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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-phenylsulfanyl-1H-pyrrolo[2,3-b]pyridine 923583-55-5 C13H10N2S
    5-phenylsulfanyl-1H-pyrrolo[2,3-b]pyridine
    —— 3-methyl-3-(phenylthio)butan-1-ol 95553-23-4 C11H16OS
    3-methyl-3-(phenylthio)butan-1-ol
    —— 1-benzenesulfonyl-3-iodo-5-phenylsulfanyl-1H-pyrrolo[2,3-b]pyridine 923583-57-7 C19H13IN2O2S2
    1-benzenesulfonyl-3-iodo-5-phenylsulfanyl-1H-pyrrolo[2,3-b]pyridine
    —— 3-cyclohexylsulfinylpropanenitrile 862972-04-1 C9H15NOS
    3-cyclohexylsulfinylpropanenitrile
    —— 2-cyclohexylsulfinyl-3-methyl-1,3-butadiene 862972-06-3 C11H18OS
    2-cyclohexylsulfinyl-3-methyl-1,3-butadiene
    —— (E)-1,2-Bis<methylthio>-3-methyl-1,3-butadiene 87745-51-5 C7H12S2
    (E)-1,2-Bis<methylthio>-3-methyl-1,3-butadiene
    —— 2[[(2,5-dimethylphenyl)methyl]thio]-1-methylpyridinium chloride 478620-27-8 C15H18NS*Cl
    2[[(2,5-dimethylphenyl)methyl]thio]-1-methylpyridinium chloride
    —— 2-((2-fluorobenzyl)thio)-1-methylpyridinium chloride 77155-89-6 C13H13FNS*Cl
    2-((2-fluorobenzyl)thio)-1-methylpyridinium chloride
    —— 1-methyl-2((2-pyridyl)methylthio)pyridinium chloride 77148-54-0 C12H13N2S*Cl
    1-methyl-2((2-pyridyl)methylthio)pyridinium chloride
    —— 1-Methyl-2-((2-methyl)benzylthio)pyridinium bromide 77148-92-6 Br*C14H16NS
    1-Methyl-2-((2-methyl)benzylthio)pyridinium bromide
    —— 2-((2-chlorobenzyl)thio)-1-methylpyridinium chloride 77148-87-9 C13H13ClNS*Cl
    2-((2-chlorobenzyl)thio)-1-methylpyridinium chloride
    —— 2-benzylsulfanyl-1-methyl-pyridinium; bromide 62058-65-5 Br*C13H14NS
    2-benzylsulfanyl-1-methyl-pyridinium; bromide
    —— 2-((-3-Fluorobenzyl)thio)-1-methylpyridinium chloride 77148-82-4 C13H13FNS*Cl
    2-((-3-Fluorobenzyl)thio)-1-methylpyridinium chloride
    —— 1,1-dimethylethyl (2-amino-1,1-dimethyl-2-thioxoethyl)carbamate 133117-98-3 C9H18N2O2S
    1,1-dimethylethyl (2-amino-1,1-dimethyl-2-thioxoethyl)carbamate
    —— 1-Methyl-2-(pyridin-3-ylmethylthio)pyridinium chloride 77148-57-3 C12H13N2S*Cl
    1-Methyl-2-(pyridin-3-ylmethylthio)pyridinium chloride
    —— 1-methyl-2-(3-chlorobenzylthio)pyridinium chloride 77148-72-2 C13H13ClNS*Cl
    1-methyl-2-(3-chlorobenzylthio)pyridinium chloride
    —— 1-methyl-2(4-imidazolylmethylthio)pyridinium chloride 77148-55-1 C10H12N3S*Cl
    1-methyl-2(4-imidazolylmethylthio)pyridinium chloride
    —— 1-Methyl-2-(2-phenylethylthio) pyridinium bromide 62058-66-6 Br*C14H16NS
    1-Methyl-2-(2-phenylethylthio) pyridinium bromide
    —— 2-(Cyclohexylmethylthio)-1-methylpyridinium bromide 77148-73-3 Br*C13H20NS
    2-(Cyclohexylmethylthio)-1-methylpyridinium bromide
    —— 2-((((4-Chlorophenyl)thio)methyl)thio)-1-methylpyridinium chloride 83958-63-8 C13H13ClNS2*Cl
    2-((((4-Chlorophenyl)thio)methyl)thio)-1-methylpyridinium chloride
    —— 2-((3-Iodobenzyl)thio)-1-methylpyridinium chloride 77148-94-8 C13H13INS*Cl
    2-((3-Iodobenzyl)thio)-1-methylpyridinium chloride
    —— 2-(3-Bromobenzylthio)-1-methylpyridinium bromide 77148-78-8 Br*C13H13BrNS
    2-(3-Bromobenzylthio)-1-methylpyridinium bromide
    —— 1-Methyl-2-(2-phenylpropylthio)pyridinium bromide 77148-70-0 Br*C15H18NS
    1-Methyl-2-(2-phenylpropylthio)pyridinium bromide
    —— 1-Methyl-2(4-methylbenzylthio)pyridinium bromide 77148-71-1 Br*C14H16NS
    1-Methyl-2(4-methylbenzylthio)pyridinium bromide
    —— 2-(((phenylthio)methyl)thio)-1-methylpyridinium chloride 83958-64-9 C13H14NS2*Cl
