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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4S)-4,5-dihydro-4-isopropyl-2-<2-(phenylsulfanyl)phenyl>-1,3-oxazole 154260-44-3 C18H19NOS
    (4S)-4,5-dihydro-4-isopropyl-2-<2-(phenylsulfanyl)phenyl>-1,3-oxazole
    —— 5-(benzylthio)pyrimidine 1240790-10-6 C11H10N2S
    5-(benzylthio)pyrimidine
    —— 2-(4-trifluoromethyl-2-aminophenylthio) benzonitrile 190328-50-8 C14H9F3N2S
    2-(4-trifluoromethyl-2-aminophenylthio) benzonitrile
    —— 2,4-dichloro-N-[3,5-dichloro-4-(5-cyano-benzothiazol-2-ylsulfanyl)-phenyl]-benzenesulfonamide 315225-31-1 C20H9Cl4N3O2S3
    2,4-dichloro-N-[3,5-dichloro-4-(5-cyano-benzothiazol-2-ylsulfanyl)-phenyl]-benzenesulfonamide
    —— 2,4-Dichloro-N-{3,5-dichloro-4-[5-(1H-tetrazol-5-yl)-benzothiazol-2-ylsulfanyl]-phenyl}-benzenesulfonamide 315225-39-9 C20H10Cl4N6O2S3
    2,4-Dichloro-N-{3,5-dichloro-4-[5-(1H-tetrazol-5-yl)-benzothiazol-2-ylsulfanyl]-phenyl}-benzenesulfonamide
    —— 5-methyl-5-(phenylthio)hex-1-en-3-ol 477482-27-2 C13H18OS
    5-methyl-5-(phenylthio)hex-1-en-3-ol
    —— 2-(1,3-Dithiol-2-ylidene)-5-[2-[2-[2-(oxan-2-yloxy)ethoxy]ethoxy]ethyl]-[1,3]dithiolo[4,5-c]pyrrole 929557-78-8 C19H25NO4S4
    2-(1,3-Dithiol-2-ylidene)-5-[2-[2-[2-(oxan-2-yloxy)ethoxy]ethoxy]ethyl]-[1,3]dithiolo[4,5-c]pyrrole
    —— (1R)-(+)-1-[3-(methylsulfanyl)phenyl]ethylamine 368447-79-4 C9H13NS
    (1R)-(+)-1-[3-(methylsulfanyl)phenyl]ethylamine
    —— N-{(1R)-1-[3-(methylsulfanyl)phenyl]ethyl}-3-phenyl-1-propanamide 368447-81-8 C18H21NOS
    N-{(1R)-1-[3-(methylsulfanyl)phenyl]ethyl}-3-phenyl-1-propanamide
    —— 1,1-bis(phenylthio)-3-methylbut-2-ene 71341-94-1 C17H18S2
    1,1-bis(phenylthio)-3-methylbut-2-ene
    —— 2,2-Bis(phenylsulfanyl)acetyl chloride 98834-76-5 C14H11ClOS2
    2,2-Bis(phenylsulfanyl)acetyl chloride
    —— 2-benzyl-4-butyl-5-(methylthio)pyridazin-3(2H)-one 1200133-61-4 C16H20N2OS
    2-benzyl-4-butyl-5-(methylthio)pyridazin-3(2H)-one
    —— 3-p-Tolylthio-2-methyl-3-buten-2-ol 82782-26-1 C12H16OS
    3-p-Tolylthio-2-methyl-3-buten-2-ol
    —— 1-(1-phenylsulfanylvinyl)cyclopentanol 141928-32-7 C13H16OS
    1-(1-phenylsulfanylvinyl)cyclopentanol
    —— 2-fluoro-6-((5-phenyl-2-(phenylthio)pent-1-en-3-yl)oxy)pyridine 1334484-19-3 C22H20FNOS
    2-fluoro-6-((5-phenyl-2-(phenylthio)pent-1-en-3-yl)oxy)pyridine
    —— 2-(6-fluoropyridin-2-ylsulfanyl)ethamine 838892-88-9 C7H9FN2S
    2-(6-fluoropyridin-2-ylsulfanyl)ethamine
