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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-(3,4-difluorophenyl)sulfanyl-N'-[2-(2-fluorophenyl)sulfanylacetyl]propanehydrazide —— C17H15F3N2O2S2
    3-(3,4-difluorophenyl)sulfanyl-N'-[2-(2-fluorophenyl)sulfanylacetyl]propanehydrazide
    —— 2-[(1R)-cyclopent-2-en-1-yl]-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide —— C16H20N2O2S
    2-[(1R)-cyclopent-2-en-1-yl]-N'-[2-(4-methylphenyl)sulfanylacetyl]acetohydrazide
    —— N'-[2-(2,5-difluorophenyl)sulfanylacetyl]-2-(4-methylphenyl)sulfanylacetohydrazide —— C17H16F2N2O2S2
    N'-[2-(2,5-difluorophenyl)sulfanylacetyl]-2-(4-methylphenyl)sulfanylacetohydrazide
    —— N'-[2-(2,5-difluorophenyl)sulfanylacetyl]-2-(2-fluorophenyl)sulfanylacetohydrazide —— C16H13F3N2O2S2
    N'-[2-(2,5-difluorophenyl)sulfanylacetyl]-2-(2-fluorophenyl)sulfanylacetohydrazide
    —— 1-cyclopent-3-en-1-yl-3-[(1S)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]urea —— C17H24N2O2S
    1-cyclopent-3-en-1-yl-3-[(1S)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]urea
    —— 2-[(5-tert-butyl-1,3-thiazol-2-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C14H22N2O2S2
    2-[(5-tert-butyl-1,3-thiazol-2-yl)sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 4-methyl-2-[(1R)-1-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1H-pyrimidin-6-one —— C14H14N4O3S
    4-methyl-2-[(1R)-1-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1H-pyrimidin-6-one
    —— 1-cyclopent-3-en-1-yl-3-[(1R)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]urea —— C17H24N2O2S
    1-cyclopent-3-en-1-yl-3-[(1R)-1-[4-(2-methoxyethylsulfanyl)phenyl]ethyl]urea
    —— 1-[(2R,4R)-4-(furan-2-yl)-4-hydroxybutan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]urea —— C17H22N2O3S
    1-[(2R,4R)-4-(furan-2-yl)-4-hydroxybutan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]urea
    —— 1-[2-(2-fluorophenyl)sulfanylethyl]-3-[(1S,2S,4R)-7-oxabicyclo[2.2.1]heptan-2-yl]urea —— C15H19FN2O2S
    1-[2-(2-fluorophenyl)sulfanylethyl]-3-[(1S,2S,4R)-7-oxabicyclo[2.2.1]heptan-2-yl]urea
    —— 1-[(2S,4S)-4-(furan-2-yl)-4-hydroxybutan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]urea —— C17H22N2O3S
    1-[(2S,4S)-4-(furan-2-yl)-4-hydroxybutan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]urea
    —— 2-[(5-tert-butyl-1,3-thiazol-2-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C14H22N2O2S2
    2-[(5-tert-butyl-1,3-thiazol-2-yl)sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— N-[(2S)-4-(furan-2-yl)-4-oxobutan-2-yl]-2-phenylsulfanylacetamide —— C16H17NO3S
    N-[(2S)-4-(furan-2-yl)-4-oxobutan-2-yl]-2-phenylsulfanylacetamide
    —— 4-methyl-2-[(1R)-1-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylethyl]-1H-pyrimidin-6-one —— C12H11F3N4OS
    4-methyl-2-[(1R)-1-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylethyl]-1H-pyrimidin-6-one
    —— 1-[(2S,4R)-4-(furan-2-yl)-4-hydroxybutan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]urea —— C17H22N2O3S
    1-[(2S,4R)-4-(furan-2-yl)-4-hydroxybutan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]urea
    —— 4-methyl-2-[(1S)-1-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1H-pyrimidin-6-one —— C14H14N4O3S
