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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C13H20N4O2S
    2-[(4-amino-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— 2-Ethanimidoyl-4-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile —— C12H10N4O3S
    2-Ethanimidoyl-4-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-oxobutanenitrile
    —— (5Z)-2-(2,5-dimethylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C19H18N2OS2
    (5Z)-2-(2,5-dimethylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C17H24N4O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— 2-(2-chlorophenyl)sulfanyl-N-(2-phenylethyl)acetamide —— C16H16ClNOS
    2-(2-chlorophenyl)sulfanyl-N-(2-phenylethyl)acetamide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide —— C17H24N4O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2R)-2-methylcyclohexyl]acetamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclohexyl]propanamide —— C16H22ClNOS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1R,2R)-2-methylcyclohexyl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-(1-cyanocyclohexyl)propanamide —— C16H19ClN2OS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-(1-cyanocyclohexyl)propanamide
    —— (2R)-N-(1-adamantyl)-2-(2-chlorophenyl)sulfanylpropanamide —— C19H24ClNOS
    (2R)-N-(1-adamantyl)-2-(2-chlorophenyl)sulfanylpropanamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1R,2S)-2-methylcyclohexyl]propanamide —— C16H22ClNOS
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(1R,2S)-2-methylcyclohexyl]propanamide
    —— 2-(2-chlorophenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C13H16ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (1R)-cyclohex-3-ene-1-carboxylate —— C21H21NO3S
    [2-oxo-2-(2-phenylsulfanylanilino)ethyl] (1R)-cyclohex-3-ene-1-carboxylate
    —— 3-benzylsulfanyl-N-[(Z)-(3-bromophenyl)methylideneamino]-1H-1,2,4-triazol-5-amine —— C16H14BrN5S
    3-benzylsulfanyl-N-[(Z)-(3-bromophenyl)methylideneamino]-1H-1,2,4-triazol-5-amine
    —— N-[(Z)-benzylideneamino]-3-benzylsulfanyl-1H-1,2,4-triazol-5-amine —— C16H15N5S
    N-[(Z)-benzylideneamino]-3-benzylsulfanyl-1H-1,2,4-triazol-5-amine
    —— 1-[4-(2,5-Dimethylphenyl)sulfanylphenyl]-3-(2-methoxyethyl)thiourea —— C18H22N2OS2
    1-[4-(2,5-Dimethylphenyl)sulfanylphenyl]-3-(2-methoxyethyl)thiourea
    —— 1-Benzyl-3-[4-(2,4-dimethylphenyl)sulfanylphenyl]thiourea —— C22H22N2S2
    1-Benzyl-3-[4-(2,4-dimethylphenyl)sulfanylphenyl]thiourea
    —— 1-[4-(4-Bromophenyl)sulfanylphenyl]-3-methylthiourea —— C14H13BrN2S2
    1-[4-(4-Bromophenyl)sulfanylphenyl]-3-methylthiourea
    —— 2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylethyl)acetamide —— C19H20N6OS
    2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-(2-phenylethyl)acetamide
    —— 2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopentylacetamide —— C16H20N6OS
    2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-cyclopentylacetamide
    —— 1-Cyclopropyl-3-[4-(2,4-dimethylphenyl)sulfanylphenyl]thiourea —— C18H20N2S2
    1-Cyclopropyl-3-[4-(2,4-dimethylphenyl)sulfanylphenyl]thiourea
    —— 1-(2-Methoxyethyl)-3-[4-(2-methoxyethylcarbamothioylamino)cyclohexyl]thiourea —— C14H28N4O2S2
    1-(2-Methoxyethyl)-3-[4-(2-methoxyethylcarbamothioylamino)cyclohexyl]thiourea
    —— 1-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-3-methylthiourea —— C10H20N2S
    1-[(1R,2S,3S)-2,3-dimethylcyclohexyl]-3-methylthiourea
    —— 1-cyclohexyl-3-[(2S)-1-methoxypropan-2-yl]thiourea —— C11H22N2OS
    1-cyclohexyl-3-[(2S)-1-methoxypropan-2-yl]thiourea
    —— (2S)-N-benzyl-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide —— C19H18ClN3O2S
    (2S)-N-benzyl-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylpropanamide
    —— (2R)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclohexyl-N-ethylpropanamide —— C19H24ClN3O2S
    (2R)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclohexyl-N-ethylpropanamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(2,4-difluorophenyl)ethyl]acetamide —— C18H14ClF2N3O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(2,4-difluorophenyl)ethyl]acetamide
    —— 2-(4-chlorophenyl)-5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-oxadiazole —— C16H13ClN2OS
    2-(4-chlorophenyl)-5-[(1S)-1-phenylethyl]sulfanyl-1,3,4-oxadiazole
