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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide —— C16H21N5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(2R)-4-phenylbutan-2-yl]acetamide
    —— (2S)-2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-(cyclohexylmethyl)propanamide —— C14H23N5O2S
    (2S)-2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-(cyclohexylmethyl)propanamide
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R)-1-(3-chlorophenyl)ethyl]acetamide —— C14H16ClN5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R)-1-(3-chlorophenyl)ethyl]acetamide
    —— 3-[2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl]sulfanyl-4-amino-6-methyl-1,2,4-triazin-5-one —— C14H17N5O3S
    3-[2-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-oxoethyl]sulfanyl-4-amino-6-methyl-1,2,4-triazin-5-one
    —— 2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R)-1-(4-bromophenyl)ethyl]acetamide —— C14H16BrN5O2S
    2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]-N-[(1R)-1-(4-bromophenyl)ethyl]acetamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C18H27N5O2S
    N-[(1S)-1-(1-adamantyl)ethyl]-2-[(4-amino-6-methyl-5-oxo-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide —— C10H14F3N5O2S
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[[(2R)-oxolan-2-yl]methyl]acetamide
    —— 2-[(4-Amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C14H16N6OS
    2-[(4-Amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-ethylacetamide —— C13H23N5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-ethylacetamide
    —— (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(1-cyanocyclohexyl)propanamide —— C13H17F3N6OS
    (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(1-cyanocyclohexyl)propanamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C12H18F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— (2S)-N-(1-adamantyl)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C16H22F3N5OS
    (2S)-N-(1-adamantyl)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylacetamide —— C7H10F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-dimethylacetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-chlorophenyl)ethyl]acetamide —— C13H16ClN5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1S)-1-(4-chlorophenyl)ethyl]acetamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C12H18F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]ethanone —— C11H19N5O2S
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(2S,6S)-2,6-dimethylmorpholin-4-yl]ethanone
    —— (2R)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]propanamide —— C13H20F3N5OS
    (2R)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]propanamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]ethanone —— C18H17ClN6O2S
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]ethanone
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide —— C15H18F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-(4-ethylphenyl)ethyl]acetamide
    —— (2R)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]propanamide —— C14H15F4N5OS
    (2R)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexyl-N-ethylpropanamide —— C14H22F3N5OS
    (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-cyclohexyl-N-ethylpropanamide
    —— 3-[(5-Methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-amine —— C7H7F3N6OS
    3-[(5-Methyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-amine
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide —— C19H21N5OS2
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide
    —— (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]propanamide —— C14H15F4N5OS
    (2S)-2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— (3R)-3-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]oxolan-2-one —— C7H10N4O2S
    (3R)-3-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]oxolan-2-one
    —— 3-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-5-methyl-1,2,4-triazol-4-amine —— C10H10N6O2S
    3-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-5-methyl-1,2,4-triazol-4-amine
    —— (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-ethylpropanamide —— C14H25N5OS
    (2S)-2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-cyclohexyl-N-ethylpropanamide
