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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1R,4R,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one —— C18H22OS
    (1R,4R,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one
    —— 3-hydroxy-2-[(1S)-1-phenylsulfanylbutyl]cyclopent-2-en-1-one —— C15H18O2S
    3-hydroxy-2-[(1S)-1-phenylsulfanylbutyl]cyclopent-2-en-1-one
    —— (1'S,2'S,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol —— C19H23NO2S3
    (1'S,2'S,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol
    —— (1'S,2'S,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol —— C19H23NO2S3
    (1'S,2'S,5'S)-2'-[(N-methyl-S-phenylsulfonimidoyl)methyl]spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]nona-3,6-diene]-2'-ol
    —— (1S,4S,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one —— C18H22OS
    (1S,4S,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one
    —— (1'R,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]non-6-ene]-2'-one —— C11H14OS2
    (1'R,5'S)-spiro[1,3-dithiolane-2,9'-bicyclo[3.2.2]non-6-ene]-2'-one
    —— (1S,4R,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one —— C18H22OS
    (1S,4R,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one
    —— (1R,4S,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one —— C18H22OS
    (1R,4S,5S,7S)-1-ethenyl-7-phenylsulfanyl-4-propan-2-ylbicyclo[3.1.1]heptan-6-one
    —— 3-hydroxy-2-[(1R)-2-methyl-1-phenylsulfanylpropyl]cyclopent-2-en-1-one —— C15H18O2S
    3-hydroxy-2-[(1R)-2-methyl-1-phenylsulfanylpropyl]cyclopent-2-en-1-one
    —— 3-hydroxy-2-[(1R)-1-phenylsulfanylbutyl]cyclopent-2-en-1-one —— C15H18O2S
    3-hydroxy-2-[(1R)-1-phenylsulfanylbutyl]cyclopent-2-en-1-one
    —— 3-hydroxy-2-[(1S)-1-phenylsulfanylethyl]cyclohex-2-en-1-one —— C14H16O2S
    3-hydroxy-2-[(1S)-1-phenylsulfanylethyl]cyclohex-2-en-1-one
    —— (NE)-N-[(1S,2R,5R)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine —— C12H13F2N3O3S
    (NE)-N-[(1S,2R,5R)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine
    —— (2R)-N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide —— C17H26N4OS
    (2R)-N-[[(1R,2R,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide
    —— (2R)-N-[[(1R,2S,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide —— C17H26N4OS
    (2R)-N-[[(1R,2S,4S)-2-bicyclo[2.2.1]hept-5-enyl]methyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylpropanamide
    —— (3'aR)-spiro[1,3-dithiane-2,4'-2,3,3a,5-tetrahydropentalene]-1'-one —— C11H14OS2
    (3'aR)-spiro[1,3-dithiane-2,4'-2,3,3a,5-tetrahydropentalene]-1'-one
    —— (1'R,5'S)-spiro[1,3-dithiane-2,2'-bicyclo[3.2.1]oct-3-ene]-6'-one —— C11H14OS2
    (1'R,5'S)-spiro[1,3-dithiane-2,2'-bicyclo[3.2.1]oct-3-ene]-6'-one
    —— (1R,4R,6R,9R)-5,12-bis(2-phenylsulfanylethyl)tetracyclo[7.2.1.04,11.06,10]dodeca-2,7-diene —— C28H30S2
    (1R,4R,6R,9R)-5,12-bis(2-phenylsulfanylethyl)tetracyclo[7.2.1.04,11.06,10]dodeca-2,7-diene
    —— (1E)-N,N-dimethyl-2,4-bis(methylsulfonyl)cycloocta-1,3-dien-1-amine —— C12H21NO4S2
