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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— S-(2-Pyridyl) (1S,3aR,4S,5R,7aS)-1-ethyl-5-<2-(trimethylsilyl)ethynyl>-2,3,3a,4,5,7a-hexahydro-1H-indene-4-carboxythiolate 153868-82-7 C22H29NOSSi
    S-(2-Pyridyl) (1S,3aR,4S,5R,7aS)-1-ethyl-5-<2-(trimethylsilyl)ethynyl>-2,3,3a,4,5,7a-hexahydro-1H-indene-4-carboxythiolate
    —— 2-(2-ethylsulfanyl-6-oxo-1H-pyrimidin-4-yl)-2-phenylacetonitrile 936568-81-9 C14H13N3OS
    2-(2-ethylsulfanyl-6-oxo-1H-pyrimidin-4-yl)-2-phenylacetonitrile
    —— pentyl 2-pyridyl sulfide 90547-38-9 C10H15NS
    pentyl 2-pyridyl sulfide
    —— S-pyridin-2-yl hept-6-enethioate 1226949-08-1 C12H15NOS
    S-pyridin-2-yl hept-6-enethioate
    —— 14-Hydroxy-tetradecanethioic acid S-pyridin-2-yl ester 61888-27-5 C19H31NO2S
    14-Hydroxy-tetradecanethioic acid S-pyridin-2-yl ester
    —— S-pyridin-2-yl oct-7-enethioate 1226949-09-2 C13H17NOS
    S-pyridin-2-yl oct-7-enethioate
    —— S-2-pyridyl (tert-butyldimethylsiloxy)thioacetate 956317-83-2 C13H21NO2SSi
    S-2-pyridyl (tert-butyldimethylsiloxy)thioacetate
    —— Cyclohexene, 3-[[2,2,2-trifluoro-1-(trifluoromethyl)ethyl]thio]- 67263-11-0 C9H10F6S
    Cyclohexene, 3-[[2,2,2-trifluoro-1-(trifluoromethyl)ethyl]thio]-
    —— S-pyridin-2-yl hex-5-enethioate 532989-95-0 C11H13NOS
    S-pyridin-2-yl hex-5-enethioate
    —— 3-(4-Chlorophenyl)sulfanyl-1,1,1-trifluoropropan-2-one 92682-40-1 C9H6ClF3OS
    3-(4-Chlorophenyl)sulfanyl-1,1,1-trifluoropropan-2-one
    —— N-[2-(2-pyridylsulfo)ethyl]morpholine 349445-41-6 C11H16N2OS
    N-[2-(2-pyridylsulfo)ethyl]morpholine
    —— 6,6-dimethyl-3-methylthio-4-oxo-4,5,6,7-tetrahydro-2-benzothiophene-1-carbothioamide 207307-82-2 C12H15NOS3
    6,6-dimethyl-3-methylthio-4-oxo-4,5,6,7-tetrahydro-2-benzothiophene-1-carbothioamide
    —— 2-cyclopentylsulfanyl-4-hydroxy-1H-pyrimidin-6-one 933879-61-9 C9H12N2O2S
    2-cyclopentylsulfanyl-4-hydroxy-1H-pyrimidin-6-one
    —— 6,6-Dimethyl-1-((4-trifluoromethyl)thiazol-2-yl)-3-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one 207306-55-6 C15H14F3NOS3
    6,6-Dimethyl-1-((4-trifluoromethyl)thiazol-2-yl)-3-methylthio-4,5,6,7-tetrahydrobenzo[c]thiophen-4-one
    —— [(2R,3R)-2-[(2-oxo-2-pyridin-2-ylsulfanylethoxy)methyl]oxan-3-yl] 2-[[(2R,3R)-3-hydroxyoxan-2-yl]methoxy]acetate 740845-50-5 C21H29NO8S
    [(2R,3R)-2-[(2-oxo-2-pyridin-2-ylsulfanylethoxy)methyl]oxan-3-yl] 2-[[(2R,3R)-3-hydroxyoxan-2-yl]methoxy]acetate
