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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 4-[2-[2-(1H-pyrazol-4-ylsulfanyl)ethoxy]ethylsulfanyl]phenol —— C13H16N2O2S2
    4-[2-[2-(1H-pyrazol-4-ylsulfanyl)ethoxy]ethylsulfanyl]phenol
    —— N-methyl-4-(4-methylphenyl)sulfanylthieno[3,2-d]pyrimidin-7-amine —— C14H13N3S2
    N-methyl-4-(4-methylphenyl)sulfanylthieno[3,2-d]pyrimidin-7-amine
    —— 2-[(Z)-3,4,4-trifluorobut-2-enyl]sulfanyl-[1,3]thiazolo[4,5-b]pyridine —— C10H7F3N2S2
    2-[(Z)-3,4,4-trifluorobut-2-enyl]sulfanyl-[1,3]thiazolo[4,5-b]pyridine
    —— 2-(5-Methylsulfanyl-4-phenylthiophen-2-yl)-2-oxoethanimidamide —— C13H12N2OS2
    2-(5-Methylsulfanyl-4-phenylthiophen-2-yl)-2-oxoethanimidamide
    —— 3-[[(3R)-1-azabicyclo[2.2.1]heptan-3-yl]oxy]-4-butylsulfanyl-1,2,5-thiadiazole —— C12H19N3OS2
    3-[[(3R)-1-azabicyclo[2.2.1]heptan-3-yl]oxy]-4-butylsulfanyl-1,2,5-thiadiazole
    —— 3-(1-Azatricyclo[3.3.1.13,7]decan-4-yl)-4-ethylsulfanyl-1,2,5-thiadiazole —— C13H19N3S2
    3-(1-Azatricyclo[3.3.1.13,7]decan-4-yl)-4-ethylsulfanyl-1,2,5-thiadiazole
    —— 3-[[(1S)-2-amino-1-phenylethyl]thio]-5-methyl-2-thiophenecarbonitrile —— C14H14N2S2
    3-[[(1S)-2-amino-1-phenylethyl]thio]-5-methyl-2-thiophenecarbonitrile
    —— 5-Methylsulfanyl-4-(4-methyl-thiazol-2-yl)-thiophene-2-carboxamidine —— C10H11N3S3
    5-Methylsulfanyl-4-(4-methyl-thiazol-2-yl)-thiophene-2-carboxamidine
    —— N-[(4-amino-2-methylpyrimidin-5-yl)methyl]-N-(2-phenylsulfanylphenyl)formamide —— C19H18N4OS
    N-[(4-amino-2-methylpyrimidin-5-yl)methyl]-N-(2-phenylsulfanylphenyl)formamide
    —— 3-(1-Azabicyclo[2.2.1]heptan-3-yl)-4-(2-phenylsulfanylethylsulfanyl)-1,2,5-thiadiazole —— C16H19N3S3
    3-(1-Azabicyclo[2.2.1]heptan-3-yl)-4-(2-phenylsulfanylethylsulfanyl)-1,2,5-thiadiazole
    —— 4-isobutylthio-3-isopropyl-1-methyl-5-{[(pyridin-4-ylmethyl)amino] methyl}-1,3-dihydro-2-imidazolone —— C18H28N4OS
    4-isobutylthio-3-isopropyl-1-methyl-5-{[(pyridin-4-ylmethyl)amino] methyl}-1,3-dihydro-2-imidazolone
    —— 4-[[4-Methyl-6-(o-tolylsulfanyl)-3-oxo-pyrazin-2-yl]amino]benzonitrile —— C19H16N4OS
    4-[[4-Methyl-6-(o-tolylsulfanyl)-3-oxo-pyrazin-2-yl]amino]benzonitrile
    —— ethyl (4S)-6-amino-4-(2-chlorophenyl)-5-cyano-2-[(3-cyano-6-thiophen-2-ylpyridin-2-yl)sulfanylmethyl]-4H-pyran-3-carboxylate —— C26H19ClN4O3S2
    ethyl (4S)-6-amino-4-(2-chlorophenyl)-5-cyano-2-[(3-cyano-6-thiophen-2-ylpyridin-2-yl)sulfanylmethyl]-4H-pyran-3-carboxylate
    —— 3-(6-Phenylsulfanylpyridin-3-yl)-3,10-diazabicyclo[4.3.1]decane —— C19H23N3S
    3-(6-Phenylsulfanylpyridin-3-yl)-3,10-diazabicyclo[4.3.1]decane
    —— 2-[(1R,3S)-3-amino-4-hydroxy-1-phenylbutyl]sulfanyl-6-(hydroxymethyl)pyridine-3-carbonitrile —— C17H19N3O2S
    2-[(1R,3S)-3-amino-4-hydroxy-1-phenylbutyl]sulfanyl-6-(hydroxymethyl)pyridine-3-carbonitrile
    —— 2,2,2-Trifluoroethyl 2-(4-pyrazol-1-ylpyrimidin-2-yl)sulfanylacetate —— C11H9F3N4O2S
    2,2,2-Trifluoroethyl 2-(4-pyrazol-1-ylpyrimidin-2-yl)sulfanylacetate
    —— trans-N-(cyanomethyl)-2-({[4-(methylsulfanyl)phenyl]sulfanyl}-methyl)cyclopentanecarboxamide —— C16H20N2OS2
    trans-N-(cyanomethyl)-2-({[4-(methylsulfanyl)phenyl]sulfanyl}-methyl)cyclopentanecarboxamide
