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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (S)-5-((2-chlorophenylthio)methyl)pyrrolidin-2-one 1448621-29-1 C11H12ClNOS
    (S)-5-((2-chlorophenylthio)methyl)pyrrolidin-2-one
    —— 3,3-Bis-(4-chloro-phenylsulfanyl)-3-phenyl-propionic acid ethyl ester 128671-24-9 C23H20Cl2O2S2
    3,3-Bis-(4-chloro-phenylsulfanyl)-3-phenyl-propionic acid ethyl ester
    —— 2,3-Dihydro-6-ethylthieno<2,3-c>furan 100103-55-7 C8H10OS
    2,3-Dihydro-6-ethylthieno<2,3-c>furan
    —— (1R,4S,5S,9R)-6-tert-butylsulfonyl-1-[(1R)-1-hydroxy-2,2-bis(phenylsulfanyl)ethyl]-4-methoxy-2-oxa-6-azabicyclo[3.3.1]nonan-9-ol 921203-12-5 C26H35NO6S3
    (1R,4S,5S,9R)-6-tert-butylsulfonyl-1-[(1R)-1-hydroxy-2,2-bis(phenylsulfanyl)ethyl]-4-methoxy-2-oxa-6-azabicyclo[3.3.1]nonan-9-ol
    —— 2,3-Dihydro-4,6-dimethylthieno<2,3-c>furan 78798-06-8 C8H10OS
    2,3-Dihydro-4,6-dimethylthieno<2,3-c>furan
    —— 2,3-Dihydro-4-methylthieno<2,3-c>furan 100103-52-4 C7H8OS
    2,3-Dihydro-4-methylthieno<2,3-c>furan
    —— 6-amino-3-carbamoyl-5-cyano-2-methylthio-3,4-dihydrospirocyclohexane-4-piperidine 402954-48-7 C13H18N4OS
    6-amino-3-carbamoyl-5-cyano-2-methylthio-3,4-dihydrospirocyclohexane-4-piperidine
    —— 2-Methyl-2-(4-pyridinylthio)propionyl chloride 125305-76-2 C9H10ClNOS
    2-Methyl-2-(4-pyridinylthio)propionyl chloride
    —— 2-bromo-3-{[(2-bromothien-3-ylthio)methyl]thio}thiophene 777097-39-9 C9H6Br2S4
    2-bromo-3-{[(2-bromothien-3-ylthio)methyl]thio}thiophene
    —— Methyl 2-[3-cyano-4-(furan-2-yl)-5,6-dimethylpyridin-2-yl]sulfanylacetate 94639-43-7 C15H14N2O3S
    Methyl 2-[3-cyano-4-(furan-2-yl)-5,6-dimethylpyridin-2-yl]sulfanylacetate
    —— 4-<Bis(phenylthio)methyl>pyridine 123195-61-9 C18H15NS2
    4-<Bis(phenylthio)methyl>pyridine
    —— ethyl 2-[[3-cyano-4-(furan-2-yl)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]sulfanyl]acetate 94639-48-2 C17H16N2O3S
    ethyl 2-[[3-cyano-4-(furan-2-yl)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]sulfanyl]acetate
    —— methyl (phenyl 4,5-N,O-carbonylamino-5,7-N,O-DTBS-8,9-O-DTBS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate 1190291-13-4 C33H53NO8SSi2
    methyl (phenyl 4,5-N,O-carbonylamino-5,7-N,O-DTBS-8,9-O-DTBS-3,5-dideoxy-2-thio-D-glycero-α-D-galacto-2-nonulopyranosid)onate
    —— methyl 2-[[3-cyano-4-(furan-2-yl)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]sulfanyl]acetate 94639-47-1 C16H14N2O3S
    methyl 2-[[3-cyano-4-(furan-2-yl)-6,7-dihydro-5H-cyclopenta[b]pyridin-2-yl]sulfanyl]acetate
    —— 5-(o-tolylsulfanylmethyl)-furan-2-carbaldehyde 685904-04-5 C13H12O2S
