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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-[[(2R,4S)-4-(4-hydroxyphenyl)sulfanylpyrrolidin-2-yl]methylsulfanyl]phenol —— C17H19NO2S2
    4-[[(2R,4S)-4-(4-hydroxyphenyl)sulfanylpyrrolidin-2-yl]methylsulfanyl]phenol
    —— 2-(2,6-dimethylphenyl)sulfanyl-6-imidazol-1-yl-1H-benzimidazole —— C18H16N4S
    2-(2,6-dimethylphenyl)sulfanyl-6-imidazol-1-yl-1H-benzimidazole
    —— 5-(thiophen-2-ylmethyl)-3-(thiophen-2-ylmethylsulfanyl)-1H-1,2,4-triazole —— C12H11N3S3
    5-(thiophen-2-ylmethyl)-3-(thiophen-2-ylmethylsulfanyl)-1H-1,2,4-triazole
    —— (Z)-cyclopentyl-hydroxy-[[5-(4-methoxyphenyl)sulfanylfuran-2-yl]methylidene]azanium —— C17H20NO3S+
    (Z)-cyclopentyl-hydroxy-[[5-(4-methoxyphenyl)sulfanylfuran-2-yl]methylidene]azanium
    —— 3-(6-Pyridin-2-ylsulfanylpyridin-3-yl)-3,10-diazabicyclo[4.3.1]decane —— C18H22N4S
    3-(6-Pyridin-2-ylsulfanylpyridin-3-yl)-3,10-diazabicyclo[4.3.1]decane
    —— 3,3,3-Trifluoropropyl 2-(4-pyrazol-1-ylpyrimidin-2-yl)sulfanylacetate —— C12H11F3N4O2S
    3,3,3-Trifluoropropyl 2-(4-pyrazol-1-ylpyrimidin-2-yl)sulfanylacetate
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-ethylphenyl)ethyl]acetamide —— C24H28N4OS
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-ethylphenyl)ethyl]acetamide
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C18H22N4O3S2
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]-N-methylacetamide —— C23H25FN4OS
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-fluorophenyl)ethyl]-N-methylacetamide
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]-N-methylacetamide —— C23H25FN4OS
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]-N-methylacetamide
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C18H22N4O3S2
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl]acetamide —— C23H33N5O2S
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2R)-4-(2-methylpropyl)morpholin-2-yl]methyl]acetamide
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl]acetamide —— C23H33N5O2S
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[[(2S)-4-(2-methylpropyl)morpholin-2-yl]methyl]acetamide
    —— (3R)-3-[[5-[[2-[(4-chlorophenyl)methyl]-1,3-thiazol-4-yl]methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide —— C19H21ClN4O2S3
    (3R)-3-[[5-[[2-[(4-chlorophenyl)methyl]-1,3-thiazol-4-yl]methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide
    —— (3S)-3-[[5-[[2-[(4-chlorophenyl)methyl]-1,3-thiazol-4-yl]methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide —— C19H21ClN4O2S3
    (3S)-3-[[5-[[2-[(4-chlorophenyl)methyl]-1,3-thiazol-4-yl]methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]thiolane 1,1-dioxide
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide —— C24H28N4OS
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide
    —— 2-[(4-chlorophenyl)methyl]-4-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole —— C22H21ClN4OS3
    2-[(4-chlorophenyl)methyl]-4-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole
