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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3R)-N-[(1S)-2-[(R)-methylsulfinyl]-1-phenylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C18H19NO2S2
    (3R)-N-[(1S)-2-[(R)-methylsulfinyl]-1-phenylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-N-[(1R)-2-[(S)-methylsulfinyl]-1-phenylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C18H19NO2S2
    (3R)-N-[(1R)-2-[(S)-methylsulfinyl]-1-phenylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— (3R)-N-[(1R)-2-[(R)-methylsulfinyl]-1-phenylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C18H19NO2S2
    (3R)-N-[(1R)-2-[(R)-methylsulfinyl]-1-phenylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]methylideneamino]acetamide —— C20H24ClN3O2S
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-[2,5-dimethyl-1-[[(2S)-oxolan-2-yl]methyl]pyrrol-3-yl]methylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide —— C14H13ClN2O2S
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]acetamide —— C14H13ClN2OS2
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N'-(1-pyrrol-2-ylideneethyl)acetohydrazide —— C14H14ClN3OS
    2-(4-chlorophenyl)sulfanyl-N'-(1-pyrrol-2-ylideneethyl)acetohydrazide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(2,4,6-trimethylphenyl)methylideneamino]acetamide —— C18H19ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(2,4,6-trimethylphenyl)methylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3,4-difluorophenyl)methylideneamino]acetamide —— C15H11ClF2N2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3,4-difluorophenyl)methylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-pyridin-3-ylethylideneamino]acetamide —— C15H14ClN3OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-1-pyridin-3-ylethylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-fluorophenyl)methylideneamino]acetamide —— C15H12ClFN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-fluorophenyl)methylideneamino]acetamide
    —— N-[(Z)-[5-chloro-3-methyl-1-(2-methylpropyl)pyrazol-4-yl]methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C17H20Cl2N4OS
    N-[(Z)-[5-chloro-3-methyl-1-(2-methylpropyl)pyrazol-4-yl]methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-[(3R)-3-methylcyclohexylidene]amino]acetamide —— C15H19ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-[(3R)-3-methylcyclohexylidene]amino]acetamide
    —— (3R)-N-[(1S)-2-[(S)-methylsulfinyl]-1-phenylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide —— C18H19NO2S2
    (3R)-N-[(1S)-2-[(S)-methylsulfinyl]-1-phenylethyl]-2,3-dihydro-1-benzothiophene-3-carboxamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-[2,5-dimethyl-1-[[(2R)-oxolan-2-yl]methyl]pyrrol-3-yl]methylideneamino]acetamide —— C20H24ClN3O2S
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-[2,5-dimethyl-1-[[(2R)-oxolan-2-yl]methyl]pyrrol-3-yl]methylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-hydroxyphenyl)methylideneamino]acetamide —— C15H13ClN2O2S
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-hydroxyphenyl)methylideneamino]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(5-cyano-1,2-dimethylpyrrol-3-yl)methylideneamino]acetamide —— C16H15ClN4OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(5-cyano-1,2-dimethylpyrrol-3-yl)methylideneamino]acetamide
    —— N-[(Z)-(2-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C15H12Cl2N2OS
    N-[(Z)-(2-chlorophenyl)methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— 2-cyclopropyl-5-[[(2R)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazole —— C11H16N2OS2
    2-cyclopropyl-5-[[(2R)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazole
    —— N-cyclopropyl-N-[(1S)-1-cyclopropylethyl]-2-pyrazin-2-ylsulfanylacetamide —— C14H19N3OS
    N-cyclopropyl-N-[(1S)-1-cyclopropylethyl]-2-pyrazin-2-ylsulfanylacetamide
    —— N-cyclopropyl-N-[(1R)-1-cyclopropylethyl]-2-pyrazin-2-ylsulfanylacetamide —— C14H19N3OS
    N-cyclopropyl-N-[(1R)-1-cyclopropylethyl]-2-pyrazin-2-ylsulfanylacetamide
    —— 2-cyclopropyl-5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazole —— C11H16N2OS2
    2-cyclopropyl-5-[[(2S)-oxan-2-yl]methylsulfanyl]-1,3,4-thiadiazole
    —— dimethyl-[(2S)-1-phenyl-3-[(2-phenylsulfanylpyridine-3-carbonyl)amino]propan-2-yl]azanium —— C23H26N3OS+
    dimethyl-[(2S)-1-phenyl-3-[(2-phenylsulfanylpyridine-3-carbonyl)amino]propan-2-yl]azanium
    —— N-[(R)-[(1R,2S)-2-methylcyclopropyl]-phenylmethyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS
    N-[(R)-[(1R,2S)-2-methylcyclopropyl]-phenylmethyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(R)-[(1S,2S)-2-methylcyclopropyl]-phenylmethyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS
