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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(2-Pyrimidinylthio)acetate —— C6H5N2O2S-
    2-(2-Pyrimidinylthio)acetate
    —— (7R)-7-methyl-4-phenylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine —— C17H16N2S2
    (7R)-7-methyl-4-phenylsulfanyl-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidine
    —— (5R)-3-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-5-phenylcyclohex-2-en-1-one —— C15H14N2OS3
    (5R)-3-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-5-phenylcyclohex-2-en-1-one
    —— 4-(4-Chlorophenyl)sulfanyl-2,5-dihydrothiophene-3-carboxylate —— C11H8ClO2S2-
    4-(4-Chlorophenyl)sulfanyl-2,5-dihydrothiophene-3-carboxylate
    —— 6-Methoxycarbonyl-5-methyl-2,3-dihydropyrrolo[2,1-b][1,3]thiazole-7-carboxylate —— C10H10NO4S-
    6-Methoxycarbonyl-5-methyl-2,3-dihydropyrrolo[2,1-b][1,3]thiazole-7-carboxylate
    —— [(2R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropyl]-dimethylazanium —— C11H20N3S+
    [(2R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropyl]-dimethylazanium
    —— (4S)-4-hydroxy-3-methylsulfanyl-4,5,6,7-tetrahydro-2-benzothiophene-1-carbonitrile —— C10H11NOS2
    (4S)-4-hydroxy-3-methylsulfanyl-4,5,6,7-tetrahydro-2-benzothiophene-1-carbonitrile
    —— 2-(4-Chlorophenyl)sulfanylpyridine-3-carboxylate —— C12H7ClNO2S-
    2-(4-Chlorophenyl)sulfanylpyridine-3-carboxylate
    —— 1-[(R)-methylsulfinyl]nonadecan-2-one —— C20H40O2S
    1-[(R)-methylsulfinyl]nonadecan-2-one
    —— 1-[(S)-methylsulfinyl]nonadecan-2-one —— C20H40O2S
    1-[(S)-methylsulfinyl]nonadecan-2-one
    —— thiolaurinoic acid <i>S</i>-(5-thioxo-4,5-dihydro-[1,3,4]thiadiazol-2-yl ester) 109477-30-7 C14H24N2OS3
    thiolaurinoic acid <i>S</i>-(5-thioxo-4,5-dihydro-[1,3,4]thiadiazol-2-yl ester)
    —— (2S)-1-(4-chloroanilino)-3-(4-chlorophenyl)sulfanylpropan-2-ol —— C15H15Cl2NOS
    (2S)-1-(4-chloroanilino)-3-(4-chlorophenyl)sulfanylpropan-2-ol
    —— 2-amino-4-(furan-2-yl)-6-[(1S)-2-oxocyclohexyl]sulfanylpyridin-1-ium-3,5-dicarbonitrile —— C17H15N4O2S+
    2-amino-4-(furan-2-yl)-6-[(1S)-2-oxocyclohexyl]sulfanylpyridin-1-ium-3,5-dicarbonitrile
    —— (2R)-1-(4-chloroanilino)-3-(4-chlorophenyl)sulfanylpropan-2-ol —— C15H15Cl2NOS
    (2R)-1-(4-chloroanilino)-3-(4-chlorophenyl)sulfanylpropan-2-ol
    —— 1,1-dimethyl-3-[(1S,5S)-3,3,5-trimethylcyclohexyl]thiourea —— C12H24N2S
    1,1-dimethyl-3-[(1S,5S)-3,3,5-trimethylcyclohexyl]thiourea
    —— (2R)-2-pyridin-3-yl-3,1-benzoxathiin-4-one —— C13H9NO2S
    (2R)-2-pyridin-3-yl-3,1-benzoxathiin-4-one
    —— 2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(1R,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone —— C23H36N4OS
    2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(1R,5R)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone
    —— 2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(1S,5S)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone —— C23H36N4OS
    2-[(5-cyclohexyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]-1-[(1S,5S)-1,3,3-trimethyl-6-azabicyclo[3.2.1]octan-6-yl]ethanone
    —— 2-([1,2,4]Triazolo[3,4-c][1,2,4]benzotriazin-1-ylsulfanyl)acetate —— C10H6N5O2S-
    2-([1,2,4]Triazolo[3,4-c][1,2,4]benzotriazin-1-ylsulfanyl)acetate
    —— 2-[(Z)-2-(5-cyclohexylsulfanylfuran-2-yl)ethenyl]-4-hydroxy-5-nitro-1H-pyrimidin-6-one —— C16H17N3O5S
    2-[(Z)-2-(5-cyclohexylsulfanylfuran-2-yl)ethenyl]-4-hydroxy-5-nitro-1H-pyrimidin-6-one
    —— 2-[(5Z)-5-[[4-(4-methylphenyl)sulfanylphenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid —— C19H15NO3S3
    2-[(5Z)-5-[[4-(4-methylphenyl)sulfanylphenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetic acid
    —— 2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(oxolan-2-ylmethyl)acetamide —— C14H18N4O3S
    2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-(oxolan-2-ylmethyl)acetamide
    —— (Z)-hept-2-ene-2,3-dithiol —— C7H14S2
    (Z)-hept-2-ene-2,3-dithiol
    —— cis-Dimercapto-ethylen 762-54-9 C2H4S2
    cis-Dimercapto-ethylen
    —— N-(4-ethylphenyl)-5-(oxan-2-ylmethylsulfanyl)-1,3,4-thiadiazol-2-amine —— C16H21N3OS2
    N-(4-ethylphenyl)-5-(oxan-2-ylmethylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— (6R)-6-(2,5-dimethylanilino)-2-(ethylamino)-4-ethylimino-7H-[1,3]thiazolo[3,2-a][1,3,5]triazin-6-ol —— C17H24N6OS
    (6R)-6-(2,5-dimethylanilino)-2-(ethylamino)-4-ethylimino-7H-[1,3]thiazolo[3,2-a][1,3,5]triazin-6-ol
    —— (6S)-6-(2,5-dimethylanilino)-2-(ethylamino)-4-ethylimino-7H-[1,3]thiazolo[3,2-a][1,3,5]triazin-6-ol —— C17H24N6OS