    —— (3S)-3-[5-[[2-[(4-chlorophenyl)methyl]-1,3-thiazol-4-yl]methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C18H19ClN4O2S3
    (3S)-3-[5-[[2-[(4-chlorophenyl)methyl]-1,3-thiazol-4-yl]methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— 2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C22H30N4O3S2
    2-[(5-benzyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-N-butyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— (3R)-3-[5-[[2-[(4-chlorophenyl)methyl]-1,3-thiazol-4-yl]methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide —— C18H19ClN4O2S3
    (3R)-3-[5-[[2-[(4-chlorophenyl)methyl]-1,3-thiazol-4-yl]methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]thiolane 1,1-dioxide
    —— 3-[(5R,6R)-1-azabicyclo[3.2.1]octan-6-yl]-4-[5-[[4-[(5R,6R)-1-azabicyclo[3.2.1]octan-6-yl]-1,2,5-thiadiazol-3-yl]sulfanyl]-3-methylpentyl]sulfanyl-1,2,5-thiadiazole —— C24H36N6S4
    3-[(5R,6R)-1-azabicyclo[3.2.1]octan-6-yl]-4-[5-[[4-[(5R,6R)-1-azabicyclo[3.2.1]octan-6-yl]-1,2,5-thiadiazol-3-yl]sulfanyl]-3-methylpentyl]sulfanyl-1,2,5-thiadiazole
    —— 3,5-dichloro-N-[3-chloro-4-[(6-methyl-1,3-benzothiazol-2-yl)sulfanyl]phenyl]benzenesulfonamide —— C20H13Cl3N2O2S3
    3,5-dichloro-N-[3-chloro-4-[(6-methyl-1,3-benzothiazol-2-yl)sulfanyl]phenyl]benzenesulfonamide
    —— (2R)-2-amino-3-(3-hydroxypropylsulfanyl)propanal —— C6H13NO2S
    (2R)-2-amino-3-(3-hydroxypropylsulfanyl)propanal
    —— 2-[[5-(2-Ethyl-5-methylpyrazol-3-yl)-4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-5-nitro-1,3-thiazole —— C15H19N7O3S2
    2-[[5-(2-Ethyl-5-methylpyrazol-3-yl)-4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]-5-nitro-1,3-thiazole
    —— 2-(1-Benzylsulfonylpyrrolidin-2-yl)sulfanylphenol —— C17H19NO3S2
    2-(1-Benzylsulfonylpyrrolidin-2-yl)sulfanylphenol
    —— [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)methyl]piperazin-1-yl]methanone —— C19H23N3O2S
    [(2R)-2,3-dihydro-1-benzothiophen-2-yl]-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)methyl]piperazin-1-yl]methanone
    —— [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)methyl]piperazin-1-yl]methanone —— C19H23N3O2S
    [(2S)-2,3-dihydro-1-benzothiophen-2-yl]-[4-[(3,5-dimethyl-1,2-oxazol-4-yl)methyl]piperazin-1-yl]methanone
    —— (2R,7S,8S,8aR)-2-phenyl-7-phenylsulfanyl-4a,5,6,7,8,8a-hexahydro-4H-[1,3]dioxino[5,4-b]pyridin-8-ol —— C19H21NO3S
    (2R,7S,8S,8aR)-2-phenyl-7-phenylsulfanyl-4a,5,6,7,8,8a-hexahydro-4H-[1,3]dioxino[5,4-b]pyridin-8-ol
    —— 3-Chloro-4-naphthalen-1-ylsulfanylaniline;hydrochloride —— C16H13Cl2NS
    3-Chloro-4-naphthalen-1-ylsulfanylaniline;hydrochloride
    —— 3-[(3R)-1-azabicyclo[2.2.1]heptan-3-yl]-4-butylsulfanyl-1,2,5-thiadiazole —— C12H19N3S2
    3-[(3R)-1-azabicyclo[2.2.1]heptan-3-yl]-4-butylsulfanyl-1,2,5-thiadiazole
    —— N'-(2-ethylsulfanylphenyl)ethane-1,2-diamine;dihydrochloride —— C10H18Cl2N2S
    N'-(2-ethylsulfanylphenyl)ethane-1,2-diamine;dihydrochloride
    —— (3E)-N-methyl-4-(5-ethylthio-3-pyridinyl)-3-buten-1-amine —— C12H18N2S
    (3E)-N-methyl-4-(5-ethylthio-3-pyridinyl)-3-buten-1-amine
    —— 4-(5-methyl-3-propan-2-ylsulfanyl-1,2-oxazol-4-yl)-N-phenylpyrimidin-2-amine —— C17H18N4OS
