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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— methyl (2Z)-2-[3-(3-methylsulfanylphenyl)-4-oxo-2-pyridin-2-ylimino-1,3-thiazolidin-5-ylidene]acetate —— C18H15N3O3S2
    methyl (2Z)-2-[3-(3-methylsulfanylphenyl)-4-oxo-2-pyridin-2-ylimino-1,3-thiazolidin-5-ylidene]acetate
    —— (6R)-3-benzylsulfanyl-4-oxo-6-phenyl-6,7-dihydro-5H-2-benzothiophene-1-carbonitrile —— C22H17NOS2
    (6R)-3-benzylsulfanyl-4-oxo-6-phenyl-6,7-dihydro-5H-2-benzothiophene-1-carbonitrile
    —— 5-[[(1S)-2,2-dichlorocyclopropyl]methylsulfanyl]-1,3,4-thiadiazol-2-amine —— C6H7Cl2N3S2
    5-[[(1S)-2,2-dichlorocyclopropyl]methylsulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-(4-chlorophenyl)sulfanyl-N-[(2R)-2-hydroxy-3-(4-methoxyphenoxy)propyl]pyridine-3-carboxamide —— C22H21ClN2O4S
    2-(4-chlorophenyl)sulfanyl-N-[(2R)-2-hydroxy-3-(4-methoxyphenoxy)propyl]pyridine-3-carboxamide
    —— (2S,3S)-3-(4-methylsulfanylphenyl)-2,3-di(morpholin-4-ium-4-yl)-1-thiophen-2-ylpropan-1-one —— C22H30N2O3S2+2
    (2S,3S)-3-(4-methylsulfanylphenyl)-2,3-di(morpholin-4-ium-4-yl)-1-thiophen-2-ylpropan-1-one
    —— 4-[2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]morpholin-4-ium —— C21H23N4OS+
    4-[2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethyl]morpholin-4-ium
    —— (2S)-2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C10H13N2O3S-
    (2S)-2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— N-(3-methylsulfanylphenyl)-1-propylpiperidin-1-ium-4-amine —— C15H25N2S+
    N-(3-methylsulfanylphenyl)-1-propylpiperidin-1-ium-4-amine
    —— Bis(2-hydroxyethyl)-[(2-naphthalen-1-ylsulfanylphenyl)methyl]azanium —— C21H24NO2S+
    Bis(2-hydroxyethyl)-[(2-naphthalen-1-ylsulfanylphenyl)methyl]azanium
    —— 2-[4-[(2-Naphthalen-1-ylsulfanylphenyl)methyl]piperazine-1,4-diium-1-yl]ethanol —— C23H28N2OS+2
    2-[4-[(2-Naphthalen-1-ylsulfanylphenyl)methyl]piperazine-1,4-diium-1-yl]ethanol
    —— 2-[4-[(1S)-1-(5-chloro-2-phenylsulfanylphenyl)ethyl]piperazine-1,4-diium-1-yl]ethanol —— C20H27ClN2OS+2
    2-[4-[(1S)-1-(5-chloro-2-phenylsulfanylphenyl)ethyl]piperazine-1,4-diium-1-yl]ethanol
    —— methyl (1R,6S)-3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-oxo-6-phenylcyclohex-2-ene-1-carboxylate —— C20H17ClO4S
    methyl (1R,6S)-3-(4-chlorophenyl)sulfanyl-2-hydroxy-4-oxo-6-phenylcyclohex-2-ene-1-carboxylate
    —— 5-[(6-Methyl-2-pyrrolidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-3-(morpholin-4-ium-4-ylmethyl)-1,3,4-oxadiazole-2-thione —— C17H25N6O2S2+
    5-[(6-Methyl-2-pyrrolidin-1-ylpyrimidin-4-yl)sulfanylmethyl]-3-(morpholin-4-ium-4-ylmethyl)-1,3,4-oxadiazole-2-thione
    —— 2-(2-Morpholin-4-ium-4-ylethylsulfanyl)-6-thiophen-2-ylpyridine-3-carbonitrile —— C16H18N3OS2+
