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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(4-ethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H18ClNO2S3
    (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(4-ethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(3-chlorophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C21H14ClNO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(3-chlorophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-methyl-2-sulfanylidene-1,3-thiazolidin-4-one —— C16H12ClNO2S3
    (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-methyl-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(2,3-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H19NO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(2,3-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(4-methylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C22H17NO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(4-methylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(3-fluorophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C21H14FNO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(3-fluorophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one —— C17H15NO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(4-bromophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C21H14BrNO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-(4-bromophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-3-benzyl-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C22H17NO2S3
    (5E)-3-benzyl-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 1-[(3R,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C21H22N6O3S
    1-[(3R,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-phenyl-2-sulfanylidene-1,3-thiazolidin-4-one —— C21H14ClNO2S3
    (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-phenyl-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (6E)-6-[(5-benzylsulfanylfuran-2-yl)methylidene]-5-imino-3-methylsulfonyl-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one —— C18H14N4O4S3
    (6E)-6-[(5-benzylsulfanylfuran-2-yl)methylidene]-5-imino-3-methylsulfonyl-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one
    —— 1-[(3S,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C21H22N6O3S
    1-[(3S,3aS,7Z)-3-(furan-2-yl)-7-(furan-2-ylmethylidene)-3a,4,5,6-tetrahydro-3H-indazol-2-yl]-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-phenyl-2-sulfanylidene-1,3-thiazolidin-4-one —— C21H15NO2S3
    (5E)-5-[(5-benzylsulfanylfuran-2-yl)methylidene]-3-phenyl-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(2-fluorophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C21H13ClFNO2S3
    (5E)-5-[[5-[(4-chlorophenyl)methylsulfanyl]furan-2-yl]methylidene]-3-(2-fluorophenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (2R)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C15H19FN4O2S
    (2R)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— N-[(3-chlorophenyl)methyl]-2-(4-fluorophenyl)sulfanylacetamide —— C15H13ClFNOS
    N-[(3-chlorophenyl)methyl]-2-(4-fluorophenyl)sulfanylacetamide
    —— (2R)-2-[[5-(2-cyclohexylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide —— C16H23N3O2S
    (2R)-2-[[5-(2-cyclohexylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide
    —— N-[(2-chlorophenyl)methyl]-3-phenylsulfanylpropanamide —— C16H16ClNOS
    N-[(2-chlorophenyl)methyl]-3-phenylsulfanylpropanamide
    —— 2-(4-chlorophenyl)sulfanyl-N-cyclopropyl-5-nitrobenzamide —— C16H13ClN2O3S
    2-(4-chlorophenyl)sulfanyl-N-cyclopropyl-5-nitrobenzamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylacetamide —— C13H12ClN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylacetamide
    —— (2R)-N-[(3-chlorophenyl)methyl]-2-phenylsulfanylpropanamide —— C16H16ClNOS
    (2R)-N-[(3-chlorophenyl)methyl]-2-phenylsulfanylpropanamide
    —— N-[(2-chlorophenyl)methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H17ClN4O2S
    N-[(2-chlorophenyl)methyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-(4-chlorophenyl)sulfanyl-N',N'-dimethyl-5-nitrobenzohydrazide —— C15H14ClN3O3S
    2-(4-chlorophenyl)sulfanyl-N',N'-dimethyl-5-nitrobenzohydrazide
    —— 3-(3,4-dimethylphenyl)sulfanyl-N',N'-dimethylpropanehydrazide —— C13H20N2OS
    3-(3,4-dimethylphenyl)sulfanyl-N',N'-dimethylpropanehydrazide
    —— 2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N',N'-dimethylacetohydrazide —— C12H13FN4O2S
    2-[[5-(4-fluorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N',N'-dimethylacetohydrazide
    —— (2S)-2-[[5-(2-cyclohexylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide —— C16H23N3O2S
    (2S)-2-[[5-(2-cyclohexylethyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-prop-2-ynylpropanamide
    —— (1S)-1-(furan-2-yl)-2-methoxy-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]ethanamine —— C16H21NO2S
    (1S)-1-(furan-2-yl)-2-methoxy-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]ethanamine
