N,N'-双(乙烯基磺酰乙酰基)乙二胺 | 66710-66-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 中文名称: N,N'-双(乙烯基磺酰乙酰基)乙二胺
• 中文别名: N,N’-1,3-亚丙基二[2-(乙烯基磺酰基)]乙酰胺；乙烯双(乙烯基磺酰乙酰胺)
• 英文名称: N,N'-Bis(vinylsulfonylacetyl)ethylenediamine
• 英文别名: 2-ethenylsulfonyl-N-[2-[(2-ethenylsulfonylacetyl)amino]ethyl]acetamide
• CAS: 66710-66-5
• 化学式: C₁₀H₁₆N₂O₆S₂
• 分子量: 324.4
• InChiKey: QWZOJDWOQYTACD-UHFFFAOYSA-N

物化性质

• 熔点：
  157 °C
• 沸点：
  792.5±55.0 °C(Predicted)
• 密度：
  1.364±0.06 g/cm3(Predicted)
• 溶解度：
  在热甲醇中几乎透明
• 稳定性/保质期：

  在常温常压下，该物质是稳定的，请远离氧化剂。

计算性质

• 辛醇/水分配系数(LogP)：
  -1.4
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  143
• 氢给体数：
  2
• 氢受体数：
  6

安全信息

• 危险品标志：
  Xi

文献信息

• HYDROXYALKYL STARCH DERIVATIVES AS REACTANTS FOR COUPLING TO THIOL GROUPS
  申请人：FRESENIUS KABI DEUTSCHLAND GMBH

  公开号：US20160311934A1

  公开（公告）日：2016-10-27

  The present invention relates to a hydroxyalkyl starch (HAS) derivative of formula (I) wherein F1 is a functional group comprising the group —NR′—, with R′ being H or alkyl; L is a spacer bridging F1 and S; wherein HAS′ is the remainder of the HAS molecule, R b and R c are —[(CR 1 R 2 ) m O] n —H and are the same or different from each other; R a is —[(CR 1 R 2 ) m O] n —H with HAS′ being the remainder of the hydroxyalkyl starch molecule, or R a is HAS″ with HAS′ and HAS″ together being the remainder of the hydroxyalkyl starch molecule; R 1 and R 2 are independently hydrogen or an alkyl group having from 1 to 4 carbon atoms, m is 2 to 4, wherein R 1 and R 2 are the same or different from each other in the m groups CR 1 R 2 ; n is from 0 to 6.

  本发明涉及一种羟基烷基淀粉（HAS）衍生物，其化学式为（I），其中F1是包含基团—NR′—的功能基团，其中R′为H或烷基；L是桥接F1和S的间隔物；其中HAS′是HAS分子的剩余部分，Rband Rcare —[(CR1R2)mO]n—H，且彼此相同或不同；Ra是—[(CR1R2)mO]n—H，其中HAS′是羟基烷基淀粉分子的剩余部分，或者Ra是HAS″，其中HAS′和HAS″一起是羟基烷基淀粉分子的剩余部分；R1和R2独立地是氢或具有1至4个碳原子的烷基基团，m为2至4，其中在m个CR1R2基团中，R1和R2彼此相同或不同；n为0至6。
• Method for producing grains of aliphatic acid silver salt and thermally processed image recording material
  申请人：——

  公开号：US20010018170A1

  公开（公告）日：2001-08-30

  A method for producing grains of aliphatic acid silver salt by mixing a solution containing silver ions and a solution of aliphatic acid alkali metal salt to attain reaction of them, wherein (1) 95-100% of the total molar number to be added of the aliphatic acid alkali metal salt is added under a condition that dilution factor of the solution of aliphatic acid alkali metal salt becomes 10-fold or higher at 1 second after the addition, (2) 95-100% of the total amount to be added of silver in the solution containing silver ions is added under a condition that dilution factor of the solution containing silver ions becomes 20-fold or higher at 1 second after the addition, and (3) 50-100% of the total amount to be added of the solution of aliphatic acid alkali metal salt is added simultaneously with the solution containing silver ions. According to the present invention, there is provided a method for producing grains of aliphatic acid silver salt, which show excellent fog prevention ability, in addition, excellent fog prevention ability even after time lapse, when used in a thermally processed image recording material.