    —— dithiocarbonic acid O-ethyl ester S-(2-oxo-3,3,3-trifluoropropyl) ester 879688-14-9 C6H7F3O2S2
    dithiocarbonic acid O-ethyl ester S-(2-oxo-3,3,3-trifluoropropyl) ester
    —— 2-Cyano-2-methyl-4H-3,1-benzoxathiin 135216-87-4 C10H9NOS
    2-Cyano-2-methyl-4H-3,1-benzoxathiin
    —— 2-benzyloxymethyl-4-isopropyl-5-(3-methoxy-phenylsulfanyl)-1H-imidazole 620969-32-6 C21H24N2O2S
    2-benzyloxymethyl-4-isopropyl-5-(3-methoxy-phenylsulfanyl)-1H-imidazole
    —— iso-butyldisulfanyl-acetic acid 220700-07-2 C6H12O2S2
    iso-butyldisulfanyl-acetic acid
    —— N-(4-methylthio-phenyl)benzamidine 613663-88-0 C14H14N2S
    N-(4-methylthio-phenyl)benzamidine
    —— 2-(2-Pyridin-2-ylsulfanylphenyl)sulfanylpyridine 1071150-76-9 C16H12N2S2
    2-(2-Pyridin-2-ylsulfanylphenyl)sulfanylpyridine
    —— (2R)-3-methyl-2-mercaptobutanol 126424-40-6 C5H12OS
    (2R)-3-methyl-2-mercaptobutanol
    —— N-(4-Methylsulfanyl-phenyl)-pyridine-2-carboxamidine 812692-63-0 C13H13N3S
    N-(4-Methylsulfanyl-phenyl)-pyridine-2-carboxamidine
    —— 1-(2-Hydroxy-ethoxymethyl)-5-methyl-6-(pyridin-2-ylsulfanyl)-1H-pyrimidine-2,4-dione 189637-41-0 C13H15N3O4S
    1-(2-Hydroxy-ethoxymethyl)-5-methyl-6-(pyridin-2-ylsulfanyl)-1H-pyrimidine-2,4-dione
    —— 4-methyl-N'-(4-methylsulfanylphenyl)benzenecarboximidamide 812692-53-8 C15H16N2S
    4-methyl-N'-(4-methylsulfanylphenyl)benzenecarboximidamide
    —— S-pyridin-2-yl 2-[(2S,3S,4S,6R)-6-[(2S)-2-hydroxy-2-[(1S,2S)-2-methylcyclopropyl]ethyl]-3-methyl-4-tri(propan-2-yl)silyloxyoxan-2-yl]ethanethioate 870096-02-9 C28H47NO4SSi
    S-pyridin-2-yl 2-[(2S,3S,4S,6R)-6-[(2S)-2-hydroxy-2-[(1S,2S)-2-methylcyclopropyl]ethyl]-3-methyl-4-tri(propan-2-yl)silyloxyoxan-2-yl]ethanethioate
    —— 2-(naphthalen-1-ylthio)pyridine 92498-41-4 C15H11NS
    2-(naphthalen-1-ylthio)pyridine
    —— N'-(4-methylsulfanylphenyl)pyridine-4-carboximidamide 812692-61-8 C13H13N3S
    N'-(4-methylsulfanylphenyl)pyridine-4-carboximidamide
    —— [3-(3-Chloro-1,1,2,2,3,3-hexafluoro-propoxy)-1,1,2,2,3,3-hexafluoro-propoxy]-difluoro-thioacetic acid S-pyridin-2-yl ester 380239-48-5 C13H4ClF14NO3S
    [3-(3-Chloro-1,1,2,2,3,3-hexafluoro-propoxy)-1,1,2,2,3,3-hexafluoro-propoxy]-difluoro-thioacetic acid S-pyridin-2-yl ester
    —— 4-(2-pyridylthio)-3,5-dimethylphenol 59089-58-6 C13H13NOS
    4-(2-pyridylthio)-3,5-dimethylphenol
    —— 5-methyl-N-[4-(methylthio)phenyl]-2-pyridinecarboximidamide 177662-56-5 C14H15N3S
    5-methyl-N-[4-(methylthio)phenyl]-2-pyridinecarboximidamide
