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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[4-[3-(4-methoxyoxan-4-yl)phenyl]sulfanylphenyl]-N-methylmorpholin-4-amine —— C23H30N2O3S
    N-[4-[3-(4-methoxyoxan-4-yl)phenyl]sulfanylphenyl]-N-methylmorpholin-4-amine
    —— 4-[4-[4-(Dimethylamino)anilino]-1,3-thiazol-2-yl]-5-methylsulfanylthiophene-2-carboximidamide —— C17H19N5S3
    4-[4-[4-(Dimethylamino)anilino]-1,3-thiazol-2-yl]-5-methylsulfanylthiophene-2-carboximidamide
    —— 3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[[(2S)-oxolan-2-yl]methyl]-N-[(3S)-thiolan-3-yl]propanamide —— C18H27N3O3S2
    3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[[(2S)-oxolan-2-yl]methyl]-N-[(3S)-thiolan-3-yl]propanamide
    —— 3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[[(2R)-oxolan-2-yl]methyl]-N-[(3R)-thiolan-3-yl]propanamide —— C18H27N3O3S2
    3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[[(2R)-oxolan-2-yl]methyl]-N-[(3R)-thiolan-3-yl]propanamide
    —— 3-Methyl-5-(1-oxypyridin-2-yl)-8-phenylthio-1,2,3,4-tetrahydronaphthalen-1-one —— C22H19NO2S
    3-Methyl-5-(1-oxypyridin-2-yl)-8-phenylthio-1,2,3,4-tetrahydronaphthalen-1-one
    —— 3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[[(2S)-oxolan-2-yl]methyl]-N-[(3R)-thiolan-3-yl]propanamide —— C18H27N3O3S2
    3-(6-methyl-2-methylsulfanyl-4-oxo-1H-pyrimidin-5-yl)-N-[[(2S)-oxolan-2-yl]methyl]-N-[(3R)-thiolan-3-yl]propanamide
    —— [(5R)-2-methyl-5-(4-methylsulfanylphenyl)-4,5-dihydro-1,3-oxazol-4-yl]methyl methanesulfonate —— C13H17NO4S2
    [(5R)-2-methyl-5-(4-methylsulfanylphenyl)-4,5-dihydro-1,3-oxazol-4-yl]methyl methanesulfonate
    —— 2-[(Difluoromethyl)thio]thiazolo[4,5-b]pyridine —— C7H4F2N2S2
    2-[(Difluoromethyl)thio]thiazolo[4,5-b]pyridine
    —— 5-oxido-4-phenylsulfanyl-N-propan-2-yl-1,2,5-oxadiazol-5-ium-3-carboxamide —— C12H13N3O3S
    5-oxido-4-phenylsulfanyl-N-propan-2-yl-1,2,5-oxadiazol-5-ium-3-carboxamide
    —— 3-Nitro-4-(1,2,3,4-tetrahydroisoquinolin-5-ylsulfanyl)aniline —— C15H15N3O2S
    3-Nitro-4-(1,2,3,4-tetrahydroisoquinolin-5-ylsulfanyl)aniline
    —— 1-methoxy-4-allylthio-5,6,7,8-tetrahydrophthalazine —— C12H16N2OS
    1-methoxy-4-allylthio-5,6,7,8-tetrahydrophthalazine
    —— (2S)-3-phenylsulfanyl-2-[(2S)-2-sulfanylpropanoyl]oxypropanoic acid —— C12H14O4S2
    (2S)-3-phenylsulfanyl-2-[(2S)-2-sulfanylpropanoyl]oxypropanoic acid
    —— N-hydroxy-N'-(4-propan-2-ylsulfanylphenyl)methanimidamide —— C10H14N2OS
    N-hydroxy-N'-(4-propan-2-ylsulfanylphenyl)methanimidamide
    —— 2-[[4-(2-Anilinopyrimidin-4-yl)-5-methyl-1,2-oxazol-3-yl]sulfanyl]acetonitrile —— C16H13N5OS
    2-[[4-(2-Anilinopyrimidin-4-yl)-5-methyl-1,2-oxazol-3-yl]sulfanyl]acetonitrile
    —— 5-[(4-chlorophenyl)methyl]-3-hexylsulfanyl-1H-1,2,4-triazole —— C15H20ClN3S
    5-[(4-chlorophenyl)methyl]-3-hexylsulfanyl-1H-1,2,4-triazole
    —— 1-(2-Hydroxy-ethyl)-3-(2-methyl-cyclohex-2-enylmethyl)-thiourea —— C11H20N2OS
    1-(2-Hydroxy-ethyl)-3-(2-methyl-cyclohex-2-enylmethyl)-thiourea
    —— N-(3-methylbutan-2-yl)-4b,5,6,7,8,8a-hexahydro-[1]benzothiolo[2,3-d]pyrimidin-4-amine —— C15H23N3S
    N-(3-methylbutan-2-yl)-4b,5,6,7,8,8a-hexahydro-[1]benzothiolo[2,3-d]pyrimidin-4-amine
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propyl]acetamide —— C19H29BrN2O2S