  本发明提供了一种制备脂肪族酸银盐颗粒的方法，包括将含有银离子的溶液和脂肪族酸碱金属盐的溶液混合以使它们反应，其中（1）脂肪族酸碱金属盐的总摩尔数的95-100％在加入后1秒钟时，脂肪族酸碱金属盐的稀释因子变为10倍或更高，（2）所含银离子的溶液中总添加量的95-100％在加入后1秒钟时，银离子溶液的稀释因子变为20倍或更高，（3）脂肪族酸碱金属盐溶液的总添加量的50-100％同时与含银离子的溶液一起加入。该发明提供了一种制备脂肪族酸银盐颗粒的方法，该颗粒具有出色的防雾能力，并且即使在时间流逝后，当用于热处理的图像记录材料时，仍具有出色的防雾能力。
• Bisphenol-phosphorous compound complex and thermally processed image recording material utilizing the same
  申请人：——

  公开号：US20020009683A1

  公开（公告）日：2002-01-24

  Bisphenol-phosphorus compound complexes represented by the following general formula (1) are disclosed (R 1 to R 4 represent hydrogen atom or a group that can be a substituent on a benzene ring; L represents —S— group or a —CHR 5 — group where R 5 represents hydrogen atom or an alkyl group; and R 6 to R 8 represent an alkyl group, an aryl group, a heterocyclic group etc.). The present invention provides reducing agents that can realize thermally processed image recording materials that can provide sufficient image density at a practical reaction temperature (specifically 100-140° C.) and within a practical reaction time (specifically 1-30 seconds), and can sufficiently suppress the coloration of white portions when the materials are stored in a dark place after the development.

  本发明揭示了以下一般式（1）所代表的双酚-磷化合物配合物（其中R1至R4代表氢原子或苯环上可取代基团；L代表—S—基团或—CHR5—基团，其中R5代表氢原子或烷基；R6至R8代表烷基、芳基、杂环基等）。本发明提供了还原剂，可以实现在实际反应温度（具体为100-140℃）和实际反应时间（具体为1-30秒）内提供足够的图像密度的热处理图像记录材料，并且在开发后在暗处存储材料时可以充分抑制白色部分的着色。
• Polyhalogenomethylsulfonyl compound
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US20020018955A1

  公开（公告）日：2002-02-14

  ? The object of the present invention is to provides a novel polyhalogenomethylsulfonyl compound which can be used for providing a thermally processed image recording material which has a high sensitivity, gives less fog, and has a good stock stability and a good image storage stability of dark and high temperature or light storage. According to the present invention, there is provided a polyhalogenomethylsulfonyl compound represented by the following formula (1), or salts thereof, or hydrates or solvates thereof: 1 wherein Z 1 and Z 2 each independently represents a halogen atom; A represents a hydrogen atom or a halogen atom; and R 1 represents an alkyl group having from 2 to 12 carbon atoms, which may have one or more substituents, an alkenyl group having from 2 to 12 carbon atoms, which may have one or more substituents, or an alkinyl group having from 2 to 12 carbon atoms, which may have one or more substituents.

  本发明的目的是提供一种新型的聚卤代甲基磺酰化合物，可用于提供具有高灵敏度、较少雾化、良好的库存稳定性和良好的暗高温或光存储稳定性的热处理图像记录材料。根据本发明，提供了由以下式（1）表示的聚卤代甲基磺酰化合物，或其盐，或其水合物或溶剂化物：其中Z1和Z2各自独立地表示卤素原子；A表示氢原子或卤素原子；R1表示具有2至12个碳原子的烷基基团，可以具有一个或多个取代基，具有2至12个碳原子的烯基基团，可以具有一个或多个取代基，或具有2至12个碳原子的炔基基团，可以具有一个或多个取代基。
• Method and apparatus for preparing grains of silver salt of organic acid and method for producing thermally processed image recording material
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20020058218A1

  公开（公告）日：2002-05-16

  Disclosed are a method for preparing grains of silver salt of an organic acid by reacting a solution containing silver ions and a solution containing an alkali metal salt of an organic acid, in which the reaction is performed in sealed mixing means and which comprises steps of supplying the solution containing silver ions into a reaction field solution before introduced into the sealed mixing means, and supplying the solution containing an alkali metal salt of an organic acid into the reaction field solution or sealed mixing means to which the solution containing silver ions has been supplied, etc. According to the present invention, high quality grains of silver salt of an organic acid can be efficiently produced at low cost.

  本发明公开了一种制备有机酸银盐晶粒的方法，通过反应含有银离子的溶液和含有有机酸碱金属盐的溶液，在密封混合装置中进行反应，包括将含有银离子的溶液供给到反应场溶液中，然后将其引入到密封混合装置中，以及将含有有机酸碱金属盐的溶液供给到已经供给了含有银离子的溶液的反应场溶液或密封混合装置中等步骤。根据本发明，可以高效地低成本地生产高质量的有机酸银盐晶粒。

表征谱图