    4-methyl-2-[(1S)-1-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethyl]-1H-pyrimidin-6-one
    —— 4-methyl-2-[(1R)-1-(1,3-thiazol-2-ylsulfanyl)ethyl]-1H-pyrimidin-6-one —— C10H11N3OS2
    4-methyl-2-[(1R)-1-(1,3-thiazol-2-ylsulfanyl)ethyl]-1H-pyrimidin-6-one
    —— 4-methyl-2-[(1R)-1-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylethyl]-1H-pyrimidin-6-one —— C16H17N5OS
    4-methyl-2-[(1R)-1-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylethyl]-1H-pyrimidin-6-one
    —— 1-[(1R)-1-(1-methylpyrazol-4-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C13H19N5OS2
    1-[(1R)-1-(1-methylpyrazol-4-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— 4-methyl-2-[(1S)-1-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylethyl]-1H-pyrimidin-6-one —— C16H17N5OS
    4-methyl-2-[(1S)-1-[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylethyl]-1H-pyrimidin-6-one
    —— 1-[(1S)-1-(1-methylpyrazol-4-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea —— C13H19N5OS2
    1-[(1S)-1-(1-methylpyrazol-4-yl)ethyl]-3-[3-(1,3-thiazol-2-ylsulfanyl)propyl]urea
    —— 1-[2-(2-fluorophenyl)sulfanylethyl]-3-[(1S,2R,4R)-7-oxabicyclo[2.2.1]heptan-2-yl]urea —— C15H19FN2O2S
    1-[2-(2-fluorophenyl)sulfanylethyl]-3-[(1S,2R,4R)-7-oxabicyclo[2.2.1]heptan-2-yl]urea
    —— N-[(2R)-4-(furan-2-yl)-4-oxobutan-2-yl]-2-phenylsulfanylacetamide —— C16H17NO3S
    N-[(2R)-4-(furan-2-yl)-4-oxobutan-2-yl]-2-phenylsulfanylacetamide
    —— 1-[(2R,4S)-4-(furan-2-yl)-4-hydroxybutan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]urea —— C17H22N2O3S
    1-[(2R,4S)-4-(furan-2-yl)-4-hydroxybutan-2-yl]-3-[(4-methylsulfanylphenyl)methyl]urea
    —— 4-methyl-2-[(1S)-1-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylethyl]-1H-pyrimidin-6-one —— C12H11F3N4OS
    4-methyl-2-[(1S)-1-[4-(trifluoromethyl)pyrimidin-2-yl]sulfanylethyl]-1H-pyrimidin-6-one
    —— N-[(Z)-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)methylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C19H25N3OS
    N-[(Z)-(2,5-dimethyl-1-propan-2-ylpyrrol-3-yl)methylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(Z)-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C20H22N4O2S
    N-[(Z)-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]methylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(Z)-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]methylideneamino]-3-(4-fluorophenyl)sulfanylpropanamide —— C20H21FN4O2S
    N-[(Z)-[2,5-dimethyl-1-(5-methyl-1,2-oxazol-3-yl)pyrrol-3-yl]methylideneamino]-3-(4-fluorophenyl)sulfanylpropanamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[(Z)-1-(5-methylthiophen-2-yl)ethylideneamino]propanamide —— C16H17FN2OS2
    3-(4-fluorophenyl)sulfanyl-N-[(Z)-1-(5-methylthiophen-2-yl)ethylideneamino]propanamide
    —— 2-(4-methylphenyl)sulfanyl-N-[(Z)-1-(5-methylthiophen-2-yl)ethylideneamino]acetamide —— C16H18N2OS2
    2-(4-methylphenyl)sulfanyl-N-[(Z)-1-(5-methylthiophen-2-yl)ethylideneamino]acetamide
    —— 3-[(5E)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]propanoic acid —— C14H13NO3S3
    3-[(5E)-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]propanoic acid
