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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— thiocarbamoyloxy-acetic acid 861535-94-6 C3H5NO3S
    thiocarbamoyloxy-acetic acid
    —— 3-(3-(dodecylsulfonyl)propyl)-6-tert-butyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine 133949-92-5 C23H42N4O2S2
    3-(3-(dodecylsulfonyl)propyl)-6-tert-butyl-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— p-tolyl benzodithioate 20876-81-7 C14H12S2
    p-tolyl benzodithioate
    —— 2-[(4-tert-butyl-1H-imidazol-2-yl)thio]acetamide 623547-73-9 C9H15N3OS
    2-[(4-tert-butyl-1H-imidazol-2-yl)thio]acetamide
    —— 6-(ethylthio)-1-hexanol 83705-78-6 C8H18OS
    6-(ethylthio)-1-hexanol
    —— 5,6-Difluoro-2-phenylsulfanyl-benzoimidazole-1-sulfonic acid dimethylamide 862180-00-5 C15H13F2N3O2S2
    5,6-Difluoro-2-phenylsulfanyl-benzoimidazole-1-sulfonic acid dimethylamide
    —— 5-cyano-5-isopropylsulphonylnorborn-2-ene 102329-70-4 C11H15NO2S
    5-cyano-5-isopropylsulphonylnorborn-2-ene
    —— 2,2'-thiobis<4-t-butylphenol> 3273-24-3 C20H26O2S
    2,2'-thiobis<4-t-butylphenol>
    —— 10-Methyl-10H-9-thia-10-sila-anthracene 76216-74-5 C13H12SSi
    10-Methyl-10H-9-thia-10-sila-anthracene
    —— 4,11-Dihydro-1-oxa-10-thia-4-aza-benzo[a]cyclopenta[e]cycloocten-5-one 139308-27-3 C12H9NO2S
    4,11-Dihydro-1-oxa-10-thia-4-aza-benzo[a]cyclopenta[e]cycloocten-5-one
    —— 6-(4,6-Dimethylpyrimidin-2-ylthio)hexan-1-ol 112641-04-0 C12H20N2OS
    6-(4,6-Dimethylpyrimidin-2-ylthio)hexan-1-ol
    —— 1-methanesulfinyl-1-methylsulfanyl-propene 51534-65-7 C5H10OS2
    1-methanesulfinyl-1-methylsulfanyl-propene
    —— 4,5-Dimethyl-2-methylmercapto-pyrimidin 17759-43-2 C7H10N2S
    4,5-Dimethyl-2-methylmercapto-pyrimidin
    —— (4-methoxyphenyl)(2-(trifluoromethyl)phenyl)sulfane 1190852-22-2 C14H11F3OS
    (4-methoxyphenyl)(2-(trifluoromethyl)phenyl)sulfane
    —— 4H,8H-2,3,6,7,4',5',4'',5''-octa(methoxycarbonyl)thiopyrano<3,2-b>thiopyran-4-spiro-2'-1',3'-dithiole-8-spiro-2''-1'',3''-dithiole 160593-44-2 C28H24O16S6
    4H,8H-2,3,6,7,4',5',4'',5''-octa(methoxycarbonyl)thiopyrano<3,2-b>thiopyran-4-spiro-2'-1',3'-dithiole-8-spiro-2''-1'',3''-dithiole
    —— 5-(bromomethyl)-4-methyl-2-(methylthio)pyrimidine 135645-54-4 C7H9BrN2S
    5-(bromomethyl)-4-methyl-2-(methylthio)pyrimidine
    —— 1-(1-hydroxycycloheptyl)-2-(p-tolylthio)-1-ethanone 134858-00-7 C16H22O2S
    1-(1-hydroxycycloheptyl)-2-(p-tolylthio)-1-ethanone
    —— 3,3-dimethylenedithio-5-(tetrahydropyranyl)oxypentanol 136400-73-2 C12H22O3S2
    3,3-dimethylenedithio-5-(tetrahydropyranyl)oxypentanol
    —— 3-Acetoxy-4-methyl-1-phenylthio-2-pentanon 69798-61-4 C14H18O3S
    3-Acetoxy-4-methyl-1-phenylthio-2-pentanon
    —— Dimethyl (2-benzyl-3-methylthio-2H-1,2,4-triazol-5-yl)iminodithiocarbonate 132395-59-6 C13H16N4S3
    Dimethyl (2-benzyl-3-methylthio-2H-1,2,4-triazol-5-yl)iminodithiocarbonate
    —— Dimethyl (1-benzyl-3-methylthio-1H-1,2,4-triazol-5-yl)iminodithiocarbonate 132395-51-8 C13H16N4S3
    Dimethyl (1-benzyl-3-methylthio-1H-1,2,4-triazol-5-yl)iminodithiocarbonate
    —— 4-(Bromomethyl)-5-methyl-2-(methylthio)pyrimidine 135645-55-5 C7H9BrN2S
    4-(Bromomethyl)-5-methyl-2-(methylthio)pyrimidine
    —— 4-[3-(4-Amino-phenyl sulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile 278183-71-4 C18H18N2OS
    4-[3-(4-Amino-phenyl sulfanyl)-phenyl]-tetrahydro-pyran-4-carbonitrile
    —— 3-methyl-2-i-propyl-2-(phenylthio)acetic acid 140400-38-0 C12H16O2S
    3-methyl-2-i-propyl-2-(phenylthio)acetic acid
