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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide —— C16H21N3OS3
    2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]acetamide
    —— 2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methyl-N-[(1S)-1-phenylethyl]acetamide —— C18H20N4O2S
    2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methyl-N-[(1S)-1-phenylethyl]acetamide
    —— (2S)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylpropanamide —— C13H18N4O2S
    (2S)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylpropanamide
    —— (2R)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]propanamide —— C17H23N3OS3
    (2R)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]propanamide
    —— (2S)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]propanamide —— C22H25N3O2S
    (2S)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]propanamide
    —— [(2R)-1-oxo-1-(propan-2-ylamino)propan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate —— C16H26N4O3S2
    [(2R)-1-oxo-1-(propan-2-ylamino)propan-2-yl] 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetate
    —— 2-[[2-(4-Ethylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-(3-methylphenyl)-1,3,4-oxadiazole —— C21H19N3OS2
    2-[[2-(4-Ethylphenyl)-1,3-thiazol-4-yl]methylsulfanyl]-5-(3-methylphenyl)-1,3,4-oxadiazole
    —— N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C20H21N3O2S
    N-methyl-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— N-(furan-2-ylmethyl)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C18H16F3N3O3S
    N-(furan-2-ylmethyl)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— (2R)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]propanamide —— C22H25N3O2S
    (2R)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylbutyl]propanamide
    —— (2R)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide —— C15H19N3O2S
    (2R)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide
    —— (2R)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]propanamide —— C20H24N4O2S
    (2R)-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]propanamide
    —— (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]propanamide —— C17H23N3OS3
    (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1S)-1-phenylbutyl]propanamide
    —— 2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide —— C16H21N3OS3
    2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-phenylbutyl]acetamide
    —— 2-(4-Ethylphenyl)-4-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole —— C19H18N4OS2
    2-(4-Ethylphenyl)-4-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3-thiazole
    —— N-methyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide —— C20H21N3O2S
    N-methyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-phenylethyl]acetamide
    —— (2E)-4,4-dimethyl-3-oxo-2-[(5E)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-4-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile —— C24H23N3O2S2
    (2E)-4,4-dimethyl-3-oxo-2-[(5E)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-4-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile
    —— (2E)-4,4-dimethyl-3-oxo-2-[(5Z)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-4-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile —— C24H23N3O2S2
    (2E)-4,4-dimethyl-3-oxo-2-[(5Z)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-4-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile
    —— (2Z)-4,4-dimethyl-3-oxo-2-[(5E)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-2-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile —— C24H23N3O2S2
    (2Z)-4,4-dimethyl-3-oxo-2-[(5E)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-2-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile
    —— (2R)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]propanamide —— C22H25N3O2S
    (2R)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R)-1-phenylbutyl]propanamide
    —— (2Z)-4,4-dimethyl-3-oxo-2-[(5E)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-4-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile —— C24H23N3O2S2
    (2Z)-4,4-dimethyl-3-oxo-2-[(5E)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-4-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile
    —— (2E)-4,4-dimethyl-3-oxo-2-[(5Z)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-2-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile —— C24H23N3O2S2
    (2E)-4,4-dimethyl-3-oxo-2-[(5Z)-4-oxo-3-(2-phenylsulfanylethyl)-5-(pyridin-2-ylmethylidene)-1,3-thiazolidin-2-ylidene]pentanenitrile
    —— (2S)-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide —— C14H16FN3OS3
    (2S)-2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propan-2-ylpropanamide
    —— [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-phenylsulfanylacetate —— C20H23NO3S
    [2-oxo-2-[[(1S)-1-phenylbutyl]amino]ethyl] 2-phenylsulfanylacetate
