二癸基硫醚 | 693-83-4

• 物质功能分类: 有机原料 - 无机酸酯
• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 中文名称: 二癸基硫醚
• 中文别名: 1-癸硫基癸烷；11-硫杂正二十一烷；二癸基硫酸酯
• 英文名称: didecyl sulfide
• 英文别名: 1-decylsulfanyldecane；di-n-decyl sulfide；didecyl thioether；didecylsulfane；decyl sulfide；bis-decyl-sulfane
• CAS: 693-83-4
• 化学式: C₂₀H₄₂S
• 分子量: 314.619
• InChiKey: RKYMVQJWYYOIJB-UHFFFAOYSA-N

物化性质

• 熔点：
  24-26°C
• 沸点：
  217-218°C 8mm
• 密度：
  0.8823 (estimate)
• 闪点：
  217-218°C/8mm
• 保留指数：
  2295;2281;2285;2295

计算性质

• 辛醇/水分配系数(LogP)：
  9.9
• 重原子数：
  21
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• TSCA：
  Yes
• 安全说明：
  S24/25
• 海关编码：
  2930909090

SDS

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SECTION 1: Identification of the substance/mixture and of the company/undertaking
Product identifiers
Product name : Decyl Sulfide
REACH No. : A registration number is not available for this substance as the substance
or its uses are exempted from registration, the annual tonnage does not
require a registration or the registration is envisaged for a later
registration deadline.
Relevant identified uses of the substance or mixture and uses advised against
Identified uses : Laboratory chemicals, Manufacture of substances

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SECTION 2: Hazards identification
Classification of the substance or mixture
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.
This substance is not classified as dangerous according to Directive 67/548/EEC.
Label elements
The product does not need to be labelled in accordance with EC directives or respective national laws.
Other hazards
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

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SECTION 3: Composition/information on ingredients
Substances
Molecular weight : 314,62 g/mol
No components need to be disclosed according to the applicable regulations.

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SECTION 4: First aid measures
Description of first aid measures
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration.
In case of skin contact
Wash off with soap and plenty of water.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Never give anything by mouth to an unconscious person. Rinse mouth with water.
Most important symptoms and effects, both acute and delayed
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
Indication of any immediate medical attention and special treatment needed
No data available

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SECTION 5: Firefighting measures
Extinguishing media
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Special hazards arising from the substance or mixture
Nature of decomposition products not known.
Advice for firefighters
Wear self-contained breathing apparatus for firefighting if necessary.
Further information
No data available

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SECTION 6: Accidental release measures
Personal precautions, protective equipment and emergency procedures
Avoid dust formation. Avoid breathing vapours, mist or gas.
For personal protection see section 8.
Environmental precautions
No special environmental precautions required.
Methods and materials for containment and cleaning up
Sweep up and shovel. Keep in suitable, closed containers for disposal.
Reference to other sections
For disposal see section 13.

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SECTION 7: Handling and storage
Precautions for safe handling
Provide appropriate exhaust ventilation at places where dust is formed.
For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
Storage class (TRGS 510): Non Combustible Solids
Specific end use(s)
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

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SECTION 8: Exposure controls/personal protection
Control parameters
Components with workplace control parameters
Exposure controls
Appropriate engineering controls
General industrial hygiene practice.
Personal protective equipment
Eye/face protection
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU).
Skin protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove's outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and
the standard EN 374 derived from it.
Body Protection
Choose body protection in relation to its type, to the concentration and amount of dangerous
substances, and to the specific work-place., The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired,
use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Control of environmental exposure
No special environmental precautions required.

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SECTION 9: Physical and chemical properties
Information on basic physical and chemical properties
a) Appearance Form: solid
b) Odour No data available
c) Odour Threshold No data available
d) pH No data available
e) Melting point/freezing No data available
point
f) Initial boiling point and No data available
boiling range
g) Flash point No data available
h) Evaporation rate No data available
i) Flammability (solid, gas) No data available
j) Upper/lower No data available
flammability or
explosive limits
k) Vapour pressure No data available
l) Vapour density No data available
m) Relative density No data available
n) Water solubility No data available
o) Partition coefficient: n- No data available
octanol/water
p) Auto-ignition No data available
temperature
q) Decomposition No data available
temperature
r) Viscosity No data available
s) Explosive properties No data available
t) Oxidizing properties No data available
Other safety information
No data available

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SECTION 10: Stability and reactivity
Reactivity
No data available
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
No data available
Conditions to avoid
No data available
Incompatible materials
No data available
Hazardous decomposition products
In the event of fire: see section 5

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SECTION 11: Toxicological information
Information on toxicological effects
Acute toxicity
No data available
Skin corrosion/irritation
No data available
Serious eye damage/eye irritation
No data available
Respiratory or skin sensitisation
No data available
Germ cell mutagenicity
No data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
Reproductive toxicity
No data available
Specific target organ toxicity - single exposure
No data available
Specific target organ toxicity - repeated exposure
No data available
Aspiration hazard
No data available
Additional Information
RTECS: Not available

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SECTION 12: Ecological information
Toxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available
Results of PBT and vPvB assessment
This substance/mixture contains no components considered to be either persistent, bioaccumulative and
toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Other adverse effects
No data available

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SECTION 13: Disposal considerations
Waste treatment methods
Product
Offer surplus and non-recyclable solutions to a licensed disposal company.
Contaminated packaging
Dispose of as unused product.