    4-(5-methyl-3-propan-2-ylsulfanyl-1,2-oxazol-4-yl)-N-phenylpyrimidin-2-amine
    —— [(Z)-2-methyl-4-phenylsulfanylbut-2-enyl] trifluoromethanesulfonate —— C12H13F3O3S2
    [(Z)-2-methyl-4-phenylsulfanylbut-2-enyl] trifluoromethanesulfonate
    —— Ethyl 2-[4-(4-chloropyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate —— C11H11ClN4O2S
    Ethyl 2-[4-(4-chloropyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate
    —— 4-[4-(3-Hydroxy-3-methyl-butylsulfanyl)-phenylsulfanyl]-2-methyl-butan-2-ol —— C16H26O2S2
    4-[4-(3-Hydroxy-3-methyl-butylsulfanyl)-phenylsulfanyl]-2-methyl-butan-2-ol
    —— 3-(2-ethylhexylsulfanyl)-1H-1,2,4-triazol-5-amine —— C10H20N4S
    3-(2-ethylhexylsulfanyl)-1H-1,2,4-triazol-5-amine
    —— 5-[(4-chlorophenyl)methyl]-3-(cyclohexylmethylsulfanyl)-1H-1,2,4-triazole —— C16H20ClN3S
    5-[(4-chlorophenyl)methyl]-3-(cyclohexylmethylsulfanyl)-1H-1,2,4-triazole
    —— 2-[(2S,4S)-2-amino-1-hydroxy-6-methylheptan-4-yl]sulfanyl-6-methylpyridine-3-carbonitrile —— C15H23N3OS
    2-[(2S,4S)-2-amino-1-hydroxy-6-methylheptan-4-yl]sulfanyl-6-methylpyridine-3-carbonitrile
    —— 4-Methylsulfanyl-10,12,13,14,15,16-hexazatetracyclo[7.7.0.02,7.011,15]hexadeca-1(16),2(7),3,5,9,11,13-heptaen-8-one —— C11H6N6OS
    4-Methylsulfanyl-10,12,13,14,15,16-hexazatetracyclo[7.7.0.02,7.011,15]hexadeca-1(16),2(7),3,5,9,11,13-heptaen-8-one
    —— 3-(furan-3-ylmethylsulfanyl)-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole —— C12H11N3OS2
    3-(furan-3-ylmethylsulfanyl)-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole
    —— 4-(3-Amino-1,2,4-triazin-5-yl)-3-ethyl-5-methylsulfanylthiophene-2-carbonitrile —— C11H11N5S2
    4-(3-Amino-1,2,4-triazin-5-yl)-3-ethyl-5-methylsulfanylthiophene-2-carbonitrile
    —— N-phenyl-5-(phenylsulfanylmethyl)-1H-1,2,4-triazol-3-amine —— C15H14N4S
    N-phenyl-5-(phenylsulfanylmethyl)-1H-1,2,4-triazol-3-amine
    —— 5-(2-Methylsulfanylpyridin-3-yl)-3-pyridin-2-yl-1,2,4-oxadiazole —— C13H10N4OS
    5-(2-Methylsulfanylpyridin-3-yl)-3-pyridin-2-yl-1,2,4-oxadiazole
    —— (2S)-N-[(1S,3S)-3-methylcyclohexyl]-2-methylsulfonylpropanamide —— C11H21NO3S
    (2S)-N-[(1S,3S)-3-methylcyclohexyl]-2-methylsulfonylpropanamide
    —— (2S)-N-[(1S,3R)-3-methylcyclohexyl]-2-methylsulfonylpropanamide —— C11H21NO3S
    (2S)-N-[(1S,3R)-3-methylcyclohexyl]-2-methylsulfonylpropanamide
    —— (2S)-N-[(1R,3R)-3-methylcyclohexyl]-2-methylsulfonylpropanamide —— C11H21NO3S
    (2S)-N-[(1R,3R)-3-methylcyclohexyl]-2-methylsulfonylpropanamide
    —— (2S)-N-[(1R,3S)-3-methylcyclohexyl]-2-methylsulfonylpropanamide —— C11H21NO3S
    (2S)-N-[(1R,3S)-3-methylcyclohexyl]-2-methylsulfonylpropanamide
    —— 6-acetyl-2-(4-fluorophenyl)-5-methyl-4-(4-methylsulfonylaminophenylthio)-3(2H)-pyridazinone 259193-93-6 C20H18FN3O4S2
    6-acetyl-2-(4-fluorophenyl)-5-methyl-4-(4-methylsulfonylaminophenylthio)-3(2H)-pyridazinone
    —— (E)-N-[4-(2,5-dioxo-3-phenylsulfanylpyrrolidin-1-yl)butyl]-3-pyridin-3-ylprop-2-enamide —— C22H23N3O3S
    (E)-N-[4-(2,5-dioxo-3-phenylsulfanylpyrrolidin-1-yl)butyl]-3-pyridin-3-ylprop-2-enamide