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[3-[(2R,6R)-2,6-dimethylmorpholin-4-yl]propyl]acetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[3-[(2R,6S)-2,6-dimethylmorpholin-4-yl]propyl]acetamide —— C19H29BrN2O2S
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[3-[(2R,6S)-2,6-dimethylmorpholin-4-yl]propyl]acetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propyl]acetamide —— C19H29BrN2O2S
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[3-[(2S,6S)-2,6-dimethylmorpholin-4-yl]propyl]acetamide
    —— 6-(4-aminophenyl)sulfanyl-2,3-bis[(4-phenylmethoxyphenoxy)methyl]-1,4-dihydroquinoxaline-5,8-dione —— C42H35N3O6S
    6-(4-aminophenyl)sulfanyl-2,3-bis[(4-phenylmethoxyphenoxy)methyl]-1,4-dihydroquinoxaline-5,8-dione
    —— 2-[6-chloro-3-[[2,2-difluoro-2-(1-oxidopyridin-1-ium-2-yl)ethyl]amino]-2-oxopyrazin-1-yl]-N-[[2-(2,2,2-trifluoroethylsulfanyl)phenyl]methyl]acetamide —— C22H19ClF5N5O3S
    2-[6-chloro-3-[[2,2-difluoro-2-(1-oxidopyridin-1-ium-2-yl)ethyl]amino]-2-oxopyrazin-1-yl]-N-[[2-(2,2,2-trifluoroethylsulfanyl)phenyl]methyl]acetamide
    —— 1-((6-chloro-1,3-benzodioxol-5-yl) methyl)-4-(((4-methoxyphenyl) methyl) thio)-2-(phenylthio)-1H-imidazole-5-carboxylic acid —— C26H21ClN2O5S2
    1-((6-chloro-1,3-benzodioxol-5-yl) methyl)-4-(((4-methoxyphenyl) methyl) thio)-2-(phenylthio)-1H-imidazole-5-carboxylic acid
    —— N'-pyridin-2-yl-2-[[3-[(E)-2-pyridin-2-ylethenyl]-1H-indazol-6-yl]sulfanyl]benzohydrazide —— C26H20N6OS
    N'-pyridin-2-yl-2-[[3-[(E)-2-pyridin-2-ylethenyl]-1H-indazol-6-yl]sulfanyl]benzohydrazide
    —— N-[(4S)-1-benzyl-4,5,6,7-tetrahydroindazol-4-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C22H21F3N4OS
    N-[(4S)-1-benzyl-4,5,6,7-tetrahydroindazol-4-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 2-(4-bromophenyl)sulfanyl-N-cyclopropyl-N-[(2S)-3-methylbutan-2-yl]acetamide —— C16H22BrNOS
    2-(4-bromophenyl)sulfanyl-N-cyclopropyl-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-cyclopropyl-N-[(2R)-3-methylbutan-2-yl]acetamide —— C16H22BrNOS
    2-(4-bromophenyl)sulfanyl-N-cyclopropyl-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— 5-[(2,3-difluorophenyl)methylsulfanyl]-7-(pyrrolidin-3-ylamino)-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one —— C16H15F2N5OS2
    5-[(2,3-difluorophenyl)methylsulfanyl]-7-(pyrrolidin-3-ylamino)-3H-[1,3]thiazolo[4,5-d]pyrimidin-2-one
    —— N-[1-[5-[2-(dimethylamino)ethylsulfanyl]-1,3,4-oxadiazol-2-yl]-4-methyl-1-oxopentan-2-yl]cycloheptanecarboxamide —— C20H34N4O3S
    N-[1-[5-[2-(dimethylamino)ethylsulfanyl]-1,3,4-oxadiazol-2-yl]-4-methyl-1-oxopentan-2-yl]cycloheptanecarboxamide
    —— 3-[[(6S)-1-azabicyclo[3.2.1]octan-6-yl]oxy]-4-[(4-fluorophenyl)methylsulfanyl]-1,2,5-thiadiazole —— C16H18FN3OS2
    3-[[(6S)-1-azabicyclo[3.2.1]octan-6-yl]oxy]-4-[(4-fluorophenyl)methylsulfanyl]-1,2,5-thiadiazole
    —— 4-Pyrimidin-2-ylsulfanyl-1-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]quinoxaline —— C14H7F3N6S
    4-Pyrimidin-2-ylsulfanyl-1-(trifluoromethyl)-[1,2,4]triazolo[4,3-a]quinoxaline
    —— 5-[(2-propyl-3H-benzimidazol-5-yl)sulfanyl]-1,2,3,4-tetrahydroisoquinoline —— C19H21N3S
    5-[(2-propyl-3H-benzimidazol-5-yl)sulfanyl]-1,2,3,4-tetrahydroisoquinoline