    N-[(R)-[(1S,2S)-2-methylcyclopropyl]-phenylmethyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(S)-[(1S,2S)-2-methylcyclopropyl]-phenylmethyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS
    N-[(S)-[(1S,2S)-2-methylcyclopropyl]-phenylmethyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(S)-[(1R,2S)-2-methylcyclopropyl]-phenylmethyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H20N4OS
    N-[(S)-[(1R,2S)-2-methylcyclopropyl]-phenylmethyl]-2-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one —— C14H17N3OS2
    (2R)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one
    —— 2-[2-(4-Chlorophenyl)sulfanylethylsulfanyl]-5-(2-methylphenyl)-1,3,4-oxadiazole —— C17H15ClN2OS2
    2-[2-(4-Chlorophenyl)sulfanylethylsulfanyl]-5-(2-methylphenyl)-1,3,4-oxadiazole
    —— N-[(1R,3R)-3-methoxy-2,2,3-trimethylcyclobutyl]-2-pyridin-4-ylsulfanylacetamide —— C15H22N2O2S
    N-[(1R,3R)-3-methoxy-2,2,3-trimethylcyclobutyl]-2-pyridin-4-ylsulfanylacetamide
    —— (2S)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one —— C14H17N3OS2
    (2S)-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one
    —— 1-[(3-methylpyridin-2-yl)methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea —— C17H21N3OS
    1-[(3-methylpyridin-2-yl)methyl]-3-[(2S)-2-phenylsulfanylpropyl]urea
    —— 1-[(3-methylpyridin-2-yl)methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea —— C17H21N3OS
    1-[(3-methylpyridin-2-yl)methyl]-3-[(2R)-2-phenylsulfanylpropyl]urea
    —— 5-[(2-chlorophenyl)methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine —— C16H14ClN3S2
    5-[(2-chlorophenyl)methylsulfanyl]-N-(3-methylphenyl)-1,3,4-thiadiazol-2-amine
    —— N-[(3R)-1-benzylpyrrolidin-1-ium-3-yl]-2-phenylsulfanylpyridine-3-carboxamide —— C23H24N3OS+
    N-[(3R)-1-benzylpyrrolidin-1-ium-3-yl]-2-phenylsulfanylpyridine-3-carboxamide
    —— 2-Naphthalen-2-ylsulfanylpyrimidine —— C14H10N2S
    2-Naphthalen-2-ylsulfanylpyrimidine
    —— N-[(1R,3S)-3-methoxy-2,2,3-trimethylcyclobutyl]-2-pyridin-4-ylsulfanylacetamide —— C15H22N2O2S
    N-[(1R,3S)-3-methoxy-2,2,3-trimethylcyclobutyl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(1S,3S)-3-methoxy-2,2,3-trimethylcyclobutyl]-2-pyridin-4-ylsulfanylacetamide —— C15H22N2O2S
    N-[(1S,3S)-3-methoxy-2,2,3-trimethylcyclobutyl]-2-pyridin-4-ylsulfanylacetamide
    —— N-[(1S,3R)-3-methoxy-2,2,3-trimethylcyclobutyl]-2-pyridin-4-ylsulfanylacetamide —— C15H22N2O2S
    N-[(1S,3R)-3-methoxy-2,2,3-trimethylcyclobutyl]-2-pyridin-4-ylsulfanylacetamide
    —— N'-[2-(3-chloro-4-fluorophenyl)sulfanylacetyl]-2-[(3R)-1,1-dioxothiolan-3-yl]acetohydrazide —— C14H16ClFN2O4S2
    N'-[2-(3-chloro-4-fluorophenyl)sulfanylacetyl]-2-[(3R)-1,1-dioxothiolan-3-yl]acetohydrazide
    —— 5-ethylsulfanyl-3-(2-thienyl)-1H-1,2,4-triazole —— C8H9N3S2
    5-ethylsulfanyl-3-(2-thienyl)-1H-1,2,4-triazole
    —— 4,6-Dimethyl-2-[2-oxo-2-[4-(thiophen-2-ylmethyl)piperazin-4-ium-1-yl]ethyl]sulfanylpyridine-3-carbonitrile —— C19H23N4OS2+
    4,6-Dimethyl-2-[2-oxo-2-[4-(thiophen-2-ylmethyl)piperazin-4-ium-1-yl]ethyl]sulfanylpyridine-3-carbonitrile
    —— N-[[4-(dimethylamino)phenyl]methyl]-2-(2-methylphenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C23H30N2O2S
    N-[[4-(dimethylamino)phenyl]methyl]-2-(2-methylphenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 4,6-Dimethyl-2-[2-oxo-2-[4-(thiophen-2-ylmethyl)piperazin-1-yl]ethyl]sulfanylpyridine-3-carbonitrile —— C19H22N4OS2
    4,6-Dimethyl-2-[2-oxo-2-[4-(thiophen-2-ylmethyl)piperazin-1-yl]ethyl]sulfanylpyridine-3-carbonitrile
    —— 1-(5-Chlorothiophen-2-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone —— C11H10ClN3OS3
    1-(5-Chlorothiophen-2-yl)-2-[[5-(prop-2-enylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]ethanone
    —— [(1S)-2-[[2-(2-cyanophenyl)sulfanylbenzoyl]amino]-1-thiophen-2-ylethyl]-dimethylazanium —— C22H22N3OS2+
    [(1S)-2-[[2-(2-cyanophenyl)sulfanylbenzoyl]amino]-1-thiophen-2-ylethyl]-dimethylazanium
    —— 2-[[4-(4-Methylphenyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]pyridine-3-carbonitrile —— C19H18N6OS
    2-[[4-(4-Methylphenyl)-5-morpholin-4-yl-1,2,4-triazol-3-yl]sulfanyl]pyridine-3-carbonitrile
    —— 2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C17H26N4O3S2
    2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-phenylsulfanyl-N-[2-(thiophen-2-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide —— C20H16N4OS2
    2-phenylsulfanyl-N-[2-(thiophen-2-ylmethyl)pyrazol-3-yl]pyridine-3-carboxamide
    —— 4-[(4-benzylsulfonylpiperazin-1-yl)methyl]-2-methylsulfanyl-1H-pyrimidin-6-one —— C17H22N4O3S2
    4-[(4-benzylsulfonylpiperazin-1-yl)methyl]-2-methylsulfanyl-1H-pyrimidin-6-one