    (1E)-N,N-dimethyl-2,4-bis(methylsulfonyl)cycloocta-1,3-dien-1-amine
    —— (1R,6R)-8-methylsulfanyl-7-azabicyclo[4.2.2]deca-2,4,7,9-tetraene —— C10H11NS
    (1R,6R)-8-methylsulfanyl-7-azabicyclo[4.2.2]deca-2,4,7,9-tetraene
    —— (1E,3Z)-N,N-dimethyl-2,4-bis(methylsulfonyl)cycloocta-1,3-dien-1-amine —— C12H21NO4S2
    (1E,3Z)-N,N-dimethyl-2,4-bis(methylsulfonyl)cycloocta-1,3-dien-1-amine
    —— methyl (1R,3S,6S)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate —— C20H17ClO4S
    methyl (1R,3S,6S)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate
    —— methyl (1S,3S,6S)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate —— C20H17ClO4S
    methyl (1S,3S,6S)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate
    —— methyl (1R,3S,6R)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate —— C20H17ClO4S
    methyl (1R,3S,6R)-3-(4-chlorophenyl)sulfanyl-2,4-dioxo-6-phenylcyclohexane-1-carboxylate
    —— [2-oxo-2-[(1S,5S)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C26H28N2O3S
    [2-oxo-2-[(1S,5S)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— (1R,5R)-6,6-dimethyl-3-[2-(2-methylprop-2-enylsulfanyl)ethyl]bicyclo[3.1.1]hept-2-ene —— C15H24S
    (1R,5R)-6,6-dimethyl-3-[2-(2-methylprop-2-enylsulfanyl)ethyl]bicyclo[3.1.1]hept-2-ene
    —— (1S,5S)-6,6-dimethyl-3-[2-(2-methylprop-2-enylsulfanyl)ethyl]bicyclo[3.1.1]hept-2-ene —— C15H24S
    (1S,5S)-6,6-dimethyl-3-[2-(2-methylprop-2-enylsulfanyl)ethyl]bicyclo[3.1.1]hept-2-ene
    —— (2R)-3-(dodecylsulfanylmethylsulfonyl)-2-methylpropanamide —— C17H35NO3S2
    (2R)-3-(dodecylsulfanylmethylsulfonyl)-2-methylpropanamide
    —— 4-(2-oxopyrido[2,3-b][1,4]thiazin-1-yl)-N-propan-2-ylbutanamide —— C14H19N3O2S
    4-(2-oxopyrido[2,3-b][1,4]thiazin-1-yl)-N-propan-2-ylbutanamide
    —— 6,8-dimethyl-1-(3-methylbenzyl)-1H-pyrido[2,3-b][1,4]thiazin-2(3H)-one —— C17H18N2OS
    6,8-dimethyl-1-(3-methylbenzyl)-1H-pyrido[2,3-b][1,4]thiazin-2(3H)-one
    —— 2-((6-(pyridin-4-yl)pyridazin-3-yl)thio)-N-((tetrahydrofuran-2-yl)methyl)acetamide —— C16H18N4O2S
    2-((6-(pyridin-4-yl)pyridazin-3-yl)thio)-N-((tetrahydrofuran-2-yl)methyl)acetamide
    —— 2-(2-methylanilino)-N-[(Z)-[5-[5-[(Z)-[[2-(2-methylanilino)acetyl]hydrazinylidene]methyl]furan-2-yl]sulfanylfuran-2-yl]methylideneamino]acetamide —— C28H28N6O4S
    2-(2-methylanilino)-N-[(Z)-[5-[5-[(Z)-[[2-(2-methylanilino)acetyl]hydrazinylidene]methyl]furan-2-yl]sulfanylfuran-2-yl]methylideneamino]acetamide
    —— (4-phenyl-3,6-dihydro-2H-pyridin-1-yl)-[(1'S,5'S)-spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-yl]methanone —— C22H27NOS2
    (4-phenyl-3,6-dihydro-2H-pyridin-1-yl)-[(1'S,5'S)-spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-yl]methanone
    —— 5-[[5-(1H-benzimidazol-2-ylthio)-2-furanyl]methylidene]-3-propan-2-ylthiazolidine-2,4-dione —— C18H15N3O3S2
    5-[[5-(1H-benzimidazol-2-ylthio)-2-furanyl]methylidene]-3-propan-2-ylthiazolidine-2,4-dione
    —— (4-phenyl-3,6-dihydro-2H-pyridin-1-yl)-[(1'R,5'R)-spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-yl]methanone —— C22H27NOS2