    —— (Z)-2-methyl-3,4-bis(phenylthio)but-3-en-2-ol 137540-60-4 C17H18OS2
    (Z)-2-methyl-3,4-bis(phenylthio)but-3-en-2-ol
    —— 2-methyl-3-(phenylthio)-2-pentene 85895-10-9 C12H16S
    2-methyl-3-(phenylthio)-2-pentene
    —— 4-methylthio-2-oxo-6-phenyl-2H-pyran-5-carbonitrile 667897-81-6 C13H9NO2S
    4-methylthio-2-oxo-6-phenyl-2H-pyran-5-carbonitrile
    —— 4,5-dihydro-1-[4-(methylthio)phenyl]-2-(3-pyridinyl)-1H-imidazole-4-carbonitrile 298205-06-8 C16H14N4S
    4,5-dihydro-1-[4-(methylthio)phenyl]-2-(3-pyridinyl)-1H-imidazole-4-carbonitrile
    —— 4-(1H-1,2.3-triazol-4-ylthio)benzonitrile 917382-33-3 C9H6N4S
    4-(1H-1,2.3-triazol-4-ylthio)benzonitrile
    —— Isopropyl-methylthioketon 17197-53-4 C5H10S
    Isopropyl-methylthioketon
    —— 4-(difluoromethyl)-4,5-dihydro-1-[4-(methylthio)phenyl]-2-(3-pyridinyl)-1H-imidazol-4-ol 298205-01-3 C16H15F2N3OS
    4-(difluoromethyl)-4,5-dihydro-1-[4-(methylthio)phenyl]-2-(3-pyridinyl)-1H-imidazol-4-ol
    —— 6-isopropyl-4-methylsulfanyl-2-oxo-2H-pyran-3-carbonitrile 916065-57-1 C10H11NO2S
    6-isopropyl-4-methylsulfanyl-2-oxo-2H-pyran-3-carbonitrile
    —— N-(2-methoxy-2-propenyl)-N-[4-(methylthio)phenyl]-3-pyridinecarboximidamide 298205-03-5 C17H19N3OS
    N-(2-methoxy-2-propenyl)-N-[4-(methylthio)phenyl]-3-pyridinecarboximidamide
    —— 2,2-Dimethyl-propionic acid 3-pyridin-3-yl-[1,2,4]oxadiazol-5-ylsulfanylmethyl ester 345631-81-4 C13H15N3O3S
    2,2-Dimethyl-propionic acid 3-pyridin-3-yl-[1,2,4]oxadiazol-5-ylsulfanylmethyl ester
    —— 4-(2-(thiazolo[5,4-b]pyridin-2-ylamino)pyridin-3-ylthio)benzonitrile 953043-21-5 C18H11N5S2
    4-(2-(thiazolo[5,4-b]pyridin-2-ylamino)pyridin-3-ylthio)benzonitrile
    —— methyl 3-(2-(thiazolo[5,4-b]pyridin-2-ylamino)pyridin-3-ylthio)propanoate 953045-54-0 C15H14N4O2S2
    methyl 3-(2-(thiazolo[5,4-b]pyridin-2-ylamino)pyridin-3-ylthio)propanoate
    —— 6-[2-(5-methylfuryl)]-4-methylthio-2-oxo-2H-pyran-3-carbonitrile 905577-90-4 C12H9NO3S
    6-[2-(5-methylfuryl)]-4-methylthio-2-oxo-2H-pyran-3-carbonitrile
    —— 4-(2-(trifluoromethoxy)phenylthio)benzonitrile 1407972-27-3 C14H8F3NOS
    4-(2-(trifluoromethoxy)phenylthio)benzonitrile
    —— bis(2-methylthiopropionic) thioanhydride 64035-95-6 C8H14S3
    bis(2-methylthiopropionic) thioanhydride
    —— 1-(nonafluorobutanesulfonyl)-3,3-dimethylbutan-2-one 445380-80-3 C10H11F9O3S
    1-(nonafluorobutanesulfonyl)-3,3-dimethylbutan-2-one
    —— 3-Ethynylsulfonylprop-1-ynyl(trimethyl)silane 934295-61-1 C8H12O2SSi