    2-(((phenylthio)methyl)thio)-1-methylpyridinium chloride
    —— 2-(4-Bromobenzylthio)-1-methylpyridinium bromide 77148-74-4 Br*C13H13BrNS
    2-(4-Bromobenzylthio)-1-methylpyridinium bromide
    —— 2((4-Fluorobenzyl)thio)-1-methylpyridinium chloride 77148-81-3 C13H13FNS*Cl
    2((4-Fluorobenzyl)thio)-1-methylpyridinium chloride
    —— 1-Methyl-2-((3-methylbenzyl)thio)pyridinium chloride 77148-85-7 C14H16NS*Cl
    1-Methyl-2-((3-methylbenzyl)thio)pyridinium chloride
    —— 1-Methyl-2-(3-phenylpropylthio)pyridinium bromide 77148-69-7 Br*C15H18NS
    1-Methyl-2-(3-phenylpropylthio)pyridinium bromide
    —— 1-Methyl-2-(3,4-dimethylbenzylthio)pyridinium chloride 77155-88-5 C15H18NS*Cl
    1-Methyl-2-(3,4-dimethylbenzylthio)pyridinium chloride
    —— 1-Methyl-2-([(pyridin-4-yl)methyl]thio)pyridinium chloride 77148-62-0 C12H13N2S*Cl
    1-Methyl-2-([(pyridin-4-yl)methyl]thio)pyridinium chloride
    —— 1-Methyl-2-((4-phenylbutyl)thio)pyridinium bromide 77148-98-2 Br*C16H20NS
    1-Methyl-2-((4-phenylbutyl)thio)pyridinium bromide
    —— 2-(4-Chlorobenzylthio)-1-methylpyridinium chloride 77148-66-4 C13H13ClNS*Cl
    2-(4-Chlorobenzylthio)-1-methylpyridinium chloride
    —— ({[1-(dimethylamino)ethylidene]amino}(methylsulfanyl)methylidene)azanium iodide 344361-87-1 C6H13N3S*HI
    ({[1-(dimethylamino)ethylidene]amino}(methylsulfanyl)methylidene)azanium iodide
    —— (R)-5-amino-3-(2-fluoro-5-(pyridin-2-ylthio)phenyl)-3,6,6-trimethyl-3,6-dihydro-2H-1,4-thiazine 1,1-dioxide 1600508-23-3 C18H20FN3O2S2
    (R)-5-amino-3-(2-fluoro-5-(pyridin-2-ylthio)phenyl)-3,6,6-trimethyl-3,6-dihydro-2H-1,4-thiazine 1,1-dioxide
    —— 2-phenylthio-2-phenylethylamine 32121-60-1 C14H15NS
    2-phenylthio-2-phenylethylamine
    —— diprop-2-ynyl sulphone 14039-88-4 C6H6O2S
    diprop-2-ynyl sulphone
    —— 3-(3-bromo-phenylsulfanyl)-6-chloro-2-methyl-1-pyridin-2-yl-1H-indole 1359980-35-0 C20H14BrClN2S
    3-(3-bromo-phenylsulfanyl)-6-chloro-2-methyl-1-pyridin-2-yl-1H-indole
    —— 2-Fluoro-3-(propylthio)pyridine 117670-92-5 C8H10FNS
    2-Fluoro-3-(propylthio)pyridine
    —— 3,3,5,5-tetramethyl-1-methylthiocyclohexene 79238-74-7 C11H20S
    3,3,5,5-tetramethyl-1-methylthiocyclohexene
    —— 3,3,5,5-Tetramethyl-1-(phenylthio)cyclohexan-1-carbonitril 142484-07-9 C17H23NS
    3,3,5,5-Tetramethyl-1-(phenylthio)cyclohexan-1-carbonitril
    —— 1-(4-Chlorphenylthio)-3,3,5,5-tetramethylcyclohexan-1-carbonitril 142484-08-0 C17H22ClNS
    1-(4-Chlorphenylthio)-3,3,5,5-tetramethylcyclohexan-1-carbonitril
    —— 3-((3-bromophenyl)thio)-6-chloro-2-methyl-1H-indole 1359979-76-2 C15H11BrClNS
    3-((3-bromophenyl)thio)-6-chloro-2-methyl-1H-indole
    —— 3-methyl-2-phenylthiobutadiene 91891-84-8 C11H12S
    3-methyl-2-phenylthiobutadiene
    —— methyl 3,4-dimethyl-4-pentenedithioate 101382-76-7 C8H14S2
    methyl 3,4-dimethyl-4-pentenedithioate
    —— 3,3,5,5-tetramethyl-2-phenylsulfanylcyclohexanone 63546-66-7 C16H22OS
    3,3,5,5-tetramethyl-2-phenylsulfanylcyclohexanone
    —— 3,3,5,5-tetramethyl-1-(phenylthio)cyclohexene 102108-78-1 C16H22S
    3,3,5,5-tetramethyl-1-(phenylthio)cyclohexene
    —— 1-(4-Chlorphenylthio)-3,3,5,5-tetramethylcyclohexen 142484-06-8 C16H21ClS
    1-(4-Chlorphenylthio)-3,3,5,5-tetramethylcyclohexen
    —— 3,6,6-Trimethylcyclohex-2-enthion 38693-71-9 C9H14S
    3,6,6-Trimethylcyclohex-2-enthion
    —— 4,5-Bis{[3-(dimethylamino)phenyl]sulfanyl}benzene-1,2-dicarbonitrile 515124-02-4 C24H22N4S2
    4,5-Bis{[3-(dimethylamino)phenyl]sulfanyl}benzene-1,2-dicarbonitrile