    (4-phenyl-3,6-dihydro-2H-pyridin-1-yl)-[(1'R,5'R)-spiro[1,3-dithiolane-2,8'-bicyclo[3.2.1]octane]-3'-yl]methanone
    —— N-[3-(1,3-benzothiazol-2-ylsulfanyl)-4-hydroxyphenyl]benzenesulfonamide —— C19H14N2O3S3
    N-[3-(1,3-benzothiazol-2-ylsulfanyl)-4-hydroxyphenyl]benzenesulfonamide
    —— N-Cyclohexyl-2-({4-oxo-3H,4H,5H,6H,7H-cyclopenta[D]pyrimidin-2-YL}sulfanyl)butanamide —— C17H25N3O2S
    N-Cyclohexyl-2-({4-oxo-3H,4H,5H,6H,7H-cyclopenta[D]pyrimidin-2-YL}sulfanyl)butanamide
    —— (4R)-5-methyl-4-(2,3,4,5,6-pentafluorophenyl)sulfanyl-2-phenyl-4H-pyrazol-3-one —— C16H9F5N2OS
    (4R)-5-methyl-4-(2,3,4,5,6-pentafluorophenyl)sulfanyl-2-phenyl-4H-pyrazol-3-one
    —— (4S)-5-methyl-4-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-2-phenyl-4H-pyrazol-3-one —— C13H13N5OS
    (4S)-5-methyl-4-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanyl]-2-phenyl-4H-pyrazol-3-one
    —— 4-bromo-N-(3,4,4-trichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl)aniline —— C16H10BrCl3N2O2S
    4-bromo-N-(3,4,4-trichloro-2-nitro-1-phenylsulfanylbuta-1,3-dienyl)aniline
    —— 6-(Furan-2-ylmethyl)-5-methylsulfanyl-3-(2-phenylethyl)-2-sulfanylidene-[1,3]thiazolo[4,5-d]pyrimidin-7-one —— C19H17N3O2S3
    6-(Furan-2-ylmethyl)-5-methylsulfanyl-3-(2-phenylethyl)-2-sulfanylidene-[1,3]thiazolo[4,5-d]pyrimidin-7-one
    —— 4-(4-Phenylsulfanyl-6-prop-2-enoxy-1,3,5-triazin-2-yl)morpholine —— C16H18N4O2S
    4-(4-Phenylsulfanyl-6-prop-2-enoxy-1,3,5-triazin-2-yl)morpholine
    —— 2-[(4-Bromophenyl)sulfanyl]-N-[3-(morpholin-4-YL)propyl]-5-(morpholine-4-sulfonyl)benzamide —— C24H30BrN3O5S2
    2-[(4-Bromophenyl)sulfanyl]-N-[3-(morpholin-4-YL)propyl]-5-(morpholine-4-sulfonyl)benzamide
    —— (5-Aminotetrazol-1-yl)-methyl-[(4-methylsulfanylphenyl)methylidene]azanium —— C10H13N6S+
    (5-Aminotetrazol-1-yl)-methyl-[(4-methylsulfanylphenyl)methylidene]azanium
    —— 2-[(pyridin-4-ylmethylamino)methylidene]-1-benzothiophen-3-one —— C15H12N2OS
    2-[(pyridin-4-ylmethylamino)methylidene]-1-benzothiophen-3-one
    —— 1-[(3R,5R)-3,5-dimethyl-1-adamantyl]-3-prop-2-enylthiourea —— C16H26N2S
    1-[(3R,5R)-3,5-dimethyl-1-adamantyl]-3-prop-2-enylthiourea
    —— 1-[(3R,5R)-3,5-dimethyl-1-adamantyl]-3-(2-methylprop-2-enyl)thiourea —— C17H28N2S
    1-[(3R,5R)-3,5-dimethyl-1-adamantyl]-3-(2-methylprop-2-enyl)thiourea
    —— 1-[(3S,5S)-3,5-dimethyl-1-adamantyl]-3-(2-methylprop-2-enyl)thiourea —— C17H28N2S
    1-[(3S,5S)-3,5-dimethyl-1-adamantyl]-3-(2-methylprop-2-enyl)thiourea
    —— 1-[(3S,5S)-3,5-dimethyl-1-adamantyl]-3-prop-2-enylthiourea —— C16H26N2S
    1-[(3S,5S)-3,5-dimethyl-1-adamantyl]-3-prop-2-enylthiourea
    —— (NE)-N-[(4E,8E,12S)-12-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]cyclododeca-4,8-dien-1-ylidene]hydroxylamine —— C15H21N3OS2
    (NE)-N-[(4E,8E,12S)-12-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]cyclododeca-4,8-dien-1-ylidene]hydroxylamine
    —— (NE)-N-[(8R)-8-(1H-1,2,4-triazol-5-ylsulfanyl)cyclooct-4-en-1-ylidene]hydroxylamine —— C10H14N4OS
    (NE)-N-[(8R)-8-(1H-1,2,4-triazol-5-ylsulfanyl)cyclooct-4-en-1-ylidene]hydroxylamine