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SECTION 14: Transport information
UN number
ADR/RID: - IMDG: - IATA: -
UN proper shipping name
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
Transport hazard class(es)
ADR/RID: - IMDG: - IATA: -
Packaging group
ADR/RID: - IMDG: - IATA: -
Environmental hazards
ADR/RID: no IMDG Marine pollutant: no IATA: no
Special precautions for user
No data available

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SECTION 15: Regulatory information
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
Safety, health and environmental regulations/legislation specific for the substance or mixture
No data available
Chemical Safety Assessment
For this product a chemical safety assessment was not carried out

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SECTION 16: Other information
Further information
Copyright 2014 Co. LLC. License granted to make unlimited paper copies for internal use
only.
The above information is believed to be correct but does not purport to be all inclusive and shall be
used only as a guide. The information in this document is based on the present state of our knowledge
and is applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Corporation and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
and/or the reverse side of invoice or packing slip for additional terms and conditions of sale.

反应信息

• 作为反应物：
  描述：

  二癸基硫醚 在 双氧水 、 溶剂黄146 作用下， 生成 1-(癸基磺酰基)癸烷
  参考文献：
  名称：

  Reactions of Atoms and Free Radicals in Solution. XXIII. The Peroxide-Induced Addition of Sulfuryl Chloride to 1-Alkenes

  摘要：

  DOI：

  10.1021/ja01147a022
• 作为产物：
  描述：

  癸基溴 在 二硫代乙酰胺 、 sodium hydroxide 作用下， 以 水 为溶剂， 反应 6.0h， 以83%的产率得到二癸基硫醚
  参考文献：
  名称：

  二硫代草酰胺作为一种有效的硫替代物，用于在湿 PEG200 中形成无味的高产碳硫键，作为一种环保、安全且可回收的溶剂

  摘要：

  在这项研究中，我们使用二硫代草酰胺（一种固体、无味且可商购的化合物）作为硫代用品，以高产率从可用的卤代烷制备二烷基硫化物。这种硫转移剂还用于铜催化从可用的芳基卤化物制备二芳基硫化物的高产率，以及高产率制备硫杂-迈克尔加合物。所有反应均在无味条件下在湿 PEG200（PEG = 聚乙二醇）中进行，这是一种环保、安全且可回收的溶剂。这些协议很容易适用于大规模操作。

  DOI：

  10.1002/ejoc.201500156

文献信息

• [EN] FUNCTIONALIZED α-ANGELICA LACTONE MONOMERS AND POLYMERS OBTAINED THEREFROM<br/>[FR] MONOMÈRES α-ANGELICA LACTONE ET POLYMÈRES OBTENUS À PARTIR DE CEUX-CI
  申请人：HENKEL AG & CO KGAA

  公开号：WO2020212041A1

  公开（公告）日：2020-10-22

  The present invention is directed to a monomer for chain growth polymerization, in particular anionic polymerization, said monomer having the general formula (EFL) wherein: Ra is a C3-C30 alkyl, C3-C30 cycloalkyl, C6-C18 aryl or C2-C12 alkenyl group. The present invention is further directed to a process for the anionic polymerization of at least one compound (EFL) as defined above, wherein said anionic polymerization is conducted in the presence of an initiator selected from the group consisting of: alkali metal organyls; alkali metal alkoxides; alkali metal thiolate; alkali metal amides; and, compounds of an element of group 3a of the Periodic Table of the Elements. The process of anionic polymerization yields a homo- or co-polymer (p-EFL) having pendant lactone functional groups in its repeating units.