    —— (2R)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]propanamide —— C18H22ClN3O2S
    (2R)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2S)-2-methylcyclohexyl]propanamide
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-pentan-2-yl]acetamide —— C15H18ClN3O2S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2S)-pentan-2-yl]acetamide
    —— (2S)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]propanamide —— C19H17ClFN3O2S
    (2S)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— (2R)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]propanamide —— C17H19ClN4O2S
    (2R)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(2R)-2-cyano-3-methylbutan-2-yl]propanamide
    —— 2-(3-Chlorobenzylthio)-5-(4-chlorophenyl)-1,3,4-oxadiazole —— C15H10Cl2N2OS
    2-(3-Chlorobenzylthio)-5-(4-chlorophenyl)-1,3,4-oxadiazole
    —— 3-cyano-N-[4-(2,4-dimethylphenyl)sulfanylphenyl]benzenesulfonamide —— C21H18N2O2S2
    3-cyano-N-[4-(2,4-dimethylphenyl)sulfanylphenyl]benzenesulfonamide
    —— N-[(1S)-1-(1-adamantyl)ethyl]-3-(4-chlorophenyl)sulfanylpropanamide —— C21H28ClNOS
    N-[(1S)-1-(1-adamantyl)ethyl]-3-(4-chlorophenyl)sulfanylpropanamide
    —— 2-[[5-[(2Z)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]acetamide —— C17H18N6O2S
    2-[[5-[(2Z)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]acetamide
    —— N-[(Z)-(3-bromophenyl)methylideneamino]-3-[(4-methylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C17H16BrN5S
    N-[(Z)-(3-bromophenyl)methylideneamino]-3-[(4-methylphenyl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— 2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]acetamide —— C19H20N6OS
    2-[[5-[(2Z)-2-benzylidenehydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(4-methylphenyl)methyl]acetamide
    —— (6-chloropyridin-3-yl)methyl (1'S,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate —— C18H22ClNO2S2
    (6-chloropyridin-3-yl)methyl (1'S,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.3.1]nonane]-3'-carboxylate
    —— 2-(4-chlorophenyl)-N-[4-(2,5-dimethylphenyl)sulfanylphenyl]acetamide —— C22H20ClNOS
    2-(4-chlorophenyl)-N-[4-(2,5-dimethylphenyl)sulfanylphenyl]acetamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-phenylacetamide —— C22H21NOS
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-2-phenylacetamide
    —— 2-(2-chlorophenoxy)-N-[4-(2,5-dimethylphenyl)sulfanylphenyl]acetamide —— C22H20ClNO2S
    2-(2-chlorophenoxy)-N-[4-(2,5-dimethylphenyl)sulfanylphenyl]acetamide
    —— N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-3-(4-methoxyphenyl)propanamide —— C24H25NO2S
    N-[4-(2,5-dimethylphenyl)sulfanylphenyl]-3-(4-methoxyphenyl)propanamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]cyclobutanecarboxamide —— C19H21NOS
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]cyclobutanecarboxamide
    —— N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(2-ethoxyphenoxy)acetamide —— C24H25NO3S
    N-[4-(3,4-dimethylphenyl)sulfanylphenyl]-2-(2-ethoxyphenoxy)acetamide
    —— 2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide —— C17H28N4OS2
    2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(1R,2R)-2-methylcyclohexyl]acetamide
    —— 2-[[5-[(2Z)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C17H18N6O2S
    2-[[5-[(2Z)-2-(furan-2-ylmethylidene)hydrazinyl]-1H-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— 1-benzyl-5-chloro-N-(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)-3-methylpyrazole-4-carboxamide —— C16H16ClN5OS2
    1-benzyl-5-chloro-N-(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)-3-methylpyrazole-4-carboxamide
    —— 2-(2-fluorophenyl)sulfanylethyl (E)-2-cyano-3-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]prop-2-enoate —— C22H25FN2O2S
    2-(2-fluorophenyl)sulfanylethyl (E)-2-cyano-3-[2,5-dimethyl-1-(2-methylpropyl)pyrrol-3-yl]prop-2-enoate
    —— 5-[(4-Chlorophenyl)methylsulfanyl]-3-(4-fluorophenyl)-1,3,4-thiadiazole-2-thione —— C15H10ClFN2S3
    5-[(4-Chlorophenyl)methylsulfanyl]-3-(4-fluorophenyl)-1,3,4-thiadiazole-2-thione
    —— 2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide —— C14H16FN3O2S3
    2-[[4-(4-fluorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(2S)-1-methoxypropan-2-yl]acetamide