    —— 2-(2-(trifluoromethyl)phenylthio)-5-methylphenol 1254831-67-8 C14H11F3OS
    2-(2-(trifluoromethyl)phenylthio)-5-methylphenol
    —— 4-(tert-butyl)phenyl 2-trifluoromethylphenyl sulfide 1350928-11-8 C17H17F3S
    4-(tert-butyl)phenyl 2-trifluoromethylphenyl sulfide
    —— 2-((4-chlorophenyl)thio)-3-methylbutanoic acid 140400-37-9 C11H13ClO2S
    2-((4-chlorophenyl)thio)-3-methylbutanoic acid
    —— 3-methyl-2-(phenylthio)butanoic acid 57557-60-5 C11H14O2S
    3-methyl-2-(phenylthio)butanoic acid
    —— 5-((p-tolylthio)methyl)dihydrofuran-2(3H)-one 108078-65-5 C12H14O2S
    5-((p-tolylthio)methyl)dihydrofuran-2(3H)-one
    —— N,N-dimethylsulfamoyl azide 33581-92-9 C2H6N4O2S
    N,N-dimethylsulfamoyl azide
    —— (R)-[2-[(2R)-2-[tert-butyl(dimethyl)silyl]oxy-3-(2-methyl-1,3-dithian-2-yl)propyl]-1,3-dithian-2-yl]-(2-prop-2-enylphenyl)methanol 1073175-01-5 C28H46O2S4Si
    (R)-[2-[(2R)-2-[tert-butyl(dimethyl)silyl]oxy-3-(2-methyl-1,3-dithian-2-yl)propyl]-1,3-dithian-2-yl]-(2-prop-2-enylphenyl)methanol
    —— 4,4'-dimethylthio-3,3'-diquinolinyl sulfide 74575-24-9 C20H16N2S3
    4,4'-dimethylthio-3,3'-diquinolinyl sulfide
    —— 2-(2-aminophenylsulfanyl)-5-ethylthiophene-3-carboxylic acid methyl ester 848555-36-2 C14H15NO2S2
    2-(2-aminophenylsulfanyl)-5-ethylthiophene-3-carboxylic acid methyl ester
    —— 1,1,1-trifluoro-4-(methylsulfonyl)but-3-ene-2,2-diol 473994-49-9 C5H7F3O4S
    1,1,1-trifluoro-4-(methylsulfonyl)but-3-ene-2,2-diol
    —— 1-(1-naphthylthio)isoquinoline 112107-65-0 C19H13NS
    1-(1-naphthylthio)isoquinoline
    —— 5-Methyl-2-(methylthio)-4-pyrimidinecarbaldehyde 135645-58-8 C7H8N2OS
    5-Methyl-2-(methylthio)-4-pyrimidinecarbaldehyde
    —— 2-(2-aminophenylsulfanyl)-5-bromothiophene-3-carboxylic acid ethyl ester 848555-47-5 C13H12BrNO2S2
    2-(2-aminophenylsulfanyl)-5-bromothiophene-3-carboxylic acid ethyl ester
    —— 4-(Dibromomethyl)-5-methyl-2-(methylthio)pyrimidine 135645-56-6 C7H8Br2N2S
    4-(Dibromomethyl)-5-methyl-2-(methylthio)pyrimidine
    —— 5-(Bromomethyl)-4,6-dimethyl-2-(methylthio)pyrimidine 135645-61-3 C8H11BrN2S
    5-(Bromomethyl)-4,6-dimethyl-2-(methylthio)pyrimidine
    —— 5-Bromo-4-(bromomethyl)-2-(methylthio)pyrimidine 135645-64-6 C6H6Br2N2S
    5-Bromo-4-(bromomethyl)-2-(methylthio)pyrimidine
    —— 4-[(4,6-dimethylpyrimidin-2-yl)thio]-2,3,5,6-tetrafluorobenzenesulfonamide 1428673-35-1 C12H9F4N3O2S2
    4-[(4,6-dimethylpyrimidin-2-yl)thio]-2,3,5,6-tetrafluorobenzenesulfonamide
    —— (2-(mesitylthio)ethyl)diphenylphosphine 919992-40-8 C23H25PS
    (2-(mesitylthio)ethyl)diphenylphosphine
    —— 2(1-Naphtylthio)benzylalkohol 56057-01-3 C17H14OS
    2(1-Naphtylthio)benzylalkohol
    —— 1-(2-bromomethyl-phenylsulfanyl)-naphthalene 613670-88-5 C17H13BrS
    1-(2-bromomethyl-phenylsulfanyl)-naphthalene
    —— 2,4-diamino-6-(naphthalen-1-ylsulfanyl)pyrido(3,2-d)pyrimidine 95095-99-1 C17H13N5S
    2,4-diamino-6-(naphthalen-1-ylsulfanyl)pyrido(3,2-d)pyrimidine
    —— 2(1-Naphthylthio)phenylessigsaeure 56057-03-5 C18H14O2S
    2(1-Naphthylthio)phenylessigsaeure
    —— 1-methyl-4-(1-naphthalenylthio)-1H-imidazole-5-carbaldehyde 141524-61-0 C15H12N2OS
    1-methyl-4-(1-naphthalenylthio)-1H-imidazole-5-carbaldehyde
    —— 2,4-diamino-5-methyl-6-(1-naphthylthio)furo[2,3-d]pyrimidine 221036-12-0 C17H14N4OS
    2,4-diamino-5-methyl-6-(1-naphthylthio)furo[2,3-d]pyrimidine
    —— 2(1-Naphthylthio)phenylacetonitril 56057-02-4 C18H13NS
    2(1-Naphthylthio)phenylacetonitril
    —— 4-(Dibromomethyl)-2-(methylthio)pyrimidine 135645-62-4 C6H6Br2N2S
    4-(Dibromomethyl)-2-(methylthio)pyrimidine