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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N'-acetyl-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide —— C11H13N5O3S
    N'-acetyl-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide
    —— 2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide —— C14H20N4O2S
    2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(2S)-3-methylbutan-2-yl]acetamide
    —— N-benzyl-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C19H22N4O2S
    N-benzyl-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— 2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C14H18N4O4S2
    2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— N-[(2-chlorophenyl)methyl]-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C16H15ClN4O2S2
    N-[(2-chlorophenyl)methyl]-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-cyclopentyl-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C14H18N4O2S2
    N-cyclopentyl-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-methyl-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C10H12N4O2S2
    N-methyl-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-pentan-3-ylacetamide —— C14H20N4O2S2
    2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-pentan-3-ylacetamide
    —— N-(1-adamantyl)-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H24N4O2S2
    N-(1-adamantyl)-2-[[5-[(2-methyl-1,3-thiazol-4-yl)methyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(2-Methyl-1,3-thiazol-4-yl)methyl]-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole —— C16H13N5O2S2
    2-[(2-Methyl-1,3-thiazol-4-yl)methyl]-5-[(5-phenyl-1,3,4-oxadiazol-2-yl)methylsulfanyl]-1,3,4-oxadiazole
    —— N-(1-adamantyl)-2-[[5-[(1R)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H30N4O2S
    N-(1-adamantyl)-2-[[5-[(1R)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— N-(1-adamantyl)-2-[[5-[(1S)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C19H30N4O2S
    N-(1-adamantyl)-2-[[5-[(1S)-1-(dimethylamino)propyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-N-carbamoyl-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-methylbutanamide —— C12H14N4O4S
    (2S)-N-carbamoyl-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-3-methylbutanamide
    —— 2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone —— C18H23N3O3S
    2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-[(1S,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone
    —— 2-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone —— C17H14N4O3S
    2-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(5-phenyl-3,4-dihydropyrazol-2-yl)ethanone
    —— N-[(4-chlorophenyl)methyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C15H12ClN3O3S
    N-[(4-chlorophenyl)methyl]-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[3-[(4-methylphenyl)methyl]-1,3-thiazol-2-ylidene]acetamide —— C19H16N4O3S2
    2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[3-[(4-methylphenyl)methyl]-1,3-thiazol-2-ylidene]acetamide
    —— N-(1-cyanocyclopentyl)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C14H14N4O3S
    N-(1-cyanocyclopentyl)-2-[[5-(furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— [2-(6-amino-2,4-dioxo-1-propylpyrimidin-5-yl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C18H21N3O5S
    [2-(6-amino-2,4-dioxo-1-propylpyrimidin-5-yl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-(cyclopropylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C14H17NO3S
    [2-(cyclopropylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[[(1S)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C19H20ClNO3S
    [2-[[(1S)-1-(3-chlorophenyl)ethyl]amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-(cyclopentylamino)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C16H21NO3S
    [2-(cyclopentylamino)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— (5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl (2R)-2-phenylsulfanylpropanoate —— C16H14N2O3S2
    (5-oxo-[1,3]thiazolo[3,2-a]pyrimidin-7-yl)methyl (2R)-2-phenylsulfanylpropanoate
    —— [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] (2S)-2-phenylsulfanylpropanoate —— C15H19NO3S
    [(2S)-1-(cyclopropylamino)-1-oxopropan-2-yl] (2S)-2-phenylsulfanylpropanoate
    —— [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C17H22N2O3S
    [2-[[(2S)-2-cyano-3-methylbutan-2-yl]amino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[(2-chlorophenyl)methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C18H18ClNO3S
    [2-[(2-chlorophenyl)methylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— 2-[(2-Chlorophenyl)methylsulfanyl]-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole —— C17H15ClN2OS
    2-[(2-Chlorophenyl)methylsulfanyl]-5-(3,4-dimethylphenyl)-1,3,4-oxadiazole
    —— [2-(2-cyanoethylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C14H16N2O3S
    [2-(2-cyanoethylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C20H20N2O3S2
    [2-[2,5-dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C19H20FNO3S
    [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— [2-(ethoxycarbonylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate —— C14H17NO5S
    [2-(ethoxycarbonylamino)-2-oxoethyl] (2R)-2-phenylsulfanylpropanoate
    —— N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C20H20ClN3O2S
    N-[(1S)-1-(3-chlorophenyl)ethyl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide —— C21H22FN3O2S
    (2S)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(4-fluorophenyl)ethyl]propanamide
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide —— C18H19N3O2S2
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methyl-N-(thiophen-2-ylmethyl)acetamide
    —— [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C19H20FNO3S
    [2-[2-(4-fluorophenyl)ethylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— (3S)-3-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one —— C14H14N2O3S
    (3S)-3-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]oxolan-2-one
    —— [2-[(2-chlorophenyl)methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C18H18ClNO3S
    [2-[(2-chlorophenyl)methylamino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— (5-phenyl-1,3,4-oxadiazol-2-yl)methyl (2R)-2-phenylsulfanylpropanoate —— C18H16N2O3S
    (5-phenyl-1,3,4-oxadiazol-2-yl)methyl (2R)-2-phenylsulfanylpropanoate
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C18H19N3OS2
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— [2-[(1-cyanocyclohexyl)amino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C18H22N2O3S
    [2-[(1-cyanocyclohexyl)amino]-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C19H24N4O2S
    (2R)-N-[(2S)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— [2-(ethoxycarbonylamino)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C14H17NO5S
    [2-(ethoxycarbonylamino)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— 2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-propylacetamide —— C19H25N3O4S2
    2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-propylacetamide
    —— (2R)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C19H24N4O2S
    (2R)-N-[(2R)-2-cyano-3-methylbutan-2-yl]-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one —— C19H26N4O2S
    (2R)-2-[[5-(3,4-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]ethanone —— C20H20N2O2S2
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]ethanone
    —— N-(1-cyanocyclohexyl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C19H21N3OS2
    N-(1-cyanocyclohexyl)-2-[[4-(4-methylphenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 1-oxidopyridin-1-ium-2-carboxylate —— C20H16N2O4S
    [2-Oxo-2-(2-phenylsulfanylanilino)ethyl] 1-oxidopyridin-1-ium-2-carboxylate
    —— N-benzyl-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C14H16N4OS
    N-benzyl-2-[(4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide —— C15H19N3O2S
    2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-propan-2-ylacetamide