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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[5-(Methylsulfanyl)-1,3,4-oxadiazol-2-yl]ethan-1-amine —— C5H9N3OS
    1-[5-(Methylsulfanyl)-1,3,4-oxadiazol-2-yl]ethan-1-amine
    —— N-(4-phenylbutan-2-yl)-2-pyrimidin-2-ylsulfanylacetamide —— C16H19N3OS
    N-(4-phenylbutan-2-yl)-2-pyrimidin-2-ylsulfanylacetamide
    —— (3S,4R)-7-fluoro-2,2-dioxo-2lambda6-thiaspiro[3.5]nona-5,7-diene-3-carboxylic acid —— C9H9FO4S
    (3S,4R)-7-fluoro-2,2-dioxo-2lambda6-thiaspiro[3.5]nona-5,7-diene-3-carboxylic acid
    —— (3S,4S)-7-fluoro-2,2-dioxo-2lambda6-thiaspiro[3.5]nona-5,7-diene-3-carboxylic acid —— C9H9FO4S
    (3S,4S)-7-fluoro-2,2-dioxo-2lambda6-thiaspiro[3.5]nona-5,7-diene-3-carboxylic acid
    —— Carbon monoxide;iron(3+);methylsulfanium —— C8H10Fe2O6S2+8
    Carbon monoxide;iron(3+);methylsulfanium
    —— 2-(2-amino-1,3-thiazol-4-yl)-N-[(2-methylsulfanylthiophen-3-yl)methylideneamino]acetamide —— C11H12N4OS3
    2-(2-amino-1,3-thiazol-4-yl)-N-[(2-methylsulfanylthiophen-3-yl)methylideneamino]acetamide
    —— (3R,4R)-7-fluoro-2,2-dioxo-2lambda6-thiaspiro[3.5]nona-5,7-diene-3-carboxylic acid —— C9H9FO4S
    (3R,4R)-7-fluoro-2,2-dioxo-2lambda6-thiaspiro[3.5]nona-5,7-diene-3-carboxylic acid
    —— (3R,4S)-7-fluoro-2,2-dioxo-2lambda6-thiaspiro[3.5]nona-5,7-diene-3-carboxylic acid —— C9H9FO4S
    (3R,4S)-7-fluoro-2,2-dioxo-2lambda6-thiaspiro[3.5]nona-5,7-diene-3-carboxylic acid
    —— 4-[(4-Chlorophenyl)sulfanylmethyl]-5-methylthiophene-2-carbaldehyde —— C13H11ClOS2
    4-[(4-Chlorophenyl)sulfanylmethyl]-5-methylthiophene-2-carbaldehyde
    —— methyl 5-[2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C20H22N4O3S2
    methyl 5-[2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 5-(2,4-dimethylbenzylthio)-1-methyl-1H-tetrazole —— C11H14N4S
    5-(2,4-dimethylbenzylthio)-1-methyl-1H-tetrazole
    —— 3-[5-(4-Methylphenyl)sulfanylfuran-2-yl]-2-(3-nitrobenzoyl)prop-2-enenitrile —— C21H14N2O4S
    3-[5-(4-Methylphenyl)sulfanylfuran-2-yl]-2-(3-nitrobenzoyl)prop-2-enenitrile
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C14H15F3N4O2S
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[4-methyl-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— 2-[(5-Phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetohydrazide —— C10H10N4O2S
    2-[(5-Phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetohydrazide
    —— 4-[[2-(4-Chlorophenyl)sulfanylphenyl]methylidene]-1-phenylpyrazolidine-3,5-dione —— C22H15ClN2O2S
    4-[[2-(4-Chlorophenyl)sulfanylphenyl]methylidene]-1-phenylpyrazolidine-3,5-dione
    —— 4-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-3-nitrobenzonitrile —— C13H10N4O2S
    4-(4,6-Dimethylpyrimidin-2-yl)sulfanyl-3-nitrobenzonitrile
    —— 4-amino-7,7-dimethyl-2-[4-(methylsulfanyl)phenyl]-5-oxo-5,6,7,8-tetrahydro-2H-chromene-3-carbonitrile —— C19H20N2O2S
    4-amino-7,7-dimethyl-2-[4-(methylsulfanyl)phenyl]-5-oxo-5,6,7,8-tetrahydro-2H-chromene-3-carbonitrile
    —— 3-[(4-Methyl-1,2,4-triazol-3-yl)sulfanyl]-1-pyrrolidin-1-ylpropan-1-one —— C10H16N4OS
    3-[(4-Methyl-1,2,4-triazol-3-yl)sulfanyl]-1-pyrrolidin-1-ylpropan-1-one
    —— 1-[(3S)-5-(furan-2-yl)-3-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C19H21N5O3S2
    1-[(3S)-5-(furan-2-yl)-3-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— 2-(4-chlorophenyl)sulfanyl-N-[(3,3-dimethyl-5-oxocyclohexylidene)amino]propanamide —— C17H21ClN2O2S
    2-(4-chlorophenyl)sulfanyl-N-[(3,3-dimethyl-5-oxocyclohexylidene)amino]propanamide
    —— 1-[(3R)-5-(furan-2-yl)-3-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C19H21N5O3S2
    1-[(3R)-5-(furan-2-yl)-3-thiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-[[4-(3-methoxypropyl)-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— 2-({3-[(Furan-2-YL)methyl]-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL}sulfanyl)-N-(3-methylbutyl)acetamide —— C23H24N4O3S3
    2-({3-[(Furan-2-YL)methyl]-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL}sulfanyl)-N-(3-methylbutyl)acetamide
    —— N-(Butan-2-YL)-2-({3-[(furan-2-YL)methyl]-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL}sulfanyl)acetamide —— C22H22N4O3S3
    N-(Butan-2-YL)-2-({3-[(furan-2-YL)methyl]-7-oxo-6-phenyl-2-sulfanylidene-2H,3H,6H,7H-[1,3]thiazolo[4,5-D]pyrimidin-5-YL}sulfanyl)acetamide