    —— (Z)-4-(1,3-benzothiazol-2-yl)-5-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]pent-4-enoic acid —— C25H20N2O4S2
    (Z)-4-(1,3-benzothiazol-2-yl)-5-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]pent-4-enoic acid
    —— 1-(4-Butylphenyl)-3-[[2-(2,5-difluorophenyl)sulfanylacetyl]amino]thiourea —— C19H21F2N3OS2
    1-(4-Butylphenyl)-3-[[2-(2,5-difluorophenyl)sulfanylacetyl]amino]thiourea
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-bromophenyl)ethyl]acetamide —— C13H16BrN5OS
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(1R)-1-(4-bromophenyl)ethyl]acetamide
    —— 2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]ethanone —— C16H16N6OS3
    2-[(4-amino-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(3R)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]ethanone
    —— 2-(4-bromophenyl)sulfanyl-N-piperidin-1-ylacetamide —— C13H17BrN2OS
    2-(4-bromophenyl)sulfanyl-N-piperidin-1-ylacetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-piperidin-1-ylacetamide —— C15H21BrN2OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-piperidin-1-ylacetamide
    —— (2E,5Z)-2-[2-(furan-2-yl)-2-oxoethylidene]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C17H13NO3S2
    (2E,5Z)-2-[2-(furan-2-yl)-2-oxoethylidene]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— 2-(2,5-difluorophenyl)sulfanyl-N-[(4-fluorophenyl)methyl]acetamide —— C15H12F3NOS
    2-(2,5-difluorophenyl)sulfanyl-N-[(4-fluorophenyl)methyl]acetamide
    —— 2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-propyl-1H-pyrimidin-6-one —— C16H15BrN4O2S
    2-[[5-(4-bromophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-4-propyl-1H-pyrimidin-6-one
    —— 2-[(4-amino-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(1-cyanocyclohexyl)acetamide —— C14H20N6OS
    2-[(4-amino-5-cyclopropyl-1,2,4-triazol-3-yl)sulfanyl]-N-(1-cyanocyclohexyl)acetamide
    —— (2E,5E)-2-(3,3-dimethyl-2-oxobutylidene)-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C18H21NO2S2
    (2E,5E)-2-(3,3-dimethyl-2-oxobutylidene)-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— (2E,5Z)-2-(3,3-dimethyl-2-oxobutylidene)-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C18H21NO2S2
    (2E,5Z)-2-(3,3-dimethyl-2-oxobutylidene)-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— (2Z,5E)-2-(3,3-dimethyl-2-oxobutylidene)-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C18H21NO2S2
    (2Z,5E)-2-(3,3-dimethyl-2-oxobutylidene)-3-methyl-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— 1-[(Z)-hex-2-enyl]-4-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]piperidine —— C16H28N4S
    1-[(Z)-hex-2-enyl]-4-[(4-methyl-5-methylsulfanyl-1,2,4-triazol-3-yl)methyl]piperidine
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-(1-propan-2-yltetrazol-5-yl)sulfanylacetamide —— C11H19N5O3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-(1-propan-2-yltetrazol-5-yl)sulfanylacetamide
    —— 2-(1-Cyclopentyltetrazol-5-yl)sulfanyl-1-(1-cyclopropyl-2,5-dimethylpyrrol-3-yl)ethanone —— C17H23N5OS
    2-(1-Cyclopentyltetrazol-5-yl)sulfanyl-1-(1-cyclopropyl-2,5-dimethylpyrrol-3-yl)ethanone
    —— 1-[4-[(1S)-1-phenylethyl]piperazin-4-ium-1-yl]-2-(1-propan-2-yltetrazol-5-yl)sulfanylethanone —— C18H27N6OS+
    1-[4-[(1S)-1-phenylethyl]piperazin-4-ium-1-yl]-2-(1-propan-2-yltetrazol-5-yl)sulfanylethanone
    —— 2-(1-propan-2-yltetrazol-5-yl)sulfanyl-N-propylacetamide —— C9H17N5OS
    2-(1-propan-2-yltetrazol-5-yl)sulfanyl-N-propylacetamide
    —— (3S,4R)-4-[2-(4-methylphenyl)sulfanylethylamino]-1,1-dioxothiolan-3-ol —— C13H19NO3S2
    (3S,4R)-4-[2-(4-methylphenyl)sulfanylethylamino]-1,1-dioxothiolan-3-ol
    —— (2R)-2-(1-benzyltetrazol-5-yl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one —— C17H24N6OS
    (2R)-2-(1-benzyltetrazol-5-yl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— (2R)-2-(1-benzyltetrazol-5-yl)sulfanyl-1-(4-ethylpiperazin-4-ium-1-yl)propan-1-one —— C17H25N6OS+
    (2R)-2-(1-benzyltetrazol-5-yl)sulfanyl-1-(4-ethylpiperazin-4-ium-1-yl)propan-1-one
    —— (2S)-2-(1-benzyltetrazol-5-yl)sulfanyl-1-(4-ethylpiperazin-4-ium-1-yl)propan-1-one —— C17H25N6OS+
    (2S)-2-(1-benzyltetrazol-5-yl)sulfanyl-1-(4-ethylpiperazin-4-ium-1-yl)propan-1-one
    —— [(3S,4S)-4-hydroxy-1,1-dioxothiolan-3-yl]-[2-(4-methylphenyl)sulfanylethyl]azanium —— C13H20NO3S2+
    [(3S,4S)-4-hydroxy-1,1-dioxothiolan-3-yl]-[2-(4-methylphenyl)sulfanylethyl]azanium