N-重氮基-1,1-二氟甲磺酰胺 | 328395-49-9

• 分子结构分类: 有机化合物 - 有机硫化合物 - 磺酰类
• 中文名称: N-重氮基-1,1-二氟甲磺酰胺
• 英文名称: Difluoromethanesulfonyl azide
• 英文别名: N-diazo-1,1-difluoromethanesulfonamide
• CAS: 328395-49-9
• 化学式: CHF₂N₃O₂S
• 分子量: 157.101
• InChiKey: FCWBCHXREWUROG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  56.9
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1-甲基-2H-吡啶 、 N-重氮基-1,1-二氟甲磺酰胺 以 乙醚 为溶剂， 反应 0.17h， 以54%的产率得到
  参考文献：
  名称：

  Synthesis of N-(1,2,3,6-tetrahydropyridylidene)-fluoroalkanesulfonylamides from reactions of per(poly)fluoroalkanesulfonyl azides with 1,2-dihydropyridines

  摘要：

  The 1,3-dipolar cycloaddition reaction of per(poly)fluoroalkanesulfonyl azides with 1,2-dihydropyridines gave N-(1,2,3,6-tetrahydropyridylidene)-Auoroalkanesulfonylamides as characterized by spectral methods and X-ray diffraction. The reaction mechanisms are discussed. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-1139(00)00322-5

文献信息

• Reactions of fluoroalkanesulfonyl azides with cyclic vinyl ethers
  作者：Shi-Zheng Zhu、Gui-Fang Jin、Jing-Wei Zhao

  DOI：10.1016/s0022-1139(02)00290-7

  日期：2003.3

  The addition reactions of fluoroalkanesulfonyl azides to dihydropyran or dihydrofuran were studied. These reactions do not give the corresponding N-fluoroalkanesulfonyl azilidines but N-fluoroalkanesulfonyl-tetrahydropyranon-2-imines or N-fluoroalkanesulfonyl-tetrahydro-furano-2-imines. The reaction mechanism is discussed.

  研究了氟代烷烃磺酰叠氮与二氢吡喃或二氢呋喃的加成反应。这些反应没有得到相应的N-氟代烷烃磺酰基氮杂环丁烷，而是N-氟代烷烃磺酰基-四氢吡喃-2-亚胺或N-氟代烷烃磺酰基-四氢呋喃-2-亚胺。讨论了反应机理。
• Synthesis of N-(1,2,3,6-tetrahydropyridylidene)-fluoroalkanesulfonylamides from reactions of per(poly)fluoroalkanesulfonyl azides with 1,2-dihydropyridines
  作者：Yong Xu、Yanli Wang、Shizheng Zhu、Guangyu Zhu、Yisi Jia、Qichen Huang

  DOI：10.1016/s0022-1139(00)00322-5

  日期：2000.12

  The 1,3-dipolar cycloaddition reaction of per(poly)fluoroalkanesulfonyl azides with 1,2-dihydropyridines gave N-(1,2,3,6-tetrahydropyridylidene)-Auoroalkanesulfonylamides as characterized by spectral methods and X-ray diffraction. The reaction mechanisms are discussed. (C) 2000 Elsevier Science S.A. All rights reserved.