    5-(o-tolylsulfanylmethyl)-furan-2-carbaldehyde
    —— Ethyl 2-[3-cyano-4-(furan-2-yl)-6-methylpyridin-2-yl]sulfanylacetate 94639-78-8 C15H14N2O3S
    Ethyl 2-[3-cyano-4-(furan-2-yl)-6-methylpyridin-2-yl]sulfanylacetate
    —— Methyl 2-[3-cyano-4-(furan-2-yl)-6-methylpyridin-2-yl]sulfanylacetate 94639-77-7 C14H12N2O3S
    Methyl 2-[3-cyano-4-(furan-2-yl)-6-methylpyridin-2-yl]sulfanylacetate
    —— S-{2-[(4-Methylphenyl)sulfanyl]ethyl} dimethylcarbamothioate 62988-35-6 C12H17NOS2
    S-{2-[(4-Methylphenyl)sulfanyl]ethyl} dimethylcarbamothioate
    —— 2-(2-aminoethylthio)-6-amino-4-(furan-2-yl)pyridine-3,5-dicarbonitrile 918901-41-4 C13H11N5OS
    2-(2-aminoethylthio)-6-amino-4-(furan-2-yl)pyridine-3,5-dicarbonitrile
    —— 2-(4-Chloro-phenyl)-4-p-tolylsulfanyl-thiazole 130775-35-8 C16H12ClNS2
    2-(4-Chloro-phenyl)-4-p-tolylsulfanyl-thiazole
    —— 2-amino-4-(furan-2-yl)-6-(propylthio)pyridine-3,5-dicarbonitrile 918901-51-6 C14H12N4OS
    2-amino-4-(furan-2-yl)-6-(propylthio)pyridine-3,5-dicarbonitrile
    —— 6-amino-2-(o-aminophenylthio)-3,5-dicyano-4-(2-furyl)pyridine 128453-32-7 C17H11N5OS
    6-amino-2-(o-aminophenylthio)-3,5-dicyano-4-(2-furyl)pyridine
    —— 2-(4-Chloro-phenyl)-4-(4-chloro-phenylsulfanyl)-thiazole 130775-32-5 C15H9Cl2NS2
    2-(4-Chloro-phenyl)-4-(4-chloro-phenylsulfanyl)-thiazole
    —— O-methyl N-amino-N-methylcarbamothioate 173673-29-5 C3H8N2OS
    O-methyl N-amino-N-methylcarbamothioate
    —— (diethylcarbamoylamino) N,N-diethylcarbamodithioate 138905-98-3 C10H21N3OS2
    (diethylcarbamoylamino) N,N-diethylcarbamodithioate
    —— 6-amino-2-(2-bromoethylthio)-4(3H)-pyrimidinone 127490-24-8 C6H8BrN3OS
    6-amino-2-(2-bromoethylthio)-4(3H)-pyrimidinone
    —— 2-<Bis(methylthio)methyl>cyclohept-1-one 128307-48-2 C10H18OS2
    2-<Bis(methylthio)methyl>cyclohept-1-one
    —— 4-chloro-2-fluoro-5-(2-tetrahydropyranyl)thiophenylisothiocyanate 121028-25-9 C12H11ClFNOS2
    4-chloro-2-fluoro-5-(2-tetrahydropyranyl)thiophenylisothiocyanate
    —— ethyl (nonafluorobutanesulfonyl)acetate 161123-65-5 C8H7F9O4S
    ethyl (nonafluorobutanesulfonyl)acetate
    —— 3-bromo-1-(methylthio)-5,6,7,8-tetrahydroisoquinoline 128736-36-7 C10H12BrNS
    3-bromo-1-(methylthio)-5,6,7,8-tetrahydroisoquinoline
    —— 2-(4-methoxyphenylthio)-6-methylbenzo[d]thiazole 1189350-88-6 C15H13NOS2
    2-(4-methoxyphenylthio)-6-methylbenzo[d]thiazole
    —— 2-(7-Acetyl-4-cyano-6-hydroxy-1,6-dimethyl-8-phenyl-5,6,7,8-tetrahydro-isoquinolin-3-ylsulfanyl)-acetamide 180985-11-9 C22H23N3O3S
    2-(7-Acetyl-4-cyano-6-hydroxy-1,6-dimethyl-8-phenyl-5,6,7,8-tetrahydro-isoquinolin-3-ylsulfanyl)-acetamide