    —— (1R)-1-(furan-2-yl)-2-methoxy-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]ethanamine —— C16H21NO2S
    (1R)-1-(furan-2-yl)-2-methoxy-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]ethanamine
    —— (2S)-6-methyl-N-(2-methyl-2-methylsulfonylpropyl)hept-5-en-2-amine —— C13H27NO2S
    (2S)-6-methyl-N-(2-methyl-2-methylsulfonylpropyl)hept-5-en-2-amine
    —— (1R)-1-(furan-2-yl)-2-methoxy-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]ethanamine —— C16H21NO2S
    (1R)-1-(furan-2-yl)-2-methoxy-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]ethanamine
    —— (1S)-1-(furan-2-yl)-2-methoxy-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]ethanamine —— C16H21NO2S
    (1S)-1-(furan-2-yl)-2-methoxy-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]ethanamine
    —— (2R)-6-methyl-N-(2-methyl-2-methylsulfonylpropyl)hept-5-en-2-amine —— C13H27NO2S
    (2R)-6-methyl-N-(2-methyl-2-methylsulfonylpropyl)hept-5-en-2-amine
    —— (1R)-1-(1-methylpyrazol-4-yl)-N-[(1-phenylsulfanylcyclopropyl)methyl]ethanamine —— C16H21N3S
    (1R)-1-(1-methylpyrazol-4-yl)-N-[(1-phenylsulfanylcyclopropyl)methyl]ethanamine
    —— (5Z)-5-[[5-(4-chlorophenyl)sulfanylthiophen-2-yl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione —— C18H13ClN2O2S3
    (5Z)-5-[[5-(4-chlorophenyl)sulfanylthiophen-2-yl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— (1S)-1-(1-methylpyrazol-4-yl)-N-[(1-phenylsulfanylcyclopropyl)methyl]ethanamine —— C16H21N3S
    (1S)-1-(1-methylpyrazol-4-yl)-N-[(1-phenylsulfanylcyclopropyl)methyl]ethanamine
    —— N-[2-[(5E)-2,4-dioxo-5-(pyridin-3-ylmethylidene)-1,3-thiazolidin-3-yl]ethyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C20H21N5O4S2
    N-[2-[(5E)-2,4-dioxo-5-(pyridin-3-ylmethylidene)-1,3-thiazolidin-3-yl]ethyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— 1-[2-(1,5-dimethylpyrazol-4-yl)ethyl]-3-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]urea —— C18H26N4OS
    1-[2-(1,5-dimethylpyrazol-4-yl)ethyl]-3-[(1S)-1-(4-ethylsulfanylphenyl)ethyl]urea
    —— 1-methyl-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)-1-[(2S)-1-thiophen-3-ylpropan-2-yl]urea —— C12H16N4OS3
    1-methyl-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)-1-[(2S)-1-thiophen-3-ylpropan-2-yl]urea
    —— 1-cyclopropyl-1-[(1S)-1-(furan-2-yl)ethyl]-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea —— C13H16N4O2S2
    1-cyclopropyl-1-[(1S)-1-(furan-2-yl)ethyl]-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea
    —— 1-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)-3-[(1R,3R)-3-(trifluoromethyl)cyclohexyl]urea —— C11H15F3N4OS2
    1-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)-3-[(1R,3R)-3-(trifluoromethyl)cyclohexyl]urea
    —— 2-[(5E)-5-[(5-naphthalen-1-ylsulfanylfuran-2-yl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid —— C20H13NO4S3
    2-[(5E)-5-[(5-naphthalen-1-ylsulfanylfuran-2-yl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid
    —— (6Z)-6-[[5-(furan-2-ylmethylsulfanyl)furan-2-yl]methylidene]-5-imino-2-(trifluoromethyl)-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C16H9F3N4O3S2
    (6Z)-6-[[5-(furan-2-ylmethylsulfanyl)furan-2-yl]methylidene]-5-imino-2-(trifluoromethyl)-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— (6E)-6-[[5-(furan-2-ylmethylsulfanyl)furan-2-yl]methylidene]-5-imino-3-propan-2-ylsulfonyl-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one —— C18H16N4O5S3
    (6E)-6-[[5-(furan-2-ylmethylsulfanyl)furan-2-yl]methylidene]-5-imino-3-propan-2-ylsulfonyl-[1,2,4]thiadiazolo[4,5-a]pyrimidin-7-one
    —— (5E)-5-[[5-(furan-2-ylmethylsulfanyl)furan-2-yl]methylidene]-3-methyl-2-sulfanylidene-1,3-thiazolidin-4-one —— C14H11NO3S3
    (5E)-5-[[5-(furan-2-ylmethylsulfanyl)furan-2-yl]methylidene]-3-methyl-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 1-[(1R,2R)-2-methylcyclopropyl]-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea —— C8H12N4OS2
    1-[(1R,2R)-2-methylcyclopropyl]-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea
    —— 1-[2-(1,5-dimethylpyrazol-4-yl)ethyl]-3-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]urea —— C18H26N4OS
    1-[2-(1,5-dimethylpyrazol-4-yl)ethyl]-3-[(1R)-1-(4-ethylsulfanylphenyl)ethyl]urea
    —— (6Z)-2-ethyl-6-[[5-(furan-2-ylmethylsulfanyl)furan-2-yl]methylidene]-5-imino-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C17H14N4O3S2
    (6Z)-2-ethyl-6-[[5-(furan-2-ylmethylsulfanyl)furan-2-yl]methylidene]-5-imino-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— 1-[(1S,2R)-2-methylcyclopropyl]-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea —— C8H12N4OS2
    1-[(1S,2R)-2-methylcyclopropyl]-3-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)urea
    —— 1-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)-3-[(1R,3S)-3-(trifluoromethyl)cyclohexyl]urea —— C11H15F3N4OS2
    1-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)-3-[(1R,3S)-3-(trifluoromethyl)cyclohexyl]urea