    (6S)-6-(2,5-dimethylanilino)-2-(ethylamino)-4-ethylimino-7H-[1,3]thiazolo[3,2-a][1,3,5]triazin-6-ol
    —— N-[(E)-(4-methylsulfanylphenyl)methylideneamino]methanamine —— C9H12N2S
    N-[(E)-(4-methylsulfanylphenyl)methylideneamino]methanamine
    —— 3-[(2,4-dimethylphenyl)sulfamoyl]-N-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]benzamide —— C26H22N6O5S2
    3-[(2,4-dimethylphenyl)sulfamoyl]-N-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]benzamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(E)-(3,4-difluorophenyl)methylideneamino]acetamide —— C17H15BrF2N2OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(E)-(3,4-difluorophenyl)methylideneamino]acetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(E)-(4-bromophenyl)methylideneamino]acetamide —— C17H16Br2N2OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(E)-(4-bromophenyl)methylideneamino]acetamide
    —— N-methyl-N-[(E)-[5-(2-nitrophenyl)sulfanylfuran-2-yl]methylideneamino]methanamine —— C13H13N3O3S
    N-methyl-N-[(E)-[5-(2-nitrophenyl)sulfanylfuran-2-yl]methylideneamino]methanamine
    —— N-[(E)-[2-methyl-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyrazolo[1,5-a]quinazolin-3-yl]methylideneamino]-3-pyrrolidin-1-ylsulfonylbenzamide —— C26H25N9O3S2
    N-[(E)-[2-methyl-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]pyrazolo[1,5-a]quinazolin-3-yl]methylideneamino]-3-pyrrolidin-1-ylsulfonylbenzamide
    —— 6-(2-nitrophenyl)sulfanyl-5-phenyl-3-[(E)-thiophen-2-ylmethylideneamino]thieno[2,3-d]pyrimidin-4-one —— C23H14N4O3S3
    6-(2-nitrophenyl)sulfanyl-5-phenyl-3-[(E)-thiophen-2-ylmethylideneamino]thieno[2,3-d]pyrimidin-4-one
    —— 4-[(4-Methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde oxime —— C14H12N2O3S
    4-[(4-Methylphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde oxime
    —— (Z)-N-[(2R)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-3-thiophen-2-ylprop-2-enamide —— C16H17NO2S2
    (Z)-N-[(2R)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-3-thiophen-2-ylprop-2-enamide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]acetamide —— C14H12ClN3OS
    2-(4-chlorophenyl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]acetamide
    —— (Z)-N-[(2S)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-3-thiophen-2-ylprop-2-enamide —— C16H17NO2S2
    (Z)-N-[(2S)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-3-thiophen-2-ylprop-2-enamide
    —— (Z)-N-[(2S)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-3-thiophen-3-ylprop-2-enamide —— C16H17NO2S2
    (Z)-N-[(2S)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-3-thiophen-3-ylprop-2-enamide
    —— (Z)-3-(furan-3-yl)-N-[(2R)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]prop-2-enamide —— C16H17NO3S
    (Z)-3-(furan-3-yl)-N-[(2R)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]prop-2-enamide
    —— (Z)-N-[(2R)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-3-thiophen-3-ylprop-2-enamide —— C16H17NO2S2
    (Z)-N-[(2R)-2-hydroxy-2-(4-methylsulfanylphenyl)ethyl]-3-thiophen-3-ylprop-2-enamide
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-pyridin-3-ylmethanimine —— C16H14BrN5S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-pyridin-3-ylmethanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine —— C18H19BrN4S2
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine
    —— (E)-1-(5-bromofuran-2-yl)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]methanimine —— C17H16Br2N4OS
    (E)-1-(5-bromofuran-2-yl)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-chlorophenyl)methanimine —— C17H14BrClN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-chlorophenyl)methanimine
    —— N-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-2-[3-(trifluoromethyl)pyrazol-1-yl]acetamide —— C17H12F3N7O3S
    N-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-2-[3-(trifluoromethyl)pyrazol-1-yl]acetamide
    —— 3-[(E)-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]iminomethyl]phenol —— C17H15BrN4OS
    3-[(E)-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]iminomethyl]phenol
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(4-methylsulfanylphenyl)methanimine —— C20H21BrN4S2
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-(4-methylsulfanylphenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2-chlorophenyl)methanimine —— C17H14BrClN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2-chlorophenyl)methanimine
    —— 3-[(E)-hydroxyiminomethyl]-7-methyl-2-(4-methylphenyl)sulfanylpyrido[1,2-a]pyrimidin-4-one —— C17H15N3O2S
    3-[(E)-hydroxyiminomethyl]-7-methyl-2-(4-methylphenyl)sulfanylpyrido[1,2-a]pyrimidin-4-one