    —— [(2S)-1-oxo-1-(propan-2-ylamino)propan-2-yl] 2-phenylsulfanylacetate —— C14H19NO3S
    [(2S)-1-oxo-1-(propan-2-ylamino)propan-2-yl] 2-phenylsulfanylacetate
    —— 2-(4,5-dihydro-1,3-thiazol-2-ylsulfanyl)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide —— C19H20N2OS3
    2-(4,5-dihydro-1,3-thiazol-2-ylsulfanyl)-N-[4-(3,4-dimethylphenyl)sulfanylphenyl]acetamide
    —— 4-chloro-2-(2-chloroethyl)-1-propan-2-ylsulfanylbenzene —— C11H14Cl2S
    4-chloro-2-(2-chloroethyl)-1-propan-2-ylsulfanylbenzene
    —— 2-(4,5-dihydro-1,3-thiazol-2-ylsulfanyl)-N-[4-(2,5-dimethylphenyl)sulfanylphenyl]acetamide —— C19H20N2OS3
    2-(4,5-dihydro-1,3-thiazol-2-ylsulfanyl)-N-[4-(2,5-dimethylphenyl)sulfanylphenyl]acetamide
    —— 6-(3-chlorophenyl)-3-(trifluoromethyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C11H6ClF3N4S
    6-(3-chlorophenyl)-3-(trifluoromethyl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— 2-[3-(5-chloro-2-methylsulfanylphenyl)imidazo[2,1-b][1,3]thiazol-6-yl]ethanamine —— C14H14ClN3S2
    2-[3-(5-chloro-2-methylsulfanylphenyl)imidazo[2,1-b][1,3]thiazol-6-yl]ethanamine
    —— 2-[3-(5-chloro-2-methylsulfanylphenyl)imidazo[2,1-b][1,3]thiazol-6-yl]acetic acid —— C14H11ClN2O2S2
    2-[3-(5-chloro-2-methylsulfanylphenyl)imidazo[2,1-b][1,3]thiazol-6-yl]acetic acid
    —— (R)-(5-chloro-2-propylsulfanylphenyl)-thiophen-2-ylmethanol —— C14H15ClOS2
    (R)-(5-chloro-2-propylsulfanylphenyl)-thiophen-2-ylmethanol
    —— 2-[3-(5-chloro-2-methylsulfanylphenyl)-2-methylimidazo[2,1-b][1,3]thiazol-6-yl]ethanamine —— C15H16ClN3S2
    2-[3-(5-chloro-2-methylsulfanylphenyl)-2-methylimidazo[2,1-b][1,3]thiazol-6-yl]ethanamine
    —— 2-[3-(5-chloro-2-methylsulfanylphenyl)-2-methylimidazo[2,1-b][1,3]thiazol-6-yl]acetic acid —— C15H13ClN2O2S2
    2-[3-(5-chloro-2-methylsulfanylphenyl)-2-methylimidazo[2,1-b][1,3]thiazol-6-yl]acetic acid
    —— 2-[3-(5-chloro-2-methylsulfanylphenyl)-6-methylimidazo[2,1-b][1,3]thiazol-5-yl]acetic acid —— C15H13ClN2O2S2
    2-[3-(5-chloro-2-methylsulfanylphenyl)-6-methylimidazo[2,1-b][1,3]thiazol-5-yl]acetic acid
    —— (S)-(5-methyl-2-methylsulfanylphenyl)-[(3S)-piperidin-3-yl]methanol —— C14H21NOS
    (S)-(5-methyl-2-methylsulfanylphenyl)-[(3S)-piperidin-3-yl]methanol
    —— 6-(4-fluorophenyl)-3-(2-methylfuran-3-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine —— C15H11FN4OS
    6-(4-fluorophenyl)-3-(2-methylfuran-3-yl)-7H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine
    —— (S)-(5-chloro-2-propylsulfanylphenyl)-thiophen-2-ylmethanol —— C14H15ClOS2
    (S)-(5-chloro-2-propylsulfanylphenyl)-thiophen-2-ylmethanol
    —— (R)-(5-methyl-2-methylsulfanylphenyl)-[(3S)-piperidin-3-yl]methanol —— C14H21NOS
    (R)-(5-methyl-2-methylsulfanylphenyl)-[(3S)-piperidin-3-yl]methanol
    —— (S)-(5-methyl-2-methylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol —— C14H21NOS
    (S)-(5-methyl-2-methylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol
    —— (S)-(5-chloro-2-propylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol —— C15H22ClNOS
    (S)-(5-chloro-2-propylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol
    —— (R)-(5-methyl-2-methylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol —— C14H21NOS
    (R)-(5-methyl-2-methylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol
    —— (R)-(5-chloro-2-propylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol —— C15H22ClNOS
    (R)-(5-chloro-2-propylsulfanylphenyl)-[(3R)-piperidin-3-yl]methanol
    —— (R)-(5-chloro-2-propylsulfanylphenyl)-piperidin-4-ylmethanol —— C15H22ClNOS
    (R)-(5-chloro-2-propylsulfanylphenyl)-piperidin-4-ylmethanol
    —— 2-Ethyl-7-(pyrimidin-2-ylsulfanylmethyl)-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C12H11N5OS2
    2-Ethyl-7-(pyrimidin-2-ylsulfanylmethyl)-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— 7-[[5-(3,5-Dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-2-ethyl-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one —— C18H17N5O2S2
    7-[[5-(3,5-Dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-2-ethyl-[1,3,4]thiadiazolo[3,2-a]pyrimidin-5-one
    —— (S)-(5-methyl-2-methylsulfanylphenyl)-piperidin-4-ylmethanol —— C14H21NOS
    (S)-(5-methyl-2-methylsulfanylphenyl)-piperidin-4-ylmethanol
    —— 4-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole —— C12H11N5S3
    4-[(1-Cyclopropyltetrazol-5-yl)sulfanylmethyl]-2-thiophen-3-yl-1,3-thiazole
    —— N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[[5-(ethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H26N4O3S2
    N-[(1S)-1-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methylpropyl]-2-[[5-(ethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-(furan-2-ylmethyl)-N-methyl-2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylacetamide —— C14H15N5O2S2
    N-(furan-2-ylmethyl)-N-methyl-2-[1-(thiophen-2-ylmethyl)tetrazol-5-yl]sulfanylacetamide