  本发明涉及一种用于链增长聚合的单体，特别是阴离子聚合，所述单体具有通式（EFL），其中：Ra是C3-C30烷基，C3-C30环烷基，C6-C18芳基或C2-C12烯基基团。本发明进一步涉及一种用于上述定义的至少一种化合物（EFL）的阴离子聚合的方法，其中所述阴离子聚合在以下引发剂的存在下进行：碱金属有机基；碱金属烷氧基；碱金属硫醇酸盐；碱金属酰胺；以及元素3a族化合物。阴离子聚合的方法产生具有其重复单元中端基内酯官能团的同聚物或共聚物（p-EFL）。
• One-Pot Synthesis of Organic Disulfides (Disulfanes) from Alkyl Halides Using Sodium Sulfide Trihydrate and Hexachloroethane or Carbon Tetrachloride in the Poly(ethylene glycol) (PEG-200)
  作者：Mohammad Abbasi、Mohammad Mohammadizadeh、Hekmat Moosavi、Narges Saeedi

  DOI：10.1055/s-0034-1380291

  日期：——

  Symmetric disulfides are produced by treating their corresponding organic halides including benzylic, allylic, primary and secondary halides with Na2S·3H2O and C2Cl6 or CCl4 in PEG-200 at room temperature in high yields.

  对称二硫化物是通过在室温下以高收率在 PEG-200 中用 Na2S·3H2O 和 C2Cl6 或 CCl4 处理其相应的有机卤化物（包括苄基、烯丙基、伯卤和仲卤）制备的。
• Continuous photochemical production of high purity linear mercaptan and sulfide compositions
  申请人：Arkema Inc.

  公开号：US11161810B1

  公开（公告）日：2021-11-02

  Continuous photochemical production of high purity linear mercaptan and sulfide-containing compositions.

  连续光化学生产高纯度的直链硫醇和含硫化物的化合物。
• Method for preparing sulfone or sulfoxide compound
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：US20030171589A1

  公开（公告）日：2003-09-11

  There is provided a method for preparing a sulfone or sulfoxide compound, characterized in that a sulfide compound is allowed to react with hydrogen peroxide in the presence of a metal oxide catalyst formed by the reaction of hydrogen peroxide with at least one metal or metal compound selected from tungsten metal; molybdenum metal; a tungsten compound comprising tungsten and a Group IIIb, IVb, Vb, or VIb element exclusive of oxygen; and a molybdenum compound comprising molybdenum and a Group IIIb, IVb, Vb, or VIb element exclusive of oxygen.

  提供了一种制备磺酰或亚磺酰化合物的方法，其特征在于在至少选择一种钨金属、钼金属、包含钨和IIIb、IVb、Vb或VIb元素（不包括氧）的钨化合物和包含钼和IIIb、IVb、Vb或VIb元素（不包括氧）的钼化合物中至少选择一种金属或金属化合物与过氧化氢反应形成的金属氧化物催化剂的存在下，使硫化物化合物与过氧化氢反应。
• Lackbindemittel und ihre Verwendung für die kathodische Elektrotauchlackierung
  申请人：BASF Aktiengesellschaft

  公开号：EP0002499A1

  公开（公告）日：1979-06-27

  Die Erfindung betrifft Lackbindemittel und ihre Verwendung. Die im wesentlichen epoxidgruppenfreien Lackbindemittel basieren auf einem Umsetzungsprodukt von A) Mannich-Basen aus mindestens einem ätnergruppenfreien, mehrwertigen Phenol, das zwei oder mehr aromatische Ringe enthält, und/oder mindestens einem mindestens eine Äthergruppe enthaltenden ein- oder mehrwertigen Phenol, das zwei oder mehr aromatische Ringe enthält, mindestens einem sekundären Amin, das ein oder zwei Hydroxyalkylgruppen enthält, gegebenenfalls im Gemisch mit sekundären Dialkyl- oder Dialkoxyalkylaminen, und Formaldehyd oder Formaldehyd bildenden Verbindungen und B) Epoxidharz, wobei das Umsetzungsprodukt aus (A) und (B) zusätzlich ein olefinisch ungesättigtes Alkylphenol der allgemeinen Formel (I) eingebaut enthält, mit der Maßgabe, daß R für einen eine bis drei C-C-Doppelbindungen enthaltenden Rest mit 11 bis 19 Kohlenstoffatomen steht. Diese Lackbindemittel werden insbesondere in ihrer protonierten Form zur kathodischen Elektrotauchlackierung von Metallteilen verwendet.

  本发明涉及涂料粘合剂及其用途。 基本上不含环氧基的涂料粘合剂是基于以下物质的反应产物：A) 至少一种不含醚基、含有两个或两个以上芳香环的多水合苯酚和/或至少一种含有至少一个醚基并含有两个或两个以上芳香环的单水合或多水合苯酚的曼尼希碱、至少一种含有一个或两个羟基烷基的仲胺，可选择与仲二烷基或二烷氧基烷基胺、甲醛或形成甲醛的化合物混合；以及 B) 环氧树脂，其中 (A) 和 (B) 的反应产物还含有通式 (I) 的烯烃不饱和烷基酚 但 R 是含有 1 至 3 个 C-C 双键和 11 至 19 个碳原子的自由基。 这些涂料粘合剂主要以质子化形式用于金属部件的阴极电镀。

表征谱图