    —— (perfluorophenyl)(o-tolyl)sulfane 1374639-69-6 C13H7F5S
    (perfluorophenyl)(o-tolyl)sulfane
    —— 5-methyl-2-[4-hydroxy-1-[4-(methylthio)phenyl]-4-(trifluoromethyl)-4,5-dihydro-1H-imidazol-2-yl]pyridine 177662-57-6 C17H16F3N3OS
    5-methyl-2-[4-hydroxy-1-[4-(methylthio)phenyl]-4-(trifluoromethyl)-4,5-dihydro-1H-imidazol-2-yl]pyridine
    —— S-pyridin-2-yl 4-phenylbutanethioate 76063-11-1 C15H15NOS
    S-pyridin-2-yl 4-phenylbutanethioate
    —— (all-Z)-Octadeca-3,6,9,12,15-pentaene-1-thiol 300552-99-2 C18H28S
    (all-Z)-Octadeca-3,6,9,12,15-pentaene-1-thiol
    —— 4-mercapto-4-methylbutan-1-ol 90325-01-2 C5H12OS
    4-mercapto-4-methylbutan-1-ol
    —— tridec-1-ene-3-thiol 909025-52-1 C13H26S
    tridec-1-ene-3-thiol
    —— 6-Hydroxy-2-(isopropylthio)pyrimidin-4(3H)-one 1026862-83-8 C7H10N2O2S
    6-Hydroxy-2-(isopropylthio)pyrimidin-4(3H)-one
    —— S-pyridin-2-yl 5,5-dimethyl-1,3-dioxane-2-carbothioate 744220-88-0 C12H15NO3S
    S-pyridin-2-yl 5,5-dimethyl-1,3-dioxane-2-carbothioate
    —— S-(pyridin-2-yl) 3-cyclohexylpropanethioate 749928-21-0 C14H19NOS
    S-(pyridin-2-yl) 3-cyclohexylpropanethioate
    —— 2'-(2″-pyridylthio)-1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-ol 1456629-15-4 C14H9F6NOS
    2'-(2″-pyridylthio)-1,1,1,3,3,3-hexafluoro-2-phenylpropan-2-ol
    —— N-[4-(methylthio)phenyl]-3-pyridinecarboxamide 298204-73-6 C13H13N3S
    N-[4-(methylthio)phenyl]-3-pyridinecarboxamide
    —— 2-oxopropanethioamide 31787-50-5 C3H5NOS
    2-oxopropanethioamide
    —— 3-cyclohex-1-enyl-thiopropionic acid S-pyridin-2-yl ester 749927-74-0 C14H17NOS
    3-cyclohex-1-enyl-thiopropionic acid S-pyridin-2-yl ester
    —— 4-hydroxy-1 - [4-(methylthio)phenyl]-2-[2-(methylthio)-1,3,4-thiadiazol-5-yl]-4-(trifluoromethyl)-4,5-dihydro-1H-imidazole 518015-15-1 C14H13F3N4OS3
    4-hydroxy-1 - [4-(methylthio)phenyl]-2-[2-(methylthio)-1,3,4-thiadiazol-5-yl]-4-(trifluoromethyl)-4,5-dihydro-1H-imidazole
    —— (2,4-dimethylphenyl)(perfluorophenyl)sulfane 1374639-70-9 C14H9F5S
    (2,4-dimethylphenyl)(perfluorophenyl)sulfane
    —— S-2-pyridyl ethanethioate 10111-76-9 C7H7NOS
    S-2-pyridyl ethanethioate
    —— 2,3-Dihydrothiopyrano<2,3-b>pyridine 103020-21-9 C8H9NS
    2,3-Dihydrothiopyrano<2,3-b>pyridine
    —— 4-Methyl-2-(pyridin-2-ylsulfanyl)-pentanoic acid amide 189809-77-6 C11H16N2OS
    4-Methyl-2-(pyridin-2-ylsulfanyl)-pentanoic acid amide
    —— 7-(2-pyridylthio)heptanoic acid ethyl ester 1356156-33-6 C14H21NO2S
    7-(2-pyridylthio)heptanoic acid ethyl ester