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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-methylthio-5-nitro-1,2,4-triazole 346631-19-4 C3H4N4O2S
    3-methylthio-5-nitro-1,2,4-triazole
    —— Trithiocarbonic acid allyl ester dodecyl ester 89622-75-3 C16H30S3
    Trithiocarbonic acid allyl ester dodecyl ester
    —— 1,2-dimethyl-4,4-bis((trifluoromethyl)sulfonyl)cyclohex-1-ene 1314918-58-5 C10H12F6O4S2
    1,2-dimethyl-4,4-bis((trifluoromethyl)sulfonyl)cyclohex-1-ene
    —— 1-methyl-4,4-bis((trifluoromethyl)sulfonyl)cyclohex-1-ene 1314918-53-0 C9H10F6O4S2
    1-methyl-4,4-bis((trifluoromethyl)sulfonyl)cyclohex-1-ene
    —— methyl 2-acetyl-5-((2,4-dimethylphenyl)thio)-5-(phenylthio)pentanoate 1266617-56-4 C22H26O3S2
    methyl 2-acetyl-5-((2,4-dimethylphenyl)thio)-5-(phenylthio)pentanoate
    —— 2,2-dimethyl-3,6-dithiaheptane 115171-99-8 C7H16S2
    2,2-dimethyl-3,6-dithiaheptane
    —— 4-[(6,7-ethylenedithio-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole 1110615-81-0 C14H14N2S8
    4-[(6,7-ethylenedithio-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole
    —— (E)-methyl 2-methyl-2-phenylthiohex-3-enoate 109542-09-8 C14H18O2S
    (E)-methyl 2-methyl-2-phenylthiohex-3-enoate
    —— bis((2,4-dimethylphenyl)thio)methane 1266253-61-5 C17H20S2
    bis((2,4-dimethylphenyl)thio)methane
    —— (2-(2,4-dimethylphenylthio)ethyl)diphenylphosphine 864228-26-2 C22H23PS
    (2-(2,4-dimethylphenylthio)ethyl)diphenylphosphine
    —— 121781-86-0 C5H6OS2
    —— methyl 2-acetyl-5,5-bis((2,4-dimethylphenyl)thio)pentanoate 1266617-45-1 C24H30O3S2
    methyl 2-acetyl-5,5-bis((2,4-dimethylphenyl)thio)pentanoate
    —— 4-chloro-3-(2,4-dimethylphenylthio)-9H-thioxanthen-9-one 1372152-27-6 C21H15ClOS2
    4-chloro-3-(2,4-dimethylphenylthio)-9H-thioxanthen-9-one
    —— ethyl 2-acetyl-5-[(2,4-dimethylphenyl)thio]-5-(p-tolyl)pentanoate 1338781-69-3 C24H30O3S
    ethyl 2-acetyl-5-[(2,4-dimethylphenyl)thio]-5-(p-tolyl)pentanoate
    —— bis[4-(2,4-dimethylphenylsulfanyl)phenyl)sulfoxide 1112460-46-4 C28H26OS3
    bis[4-(2,4-dimethylphenylsulfanyl)phenyl)sulfoxide
    —— 2-((2,4 dimethylphenyl)thio)benzaldehyde 710961-37-8 C15H14OS
    2-((2,4 dimethylphenyl)thio)benzaldehyde
    —— 3-hydroxy-5-(methylsulfanyl)thiophene 128889-84-9 C5H6OS2
    3-hydroxy-5-(methylsulfanyl)thiophene
    —— 4-[(2,6,7-tris(methylthio)-TTF-3-yl)thio]-3,5-dimethylpyrazole 1110615-78-5 C14H16N2S8
    4-[(2,6,7-tris(methylthio)-TTF-3-yl)thio]-3,5-dimethylpyrazole
    —— 2-mercapto-4-methylsulfanyl-6-oxo-1,6-dihydro-pyridine-3-carbonitrile 726695-79-0 C7H6N2OS2
    2-mercapto-4-methylsulfanyl-6-oxo-1,6-dihydro-pyridine-3-carbonitrile
    —— 4-[(6,7-benzo-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole 1110615-79-6 C16H14N2S6
    4-[(6,7-benzo-2-methylthio-TTF-3-yl)thio]-3,5-dimethylpyrazole
    —— (E)-1-[(2-pyridyl)thio]-1-propene 51388-93-3 C8H9NS
    (E)-1-[(2-pyridyl)thio]-1-propene
    —— 2-((3-(triethoxysilyl)propyl)thio)pyridine 656230-07-8 C14H25NO3SSi
    2-((3-(triethoxysilyl)propyl)thio)pyridine
    —— O-Propyl-N-<2-propylthiolcarbonato-ethyl>-carbamat 93480-41-2 C10H19NO4S
    O-Propyl-N-<2-propylthiolcarbonato-ethyl>-carbamat
    —— 4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(thiophen-2-ylmethylthiomethyl)-pyridin-2(1H)-one 1025830-77-6 C20H20INOS3
    4-(3,5-dimethylphenylsulfanyl)-3-iodo-6-methyl-5-(thiophen-2-ylmethylthiomethyl)-pyridin-2(1H)-one
    —— (5-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)carbamic acid phenyl ester 417722-25-9 C22H18N2O4S2
