    —— 6-methyl-2-(phenylthio)tetrahydropyran 193539-57-0 C12H16OS
    6-methyl-2-(phenylthio)tetrahydropyran
    —— [((E)-Hex-3-enyl)oxy]-phenylsulfanyl-acetic acid ethyl ester 134277-88-6 C16H22O3S
    [((E)-Hex-3-enyl)oxy]-phenylsulfanyl-acetic acid ethyl ester
    —— methyl 2-methyl-1,3-dithiolane-2-carboxylate 61784-35-8 C6H10O2S2
    methyl 2-methyl-1,3-dithiolane-2-carboxylate
    —— 5-<(E)-1-(Phenylthio)-1-propenyl>-1-pyrroline 128845-07-8 C13H15NS
    5-<(E)-1-(Phenylthio)-1-propenyl>-1-pyrroline
    —— N,N'-(hexamethylene)bisdithiocarbamic acid 45131-67-7 C8H16N2S4
    N,N'-(hexamethylene)bisdithiocarbamic acid
    —— N,2-dimethyl-N-hydroxy-1-propanethioamide 105183-87-7 C5H11NOS
    N,2-dimethyl-N-hydroxy-1-propanethioamide
    —— hexamethylenedithiourea 10017-50-2 C8H18N4S2
    hexamethylenedithiourea
    —— 2-(2,4-dichloro-benzenesulfonylamino)-N-methoxy-N-methyl-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-isonicotinamide 882500-08-5 C25H26Cl2N4O6S3
    2-(2,4-dichloro-benzenesulfonylamino)-N-methoxy-N-methyl-5-[4-(piperidine-1-sulfonyl)-phenylsulfanyl]-isonicotinamide
    —— (3'S,4S)-3-[3'-hydroxy-4-(2-methyl-1,3-dithianyl)]butanoate-4-isopropyloxazolidin-2-one 236094-48-7 C15H25NO4S2
    (3'S,4S)-3-[3'-hydroxy-4-(2-methyl-1,3-dithianyl)]butanoate-4-isopropyloxazolidin-2-one
    —— (3'R,4S)-3-[3'-hydroxy-4-(2-methyl-1,3-dithianyl)]butanoate-4-isopropylooxazolidin-2-one 236094-47-6 C15H25NO4S2
    (3'R,4S)-3-[3'-hydroxy-4-(2-methyl-1,3-dithianyl)]butanoate-4-isopropylooxazolidin-2-one
    —— N-<2-Phenylmercapto-1-methyl-aethyl>-acetamid 91281-29-7 C11H15NOS
    N-<2-Phenylmercapto-1-methyl-aethyl>-acetamid
    —— 2-(Methylsulfinylmethylsulfanyl)-5-phenyl-1,3,4-thiadiazole 154220-74-3 C10H10N2OS3
    2-(Methylsulfinylmethylsulfanyl)-5-phenyl-1,3,4-thiadiazole
    —— (4S)-3-<(2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanyl-1-oxoheptyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one 143879-17-8 C20H29NO4S
    (4S)-3-<(2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanyl-1-oxoheptyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one
    —— trans-3-Ethyl-2,4,5-trithia-6-octene 2-S-oxide 197566-05-5 C7H14OS3
    trans-3-Ethyl-2,4,5-trithia-6-octene 2-S-oxide
    —— Imidodi(thiokohlensaeure-O-ethylester) 77588-28-4 C6H11NO2S2
    Imidodi(thiokohlensaeure-O-ethylester)
    —— (4S)-3-<(2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanyl-1-oxohexyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one 143879-16-7 C19H27NO4S
    (4S)-3-<(2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanyl-1-oxohexyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one
    —— (2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanylhexan-1-ol 182824-31-3 C13H20O2S
    (2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanylhexan-1-ol
    —— (4S)-3-<(2R,3S,4R)-3-Hydroxy-2,5-dimethyl-4-phenylsulfanyl-1-oxohexyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one 143879-18-9 C20H29NO4S
    (4S)-3-<(2R,3S,4R)-3-Hydroxy-2,5-dimethyl-4-phenylsulfanyl-1-oxohexyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one
    —— (2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanylheptan-1-ol 143879-19-0 C14H22O2S
    (2R,3S,4R)-3-Hydroxy-2-methyl-4-phenylsulfanylheptan-1-ol
    —— (4S)-3-<(2R,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclododecyl)propyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one 154868-38-9 C28H43NO4S
    (4S)-3-<(2R,3S)-3-hydroxy-2-methyl-1-oxo-3-(1-phenylsulfanylcyclododecyl)propyl>-4-(1-methylethyl)-1,3-oxazolidin-2-one
    —— Ethyl {[(2-methoxyethoxy)carbonyl]sulfanyl}acetate 135742-69-7 C8H14O5S
    Ethyl {[(2-methoxyethoxy)carbonyl]sulfanyl}acetate
    —— (3R)-3-mercaptopentan-1-ol 350611-23-3 C5H12OS
    (3R)-3-mercaptopentan-1-ol
    —— 1-[5-(2-methyl-1,3-benzodithiol-2-yl)-1H-pyrrol-3-yl]ethanone 147089-10-9 C14H13NOS2
    1-[5-(2-methyl-1,3-benzodithiol-2-yl)-1H-pyrrol-3-yl]ethanone
    —— 2-(benzylthio)pyrimidine-4,5,6-triamine 95493-97-3 C11H13N5S
    2-(benzylthio)pyrimidine-4,5,6-triamine
    —— bis-(Heptadecafluorooctanesulfonyl)methane 29214-34-4 C17H2F34O4S2
    bis-(Heptadecafluorooctanesulfonyl)methane