    2-(2-Morpholin-4-ium-4-ylethylsulfanyl)-6-thiophen-2-ylpyridine-3-carbonitrile
    —— 2-[5-[(2-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethylazanium —— C11H13FN3OS+
    2-[5-[(2-Fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethylazanium
    —— (6S,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-6-carbonitrile —— C13H10N2OS2
    (6S,7R)-2-oxo-7-phenyl-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-6-carbonitrile
    —— [(1S,2R)-1-[5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium —— C13H25N4O2S+
    [(1S,2R)-1-[5-[2-(diethylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]-2-methylbutyl]azanium
    —— 3-[[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C11H8ClN2O3S-
    3-[[5-(3-Chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— (2R)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C12H11N2O3S-
    (2R)-2-[[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— (2S)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C12H11N2O3S-
    (2S)-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— 4-[2-[(5-Phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethyl]morpholin-4-ium —— C14H18N3O2S+
    4-[2-[(5-Phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]ethyl]morpholin-4-ium
    —— (1R)-1-(4-chlorophenyl)-3-(4-chlorophenyl)sulfanylpropan-1-ol —— C15H14Cl2OS
    (1R)-1-(4-chlorophenyl)-3-(4-chlorophenyl)sulfanylpropan-1-ol
    —— (5E,10R)-10-phenylsulfanylcyclodec-5-en-1-one —— C16H20OS
    (5E,10R)-10-phenylsulfanylcyclodec-5-en-1-one
    —— 1-Methyl-4-(4-phenylsulfanylphenoxy)piperidin-1-ium —— C18H22NOS+
    1-Methyl-4-(4-phenylsulfanylphenoxy)piperidin-1-ium
    —— 2-Amino-6-(2-methylpropylsulfanyl)-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile —— C15H15N4S2+
    2-Amino-6-(2-methylpropylsulfanyl)-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile
    —— [5-Fluoro-2-(4-methylsulfanylphenyl)sulfanylphenyl]methyl-dimethylazanium —— C16H19FNS2+
    [5-Fluoro-2-(4-methylsulfanylphenyl)sulfanylphenyl]methyl-dimethylazanium
    —— 2-Amino-6-[(4-chlorophenyl)methylsulfanyl]pyridin-1-ium-3,5-dicarbonitrile —— C14H10ClN4S+
    2-Amino-6-[(4-chlorophenyl)methylsulfanyl]pyridin-1-ium-3,5-dicarbonitrile
    —— [(2S)-1-[2-(4-hydroxyphenyl)sulfanylphenyl]propan-2-yl]-methylazanium —— C16H20NOS+
    [(2S)-1-[2-(4-hydroxyphenyl)sulfanylphenyl]propan-2-yl]-methylazanium
    —— [5-Chloro-2-(4-methylsulfanylphenyl)sulfanylphenyl]methyl-dimethylazanium —— C16H19ClNS2+
    [5-Chloro-2-(4-methylsulfanylphenyl)sulfanylphenyl]methyl-dimethylazanium
    —— 2-Amino-6-methylsulfanyl-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile —— C12H9N4S2+
    2-Amino-6-methylsulfanyl-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile
