N,N'-二庚基硫脲 | 54244-10-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫脲类
• 中文名称: N,N'-二庚基硫脲
• 英文名称: 1,3-diheptyl-thiourea
• 英文别名: N,N'-diheptyl-thiourea；N,N'-Diheptyl-thioharnstoff；N.N'-Di-n-heptyl-thioharnstoff；1,3-di-n-heptyl-2-thiourea；Thiourea, N,N'-diheptyl-；1,3-diheptylthiourea
• CAS: 54244-10-9
• 化学式: C₁₅H₃₂N₂S
• 分子量: 272.498
• InChiKey: ZVFTWKBRNQSRLB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  56.2
• 氢给体数：
  2
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N,N'-二庚基硫脲 在 铜 、 paraffin oil 作用下， 生成 正辛腈
  参考文献：
  名称：

  DE259363

  摘要：

  公开号：
• 作为产物：
  描述：

  1-异硫代氰酸庚酯 在 硫化氢 、 水 作用下， 生成 N,N'-二庚基硫脲
  参考文献：
  名称：

  Ponzio, Gazzetta Chimica Italiana, 1896, vol. 26 I, p. 326

  摘要：

  DOI：

文献信息

• Rapid and highly efficient synthesis of thioureas in biocompatible basic choline hydroxide
  作者：Najmedin Azizi、Elham Farhadi

  DOI：10.1080/17415993.2017.1327591

  日期：2017.9.3

  ABSTRACT A straightforward and convenient synthesis of symmetrical thiourea derivatives by the reaction of primary amines and carbon disulfide in biocompatible basic choline hydroxide is presented. A variety of biologically important thiourea derivatives can be obtained in good to excellent yields without a tedious work-up under mild reaction conditions. A series of primary aliphatic and aromatic amines

  摘要介绍了通过伯胺和二硫化碳在生物相容性碱性氢氧化胆碱中的反应直接和方便地合成对称硫脲衍生物。无需在温和的反应条件下进行繁琐的后处理，即可以良好至极好的收率获得多种具有生物学意义的硫脲衍生物。一系列具有不同取代官能团的脂肪族和芳香族伯胺已在较温和的反应条件和较短的反应时间内转化为硫脲衍生物。图形概要
• Studies on 1,2,4-Thiadiazolidine Derivatives. I. The Synthesis and Structural Determination of 2,4-Disubstituted 3,5-Disubstituted Imino-1,2,4-thiadiazolidines
  作者：Takeshi Kinoshita、Sadao Sato、Chihiro Tamura

  DOI：10.1246/bcsj.49.2236

  日期：1976.8

  The reaction of symmetrical thiourea derivatives, RNHCSNHR, with benzoyl peroxide (BPO) gave only one isomer of 2,4-disubstituted 3,5-disubstituted imino-1,2,4-thiadiazolidines, and that of nonsymmetrical thiourea derivatives, RNHCSNHR′, with BPO yielded a mixture of some of the possible isomeric derivatives. The structures of these compounds were determined by means of NMR, mass spectra, and X-ray

  对称硫脲衍生物 RNHCSNHR 与过氧化苯甲酰 (BPO) 的反应仅产生 2,4-二取代 3,5-二取代亚氨基-1,2,4-噻二唑烷的一种异构体，以及非对称硫脲衍生物 RNHCSNHR' 的异构体，与 BPO 产生一些可能的异构衍生物的混合物。这些化合物的结构是通过核磁共振、质谱和 X 射线分析确定的。讨论了噻二唑烷环周围基团的空间效应和一些反应机理。
• FUNCTIONALIZED HIGHLY BRANCHED MELAMINE-POLYAMINE POLYMERS
  申请人：Peretolchin Maxim

  公开号：US20120252987A1

  公开（公告）日：2012-10-04

  The present invention relates to a method for producing amphiphilic functionalized highly branched melamine-polyamine polymers by condensing melamine and optionally a melamine derivate having at least one different amine having at least two primary amino groups and optionally also with urea and/or at least one urea derivative and/or with at least one at least difunctional diisocyanate or polyisocyanate and/or at least one carbolic acid having at least two carboxyl groups or at least one derivative thereof, optionally quaternizing a portion of the amino groups of the polymer thereby obtained, reacting the polymer thus obtained with at least one compound capable of undergoing a condensation or addition reaction with amino groups, and optionally quaternizing at least part of the amino groups of the polymer obtained in the first step. The invention further relates to the amphiphilic functionalized highly branched melamine-polyamine polymers that can be obtained by the method according to the invention, and to the use thereof as surface active agents.

  本发明涉及一种通过将三聚氰胺和至少一种具有至少两个主要氨基的不同氨基的三聚氰胺衍生物以及可能还包括尿素和/或至少一种尿素衍生物和/或至少一种至少双官能团二异氰酸酯或多异氰酸酯和/或至少一种至少具有两个羧基的羧酸或其衍生物缩合，从而制备含有两性功能化的高支化三聚氰胺-多胺聚合物的方法。可选地，对所获得的聚合物的部分氨基进行季铵化，然后将所获得的聚合物与至少一种能够与氨基发生缩合或加成反应的化合物反应，并可选地对第一步中获得的聚合物的部分氨基进行季铵化。本发明还涉及通过本发明的方法可以获得的含有两性功能化的高支化三聚氰胺-多胺聚合物，以及将其用作表面活性剂的用途。
• [3-substituted-2-(substituted imino)-4-oxo-5-thiazolidinylidene]acetic
  申请人：Warner-Lambert Company

  公开号：US04775677A1

  公开（公告）日：1988-10-04

  The present invention provides novel [3-substituted-2-(substituted imino)-4-oxo-5-thiazolidinylidene]acetic acids, and novel pharmaceutical compositions and methods of use thereof. The novel acids of the invention are leukotriene antagonists having activity useful for treating asthma, allergies, cardiovascular diseases, migraines, and inflammation.

  本发明提供了新颖的[3-取代-2-(取代亚胺)-4-氧代-5-噻唑烯基]乙酸，以及新颖的药物组合物和使用方法。该发明的新颖酸是白三烯拮抗剂，具有用于治疗哮喘、过敏、心血管疾病、偏头痛和炎症的活性。
• METHODS OF DEGRADING ORGANIC POLLUTANTS AND PREVENTING OR TREATING MICROBE USING Bi2S3-CdS PARTICLES
  申请人：Imam Abdulrahman Bin Faisal University

  公开号：US20200102228A1

  公开（公告）日：2020-04-02

  Methods of synthesizing Bi 2 S 3 —CdS particles in the form of spheres as well as properties of these Bi 2 S 3 —CdS particles are described. Methods of photocatalytic degradation of organic pollutants employing these Bi 2 S 3 —CdS particles and methods of preventing or reducing microbial growth on a surface by applying these Bi 2 S 3 —CdS particles in the form of a solution or an antimicrobial product onto the surface are also specified.

  本文描述了合成球形Bi2S3-CdS颗粒的方法以及这些颗粒的性质。还介绍了利用这些Bi2S3-CdS颗粒进行光催化降解有机污染物的方法，以及通过将这些Bi2S3-CdS颗粒以溶液或抗微生物产品的形式涂布在表面上来防止或减少微生物生长的方法。