    —— methyl (2R)-2-(4-fluorophenyl)-2-(2H-triazol-4-ylsulfanyl)acetate —— C11H10FN3O2S
    methyl (2R)-2-(4-fluorophenyl)-2-(2H-triazol-4-ylsulfanyl)acetate
    —— 3-[(1S)-cyclohex-2-en-1-yl]-1-ethyl-1-[(2S)-1-methylsulfonylpropan-2-yl]urea —— C13H24N2O3S
    3-[(1S)-cyclohex-2-en-1-yl]-1-ethyl-1-[(2S)-1-methylsulfonylpropan-2-yl]urea
    —— (2S)-N-(4-methylcyclohexyl)-2-(2H-triazol-4-ylsulfanyl)propanamide —— C12H20N4OS
    (2S)-N-(4-methylcyclohexyl)-2-(2H-triazol-4-ylsulfanyl)propanamide
    —— 2-[(1R)-1-ethoxyethyl]-4-(2H-triazol-4-ylsulfanylmethyl)-1,3-thiazole —— C10H14N4OS2
    2-[(1R)-1-ethoxyethyl]-4-(2H-triazol-4-ylsulfanylmethyl)-1,3-thiazole
    —— 3-[(1R)-cyclohex-2-en-1-yl]-1-ethyl-1-[(2S)-1-methylsulfonylpropan-2-yl]urea —— C13H24N2O3S
    3-[(1R)-cyclohex-2-en-1-yl]-1-ethyl-1-[(2S)-1-methylsulfonylpropan-2-yl]urea
    —— 1-[(3S,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C24H20N4O5S
    1-[(3S,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— 3-benzyl-5-[(1S)-1-(2H-triazol-4-ylsulfanyl)ethyl]-1,2,4-oxadiazole —— C13H13N5OS
    3-benzyl-5-[(1S)-1-(2H-triazol-4-ylsulfanyl)ethyl]-1,2,4-oxadiazole
    —— methyl (2S)-2-(4-fluorophenyl)-2-(2H-triazol-4-ylsulfanyl)acetate —— C11H10FN3O2S
    methyl (2S)-2-(4-fluorophenyl)-2-(2H-triazol-4-ylsulfanyl)acetate
    —— 1-[(3S,3aR,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone —— C24H20N4O5S
    1-[(3S,3aR,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]ethanone
    —— 2-[(1S)-1-ethoxyethyl]-4-(2H-triazol-4-ylsulfanylmethyl)-1,3-thiazole —— C10H14N4OS2
    2-[(1S)-1-ethoxyethyl]-4-(2H-triazol-4-ylsulfanylmethyl)-1,3-thiazole
    —— (2R)-N-(4-methylcyclohexyl)-2-(2H-triazol-4-ylsulfanyl)propanamide —— C12H20N4OS
    (2R)-N-(4-methylcyclohexyl)-2-(2H-triazol-4-ylsulfanyl)propanamide
    —— 1-[(1R)-cyclohex-2-en-1-yl]-3-[(2S)-1-methylsulfonylpropan-2-yl]urea —— C11H20N2O3S
    1-[(1R)-cyclohex-2-en-1-yl]-3-[(2S)-1-methylsulfonylpropan-2-yl]urea
    —— 3-[(1S)-cyclohex-2-en-1-yl]-1-ethyl-1-[(2R)-1-methylsulfonylpropan-2-yl]urea —— C13H24N2O3S
    3-[(1S)-cyclohex-2-en-1-yl]-1-ethyl-1-[(2R)-1-methylsulfonylpropan-2-yl]urea
    —— 1-[(1S)-cyclohex-2-en-1-yl]-3-[(2R)-1-methylsulfonylpropan-2-yl]urea —— C11H20N2O3S
    1-[(1S)-cyclohex-2-en-1-yl]-3-[(2R)-1-methylsulfonylpropan-2-yl]urea
    —— 3-[(1R)-cyclohex-2-en-1-yl]-1-ethyl-1-[(2R)-1-methylsulfonylpropan-2-yl]urea —— C13H24N2O3S
    3-[(1R)-cyclohex-2-en-1-yl]-1-ethyl-1-[(2R)-1-methylsulfonylpropan-2-yl]urea
    —— 1-[(1R)-cyclohex-2-en-1-yl]-3-[(2R)-1-methylsulfonylpropan-2-yl]urea —— C11H20N2O3S
    1-[(1R)-cyclohex-2-en-1-yl]-3-[(2R)-1-methylsulfonylpropan-2-yl]urea
    —— N-[(1S)-1-(2-bromophenyl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide —— C18H22BrN3OS
    N-[(1S)-1-(2-bromophenyl)ethyl]-3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)propanamide
    —— N-[(1R)-1-(2-bromophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide —— C16H14BrF2NOS
    N-[(1R)-1-(2-bromophenyl)ethyl]-2-(2,5-difluorophenyl)sulfanylacetamide
    —— 1-[4-[(3,5-Dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-phenylsulfanylethanone —— C17H21N3O4S2
    1-[4-[(3,5-Dimethyl-1,2-oxazol-4-yl)sulfonyl]piperazin-1-yl]-2-phenylsulfanylethanone