    —— [2-(3-Methoxyphenyl)sulfanylphenyl]methyl-dimethylazanium —— C16H20NOS+
    [2-(3-Methoxyphenyl)sulfanylphenyl]methyl-dimethylazanium
    —— 2-[5-Chloro-2-(4-propan-2-ylphenyl)sulfanylphenyl]acetate —— C17H16ClO2S-
    2-[5-Chloro-2-(4-propan-2-ylphenyl)sulfanylphenyl]acetate
    —— (2R)-3-methyl-2-(1,3-thiazol-2-ylsulfanyl)butanoate —— C8H10NO2S2-
    (2R)-3-methyl-2-(1,3-thiazol-2-ylsulfanyl)butanoate
    —— 6-Methyl-2-phenylsulfanylpyridine-3-carboxylate —— C13H10NO2S-
    6-Methyl-2-phenylsulfanylpyridine-3-carboxylate
    —— (2S)-3-methyl-2-(1,3-thiazol-2-ylsulfanyl)butanoate —— C8H10NO2S2-
    (2S)-3-methyl-2-(1,3-thiazol-2-ylsulfanyl)butanoate
    —— N-[[2-(4-fluorophenyl)sulfanylphenyl]methyl]-4,5-dihydro-1H-imidazol-3-ium-2-amine —— C16H17FN3S+
    N-[[2-(4-fluorophenyl)sulfanylphenyl]methyl]-4,5-dihydro-1H-imidazol-3-ium-2-amine
    —— [4-(3-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H17ClNS+
    [4-(3-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium
    —— (2S)-3-methyl-2-pyrimidin-2-ylsulfanylbutanoate —— C9H11N2O2S-
    (2S)-3-methyl-2-pyrimidin-2-ylsulfanylbutanoate
    —— 2-(3-Cyano-6-ethyl-5-methylpyridin-2-yl)sulfanylacetate —— C11H11N2O2S-
    2-(3-Cyano-6-ethyl-5-methylpyridin-2-yl)sulfanylacetate
    —— (2R)-3-methyl-2-pyrimidin-2-ylsulfanylbutanoate —— C9H11N2O2S-
    (2R)-3-methyl-2-pyrimidin-2-ylsulfanylbutanoate
    —— 2-Amino-6-methylsulfanyl-4-propan-2-ylpyridin-1-ium-3,5-dicarbonitrile —— C11H13N4S+
    2-Amino-6-methylsulfanyl-4-propan-2-ylpyridin-1-ium-3,5-dicarbonitrile
    —— (3S,6R)-N-cyclohexyltricyclo[4.3.1.13,8]undecane-1-carbothioamide —— C18H29NS
    (3S,6R)-N-cyclohexyltricyclo[4.3.1.13,8]undecane-1-carbothioamide
    —— 2-[(2-Chlorophenyl)methylsulfanyl]-4-(dimethylamino)pyridin-1-ium-3-carbonitrile —— C15H15ClN3S+
    2-[(2-Chlorophenyl)methylsulfanyl]-4-(dimethylamino)pyridin-1-ium-3-carbonitrile
    —— (2R)-1,1-dichloro-2-[[(1S)-2,2-dichlorocyclopropyl]methylsulfonylmethyl]cyclopropane —— C8H10Cl4O2S
    (2R)-1,1-dichloro-2-[[(1S)-2,2-dichlorocyclopropyl]methylsulfonylmethyl]cyclopropane
    —— Ethyl 2-[6-amino-3,5-dicyano-4-(2-methylpropyl)pyridin-1-ium-2-yl]sulfanylacetate —— C15H19N4O2S+
    Ethyl 2-[6-amino-3,5-dicyano-4-(2-methylpropyl)pyridin-1-ium-2-yl]sulfanylacetate
    —— (3R)-3-phenylsulfanyl-2,3-dihydro-1-benzothiophene 1,1-dioxide —— C14H12O2S2
    (3R)-3-phenylsulfanyl-2,3-dihydro-1-benzothiophene 1,1-dioxide
    —— 1.3-Bis-tetradecylmercapto-propan 96591-10-5 C31H64S2
    1.3-Bis-tetradecylmercapto-propan
    —— (2S)-2-cyano-3-oxobutanethioamide —— C5H6N2OS
    (2S)-2-cyano-3-oxobutanethioamide
    —— 3-(4-Fluorophenyl)sulfanylpropanoate —— C9H8FO2S-
    3-(4-Fluorophenyl)sulfanylpropanoate
    —— 4-Methylmercaptophenylacetate —— C9H9O2S-
    4-Methylmercaptophenylacetate