    (5-(6,7-dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)carbamic acid phenyl ester
    —— N-(5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)-N'-(4-hydroxymethylphenyl)urea 417715-31-2 C23H21N3O4S2
    N-(5-(6,7-Dimethoxyquinolin-4-ylsulfanyl)thiophen-2-yl)-N'-(4-hydroxymethylphenyl)urea
    —— 1-(phenylthio)pentan-2-one 38793-73-6 C11H14OS
    1-(phenylthio)pentan-2-one
    —— 2,3,5,6-Tetrafluor-4-phenylmercapto-toluol 1548-86-3 C13H5F7S
    2,3,5,6-Tetrafluor-4-phenylmercapto-toluol
    —— 4,6,16,18-tetraaza-11-methyl-5,17-bis(methylsulfanyl)-2,8,14,20,26-pentaoxacalix[5]arene 1260029-55-7 C29H22N4O5S2
    4,6,16,18-tetraaza-11-methyl-5,17-bis(methylsulfanyl)-2,8,14,20,26-pentaoxacalix[5]arene
    —— 2-(2-thenylthio)-5-trifluoromethylpyrimidine 94447-85-5 C10H7F3N2S2
    2-(2-thenylthio)-5-trifluoromethylpyrimidine
    —— 3-bromo-2-{4-(methylthio)phenyl}-1-oxa-spiro[4,4]non-2-en-4-one 301699-20-7 C15H15BrO2S
    3-bromo-2-{4-(methylthio)phenyl}-1-oxa-spiro[4,4]non-2-en-4-one
    —— 4,6,16,18-tetraaza-11,23-dimethyl-5,17-bis(methylsulfanyl)-2,8,14,20-tetraoxacalix[4]arene 911713-50-3 C24H20N4O4S2
    4,6,16,18-tetraaza-11,23-dimethyl-5,17-bis(methylsulfanyl)-2,8,14,20-tetraoxacalix[4]arene
    —— 1,4-bis(chlorosulfanyl)butane 57693-23-9 C4H8Cl2S2
    1,4-bis(chlorosulfanyl)butane
    —— DL-threo-2-Amino-1-(4-methylmercapto-phenyl)-propan-1,3-diol 14172-52-2 C10H15NO2S
    DL-threo-2-Amino-1-(4-methylmercapto-phenyl)-propan-1,3-diol
    —— 2-(cyclopentylidenyl)ethenyl phenyl sulfide 77084-80-1 C13H14S
    2-(cyclopentylidenyl)ethenyl phenyl sulfide
    —— 1,2-dimethyl-5-nitro-4-phenylthioimidazole 113121-64-5 C11H11N3O2S
    1,2-dimethyl-5-nitro-4-phenylthioimidazole
    —— 2-(4-(methylthio)phenyl)-1-oxa-spiro[4.4]non-2-en-4-one 301699-19-4 C15H16O2S
    2-(4-(methylthio)phenyl)-1-oxa-spiro[4.4]non-2-en-4-one
    —— 2-benzylsulfanyl-5-bromo-aniline 107254-84-2 C13H12BrNS
    2-benzylsulfanyl-5-bromo-aniline
    —— 5-(phenylthio)-1-hexene 89113-72-4 C12H16S
    5-(phenylthio)-1-hexene
    —— 4-(phenylthio)-1-pentene 62162-25-8 C11H14S
    4-(phenylthio)-1-pentene
    —— 2-phenyl-1-(p-tolylthio)propan-2-ol 681006-46-2 C16H18OS
    2-phenyl-1-(p-tolylthio)propan-2-ol
    —— 4-(o-tolylthio)benzonitrile 1178206-52-4 C14H11NS
    4-(o-tolylthio)benzonitrile
    —— 2-t-butyl-4-chloro-5-{(5-chloro-2-thienyl)-α-methylmethylthio}-3(2H)-pyridazinone 106341-11-1 C14H16Cl2N2OS2
    2-t-butyl-4-chloro-5-{(5-chloro-2-thienyl)-α-methylmethylthio}-3(2H)-pyridazinone
    —— methyl 7-chloro-4-(3-chloropropyl)-3-oxo-3,4-dihydro-2H-1,5-benzoxathiepin-4-carboxylate 99204-03-2 C14H14Cl2O4S
    methyl 7-chloro-4-(3-chloropropyl)-3-oxo-3,4-dihydro-2H-1,5-benzoxathiepin-4-carboxylate
    —— 1,1-bis(phenylthio)-2-acetoxy-1-pentene 111731-09-0 C19H20O2S2
    1,1-bis(phenylthio)-2-acetoxy-1-pentene
    —— phenyl(2,4,5-trimethylphenyl)sulfane 1215002-21-3 C15H16S
    phenyl(2,4,5-trimethylphenyl)sulfane
    —— 2-methyl-2-phenyl-[1,3]dithiane-1,1,3,3-tetraoxide 68523-74-0 C11H14O4S2
    2-methyl-2-phenyl-[1,3]dithiane-1,1,3,3-tetraoxide
    —— 2-(methylthio)-4-(tert-pentylamino)pyrimidine-5-carbonitrile 1403865-16-6 C11H16N4S
    2-(methylthio)-4-(tert-pentylamino)pyrimidine-5-carbonitrile
    —— S-Pyridin-4-yl diethylcarbamothioate 114085-03-9 C10H14N2OS
    S-Pyridin-4-yl diethylcarbamothioate
    —— 2-methyl-6-phenylthiomethyl-5,6-dihydro-4H-1,3-oxazine 113261-16-8 C12H15NOS
    2-methyl-6-phenylthiomethyl-5,6-dihydro-4H-1,3-oxazine