    —— methyl (Z)-7-[(1R,2R,3R)-3-[tert-butyl(dimethyl)silyl]oxy-2-(methoxy-phenylsulfanyl-trimethylsilylmethyl)-5-oxocyclopentyl]hept-5-enoate 143261-28-3 C30H50O5SSi2
    methyl (Z)-7-[(1R,2R,3R)-3-[tert-butyl(dimethyl)silyl]oxy-2-(methoxy-phenylsulfanyl-trimethylsilylmethyl)-5-oxocyclopentyl]hept-5-enoate
    —— 2-(2-nitrophenylthio)-6-methylbenzo[d]thiazole 1189350-89-7 C14H10N2O2S2
    2-(2-nitrophenylthio)-6-methylbenzo[d]thiazole
    —— Diethylcarbamoyl-isothiocyanat 16011-85-1 C6H10N2OS
    Diethylcarbamoyl-isothiocyanat
    —— 4-methylcyclohexanethiol 60260-87-9 C7H14S
    4-methylcyclohexanethiol
    —— 2-(6-amino-8-(6-bromobenzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)ethyl methanesulfonate 1012059-32-3 C15H14BrN5O5S2
    2-(6-amino-8-(6-bromobenzo[d][1,3]dioxol-5-ylthio)-9H-purin-9-yl)ethyl methanesulfonate
    —— dimethyl 2,3-dihydro-5-phenylthio-1H-pyrrolizine-6,7-dicarboxylate 129503-31-7 C17H17NO4S
    dimethyl 2,3-dihydro-5-phenylthio-1H-pyrrolizine-6,7-dicarboxylate
    —— 2-[3-(4-[2-(2,2,2-trifluoroethyl)guanidino]pyrimid-2-ylthio)propylthio]acetamide 84544-67-2 C12H17F3N6OS2
    2-[3-(4-[2-(2,2,2-trifluoroethyl)guanidino]pyrimid-2-ylthio)propylthio]acetamide
    —— 6-(2-aminophenyl-1-thio)-9H-(2-tetrahydropyranyl)purine 128033-41-0 C16H17N5OS
    6-(2-aminophenyl-1-thio)-9H-(2-tetrahydropyranyl)purine
    —— 3-[4-(2-[2,2,2-trifluoroethyl]guanidino)pyrimid-2-ylthio]propanethiol hydrogen maleate 84544-66-1 C4H4O4*C10H14F3N5S2
    3-[4-(2-[2,2,2-trifluoroethyl]guanidino)pyrimid-2-ylthio]propanethiol hydrogen maleate
    —— 3-(4-Methylphenylthio)furan 128348-24-3 C11H10OS
    3-(4-Methylphenylthio)furan
    —— (+)-2-<(phenylthio)methyl>-(2R,3R)-3-propyloxirane 169738-71-0 C12H16OS
    (+)-2-<(phenylthio)methyl>-(2R,3R)-3-propyloxirane
    —— O-[17,20-bis(methylsulfanylcarbothioyloxy)-14-tetracyclo[11.5.2.01,12.012,16]icosanyl] methylsulfanylmethanethioate 130136-71-9 C26H40O3S6
    O-[17,20-bis(methylsulfanylcarbothioyloxy)-14-tetracyclo[11.5.2.01,12.012,16]icosanyl] methylsulfanylmethanethioate
    —— Ethyl 2-[4-(2-ethoxy-2-oxoethyl)sulfanylphenyl]sulfanylacetate 143526-80-1 C14H18O4S2
    Ethyl 2-[4-(2-ethoxy-2-oxoethyl)sulfanylphenyl]sulfanylacetate
    —— dodecylmethyl sulfide 126841-38-1 C26H54S
    dodecylmethyl sulfide
    —— 2,2-Dibenzylsulfonpropan 38377-25-2 C17H20O4S2
    2,2-Dibenzylsulfonpropan
    —— 2-p-tolylsulfanylbenzenesulfonamide 249555-70-2 C13H13NO2S2
    2-p-tolylsulfanylbenzenesulfonamide
    —— bis(methylsulfonyldichloromethyl) disulfide 74963-69-2 C4H6Cl4O4S4
    bis(methylsulfonyldichloromethyl) disulfide
    —— bis(n-octyl)pentasulfane 4089-80-9 C16H34S5
    bis(n-octyl)pentasulfane