    3-Ethynylsulfonylprop-1-ynyl(trimethyl)silane
    —— 4-[(4-chloro-3-methoxyphenyl)thio]benzonitrile 1257087-37-8 C14H10ClNOS
    4-[(4-chloro-3-methoxyphenyl)thio]benzonitrile
    —— 4-(3,5-difluorophenylsulfanyl)benzonitrile 1450723-64-4 C13H7F2NS
    4-(3,5-difluorophenylsulfanyl)benzonitrile
    —— 4-((3-(trifluoromethoxy)phenyl)thio)benzonitrile 1362160-55-1 C14H8F3NOS
    4-((3-(trifluoromethoxy)phenyl)thio)benzonitrile
    —— (2S)-2-[(2R,5S)-2-cyclohexyl-2-phenyl-1,3-oxathiolan-5-yl]-1-methylpyrrolidine 934271-87-1 C20H29NOS
    (2S)-2-[(2R,5S)-2-cyclohexyl-2-phenyl-1,3-oxathiolan-5-yl]-1-methylpyrrolidine
    —— 2-<(2-amino-3-bromo-5-methylphenyl)thio>ethanol 166818-81-1 C9H12BrNOS
    2-<(2-amino-3-bromo-5-methylphenyl)thio>ethanol
    —— 4-(3-(trifluoromethyl)phenylthio)benzonitrile 1374864-77-3 C14H8F3NS
    4-(3-(trifluoromethyl)phenylthio)benzonitrile
    —— allyl(n-butyl)sulfide 5399-19-9 C7H14S
    allyl(n-butyl)sulfide
    —— N-methyl-3-(phenylthio)propionamide 89024-23-7 C10H13NOS
    N-methyl-3-(phenylthio)propionamide
    —— N-2,2-trimethyl-3-(phenylthio)-propionamide 89024-20-4 C12H17NOS
    N-2,2-trimethyl-3-(phenylthio)-propionamide
    —— N-[(1S)-2,2-difluoro-1-(furan-2-yl)-2-phenylsulfanylethyl]prop-2-en-1-amine 938463-91-3 C15H15F2NOS
    N-[(1S)-2,2-difluoro-1-(furan-2-yl)-2-phenylsulfanylethyl]prop-2-en-1-amine
    —— 2-tert-butyl-2-methyl-1,3-dithiane 37754-53-3 C9H18S2
    2-tert-butyl-2-methyl-1,3-dithiane
    —— 2,2-Dimethyl-3-(oxo-lambda~4~-sulfanylidene)butane 133619-37-1 C6H12OS
    2,2-Dimethyl-3-(oxo-lambda~4~-sulfanylidene)butane
    —— 2-(t-butyl)-2-methyl-1,3-dithiolane 26785-73-9 C8H16S2
    2-(t-butyl)-2-methyl-1,3-dithiolane
    —— (2S)-2-[(2S,5S)-2-cyclohexyl-2-phenyl-1,3-oxathiolan-5-yl]-1-methylpyrrolidine 934271-88-2 C20H29NOS
    (2S)-2-[(2S,5S)-2-cyclohexyl-2-phenyl-1,3-oxathiolan-5-yl]-1-methylpyrrolidine
    —— (2R)-2-[(2S,5R)-2-cyclohexyl-2-phenyl-1,3-oxathiolan-5-yl]-1-methylpyrrolidine 934271-89-3 C20H29NOS
    (2R)-2-[(2S,5R)-2-cyclohexyl-2-phenyl-1,3-oxathiolan-5-yl]-1-methylpyrrolidine
    —— 5-ethyl-2-methylthio-6-{3-[(5-ethyl-2-piperidinyl-pyrimidin-4(1H,3H)-yl)methyl]benzyl}pyrimidine-2,4(1H,3H)-one 938183-90-5 C26H33N5O2S
    5-ethyl-2-methylthio-6-{3-[(5-ethyl-2-piperidinyl-pyrimidin-4(1H,3H)-yl)methyl]benzyl}pyrimidine-2,4(1H,3H)-one
    —— 3-iodo-5-phenylsulfanyl-1H-pyrrolo[2,3-b]pyridine 923583-56-6 C13H9IN2S
    3-iodo-5-phenylsulfanyl-1H-pyrrolo[2,3-b]pyridine