    —— S-methyl N-(3-ethyl-1-adamantyl)carbamothioate —— C14H23NOS
    S-methyl N-(3-ethyl-1-adamantyl)carbamothioate
    —— [(2R)-oxolan-2-yl]methyl 3-phenylsulfanylpropanoate —— C14H18O3S
    [(2R)-oxolan-2-yl]methyl 3-phenylsulfanylpropanoate
    —— 2-(1H-benzimidazol-2-yl)-3-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]prop-2-enenitrile —— C20H14N6O2S
    2-(1H-benzimidazol-2-yl)-3-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]prop-2-enenitrile
    —— [(2S)-oxolan-2-yl]methyl 3-phenylsulfanylpropanoate —— C14H18O3S
    [(2S)-oxolan-2-yl]methyl 3-phenylsulfanylpropanoate
    —— 2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylacetamide —— C19H25N3O2S2
    2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylacetamide
    —— (2R)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide —— C20H27N3O2S2
    (2R)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide
    —— 2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethylacetamide —— C18H25N3O2S2
    2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-ethylacetamide
    —— 2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide —— C17H23N3O2S2
    2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H23N3O2S
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide —— C20H27N3O2S2
    (2S)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide
    —— (2S)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide —— C20H27N3O2S2
    (2S)-2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide
    —— 2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylacetamide —— C19H25N3O2S2
    2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylacetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]acetamide —— C18H22ClN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]acetamide
    —— (2R)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide —— C20H27N3O2S2
    (2R)-2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclopropylpropanamide
    —— 3-[[4-(4-Methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one —— C24H20N4O3S2
    3-[[4-(4-Methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-5,6,7,8-tetrahydro-[1]benzothiolo[2,3-d]pyrimidin-4-one
    —— N-[2-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C14H14FN3OS
    N-[2-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— 2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide —— C17H23N3O2S2
    2-[[5-[(5R)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]-N-methylacetamide
    —— 2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]acetamide —— C18H22ClN3O2S
    2-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]acetamide
    —— N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C21H23N3O2S
    N-[(1R)-1-(4-ethylphenyl)ethyl]-2-[[5-(2-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— [2-(1-Adamantylamino)-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate —— C21H26BrNO3S
    [2-(1-Adamantylamino)-2-oxoethyl] 2-(4-bromo-2-methylphenyl)sulfanylacetate
    —— Butyl-S-(6-hydroxy-4-methyl-2-pyrimidyl)-thioglycolat 21418-90-6 C11H16N2O3S
    Butyl-S-(6-hydroxy-4-methyl-2-pyrimidyl)-thioglycolat
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N,N-bis(prop-2-enyl)propanamide —— C15H18ClNOS
    (2R)-2-(4-chlorophenyl)sulfanyl-N,N-bis(prop-2-enyl)propanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N,N-bis(prop-2-enyl)propanamide —— C15H18ClNOS
    (2S)-2-(4-chlorophenyl)sulfanyl-N,N-bis(prop-2-enyl)propanamide
    —— 2-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-[1-[(2-chlorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]ethanone —— C24H23ClN4OS2
    2-[[5-(Benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-1-[1-[(2-chlorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— N-[[4-(3-methoxyphenyl)-5-[5-(trifluoromethyl)pyridin-2-yl]sulfanyl-1,2,4-triazol-3-yl]methyl]acetamide —— C18H16F3N5O2S
    N-[[4-(3-methoxyphenyl)-5-[5-(trifluoromethyl)pyridin-2-yl]sulfanyl-1,2,4-triazol-3-yl]methyl]acetamide
    —— 1-{5-[(4-chlorophenyl)sulfanyl]-4-phenyl-1,3-thiazol-2-yl}-4-(2-thienyl)-1H-pyrazol-5-amine —— C22H15ClN4S3
    1-{5-[(4-chlorophenyl)sulfanyl]-4-phenyl-1,3-thiazol-2-yl}-4-(2-thienyl)-1H-pyrazol-5-amine
    —— 3-benzyl-4-ethyl-5-[(1R)-1-phenylethyl]sulfanyl-1,2,4-triazole —— C19H21N3S
    3-benzyl-4-ethyl-5-[(1R)-1-phenylethyl]sulfanyl-1,2,4-triazole