    —— N-methyl-1-(pyridin-2-ylsulfanylmethyl)cyclopropan-1-amine —— C10H14N2S
    N-methyl-1-(pyridin-2-ylsulfanylmethyl)cyclopropan-1-amine
    —— 4-chloro-6-cyclopropylamino-2-methylsulfanylpyrimidine-5-carbaldehyde 444605-23-6 C9H10ClN3OS
    4-chloro-6-cyclopropylamino-2-methylsulfanylpyrimidine-5-carbaldehyde
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[(2S)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)pyrrolidin-1-yl]ethanone —— C21H23ClN6O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[(2S)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)pyrrolidin-1-yl]ethanone
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[(2R)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)pyrrolidin-1-yl]ethanone —— C21H23ClN6O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[(2R)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)pyrrolidin-1-yl]ethanone
    —— (3R)-3-[[(2S)-4-methylsulfanyl-1-phenylsulfanylbutan-2-yl]carbamoylamino]-4-phenylsulfanylbutanoic acid —— C22H28N2O3S3
    (3R)-3-[[(2S)-4-methylsulfanyl-1-phenylsulfanylbutan-2-yl]carbamoylamino]-4-phenylsulfanylbutanoic acid
    —— 6-acetyl-4-(4-dimethylaminophenylthio)-2-(4-fluorophenyl)-5-methyl-3(2H)-pyridazinone 259193-97-0 C21H20FN3O2S
    6-acetyl-4-(4-dimethylaminophenylthio)-2-(4-fluorophenyl)-5-methyl-3(2H)-pyridazinone
    —— 3-(2-Hydroxyphenyl)sulfanyl-6-(imidazol-1-ylmethyl)-1-benzothiophene-2-carboxylic acid —— C19H14N2O3S2
    3-(2-Hydroxyphenyl)sulfanyl-6-(imidazol-1-ylmethyl)-1-benzothiophene-2-carboxylic acid
    —— 3-Chloro-4-(2,4,5-trichlorophenyl)sulfanylaniline —— C12H7Cl4NS
    3-Chloro-4-(2,4,5-trichlorophenyl)sulfanylaniline
    —— N-cyclohexyl-N-[[5-(4-methoxyphenyl)sulfanylthiophen-2-yl]methyl]hydroxylamine —— C18H23NO2S2
    N-cyclohexyl-N-[[5-(4-methoxyphenyl)sulfanylthiophen-2-yl]methyl]hydroxylamine
    —— 5-[(2-Phenyl-2,3-dihydro-1-benzothiophen-5-yl)methyl]-1,3-thiazolidine-2,4-dione —— C18H15NO2S2
    5-[(2-Phenyl-2,3-dihydro-1-benzothiophen-5-yl)methyl]-1,3-thiazolidine-2,4-dione
    —— 1-[3-[3-(4-Fluorophenyl)sulfanylphenyl]cyclopent-2-en-1-yl]-1-hydroxyurea —— C18H17FN2O2S
    1-[3-[3-(4-Fluorophenyl)sulfanylphenyl]cyclopent-2-en-1-yl]-1-hydroxyurea
    —— 2-Phenylsulfanyl-3-(3-pyridin-4-ylpropoxy)pyridine —— C19H18N2OS
    2-Phenylsulfanyl-3-(3-pyridin-4-ylpropoxy)pyridine
    —— 2-{4-[(3,5-dichlorophenyl)sulfanyl]-3,5-dimethyl-1H-pyrazol-1-yl}ethanol —— C13H14Cl2N2OS
    2-{4-[(3,5-dichlorophenyl)sulfanyl]-3,5-dimethyl-1H-pyrazol-1-yl}ethanol
    —— 3-(1-Azatricyclo[3.3.1.13,7]decan-4-yl)-4-propylsulfanyl-1,2,5-thiadiazole —— C14H21N3S2
    3-(1-Azatricyclo[3.3.1.13,7]decan-4-yl)-4-propylsulfanyl-1,2,5-thiadiazole
    —— 4-[2-[2-(1H-pyrrol-2-ylsulfanyl)ethoxy]ethylsulfanyl]phenol —— C14H17NO2S2
    4-[2-[2-(1H-pyrrol-2-ylsulfanyl)ethoxy]ethylsulfanyl]phenol
    —— 3-Chloro-4-(2-chlorophenyl)sulfanylaniline;hydrochloride —— C12H10Cl3NS
    3-Chloro-4-(2-chlorophenyl)sulfanylaniline;hydrochloride
    —— 5-(4-Nitrophenyl)sulfanyl-1,2,3,4-tetrahydroisoquinoline —— C15H14N2O2S
    5-(4-Nitrophenyl)sulfanyl-1,2,3,4-tetrahydroisoquinoline
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-(furan-2-yl)propan-2-yl]acetamide —— C17H20N4O3S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-(furan-2-yl)propan-2-yl]acetamide