    —— 2-[(1S)-2-amino-1-phenylethyl]sulfanyl-6-(trifluoromethyl)pyridine-3-carbonitrile —— C15H12F3N3S
    2-[(1S)-2-amino-1-phenylethyl]sulfanyl-6-(trifluoromethyl)pyridine-3-carbonitrile
    —— Ethyl 2-[4-(5-nitropyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate —— C11H11N5O4S
    Ethyl 2-[4-(5-nitropyrazol-1-yl)pyrimidin-2-yl]sulfanylacetate
    —— trans-N-cyanomethyl-2-(4-fluorophenylsulfanylmethyl)-cyclohexanecarboxamide —— C16H19FN2OS
    trans-N-cyanomethyl-2-(4-fluorophenylsulfanylmethyl)-cyclohexanecarboxamide
    —— 2-Amino-4-furan-2-yl-6-(pyridin-2-ylmethylsulfanyl)-pyrimidine-5-carbonitrile —— C15H11N5OS
    2-Amino-4-furan-2-yl-6-(pyridin-2-ylmethylsulfanyl)-pyrimidine-5-carbonitrile
    —— 6-(5,5-Dimethyl-6-oxohexyl)sulfinyl-2,2-dimethylhexanal —— C16H30O3S
    6-(5,5-Dimethyl-6-oxohexyl)sulfinyl-2,2-dimethylhexanal
    —— (4-amino-5-thiophen-2-ylmethyl-pyrimidin-2-ylsulfanyl)-acetic acid methyl ester 476302-03-1 C12H13N3O2S2
    (4-amino-5-thiophen-2-ylmethyl-pyrimidin-2-ylsulfanyl)-acetic acid methyl ester
    —— 2-[(1R)-3-amino-1-(3-chloro-1,2-oxazol-5-yl)propyl]sulfanyl-6-methylpyridine-3-carbonitrile —— C13H13ClN4OS
    2-[(1R)-3-amino-1-(3-chloro-1,2-oxazol-5-yl)propyl]sulfanyl-6-methylpyridine-3-carbonitrile
    —— 4-methylthio-3-(isoxazol-3-yl)-2-ethylbromobenzene 391199-98-7 C12H12BrNOS
    4-methylthio-3-(isoxazol-3-yl)-2-ethylbromobenzene
    —— 2-[[5-[(2-methylphenyl)methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine —— C16H16N4S
    2-[[5-[(2-methylphenyl)methyl]-1H-1,2,4-triazol-3-yl]sulfanylmethyl]pyridine
    —— (Tetrahydrofuran-2-ylmethyl)dithiocarbamic acid 2,4-difluoro-phenyl ester 370065-44-4 C12H13F2NOS2
    (Tetrahydrofuran-2-ylmethyl)dithiocarbamic acid 2,4-difluoro-phenyl ester
    —— 3-benzylsulfanyl-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole —— C14H13N3S2
    3-benzylsulfanyl-5-(thiophen-2-ylmethyl)-1H-1,2,4-triazole
    —— (+)-Exo-6-(3-butylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane —— C13H21N3S2
    (+)-Exo-6-(3-butylthio-1,2,5-thiadiazol-4-yl)-1-azabicyclo[3.2.1]octane
    —— methyl (E)-4,4-dimethyl-3-phenylsulfanylpent-2-enoate —— C14H18O2S
    methyl (E)-4,4-dimethyl-3-phenylsulfanylpent-2-enoate
    —— 2-[(2,2,5,5-tetramethyl-1H-imidazol-4-yl)sulfanyl]ethanol —— C9H18N2OS
    2-[(2,2,5,5-tetramethyl-1H-imidazol-4-yl)sulfanyl]ethanol
    —— 3-[(5-chlorothiophen-2-yl)methylsulfanyl]-1H-1,2,4-triazol-5-amine —— C7H7ClN4S2
    3-[(5-chlorothiophen-2-yl)methylsulfanyl]-1H-1,2,4-triazol-5-amine
    —— 1-(2-hydroxyethyl)-3-[(1R,2R)-2-methylcyclohexyl]thiourea —— C10H20N2OS
    1-(2-hydroxyethyl)-3-[(1R,2R)-2-methylcyclohexyl]thiourea
    —— 1-Tert-butylsulfinyl-2-methylpropane —— C8H18OS
    1-Tert-butylsulfinyl-2-methylpropane
    —— (4R)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-oxo-1-oxaspiro[4.5]decane-4-carboxamide —— C18H22ClNO3S
    (4R)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-oxo-1-oxaspiro[4.5]decane-4-carboxamide
    —— (4S)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-oxo-1-oxaspiro[4.5]decane-4-carboxamide —— C18H22ClNO3S
    (4S)-N-[2-(4-chlorophenyl)sulfanylethyl]-2-oxo-1-oxaspiro[4.5]decane-4-carboxamide
    —— (3S)-8-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1-oxa-8-azaspiro[4.5]decan-3-ol —— C16H22N4O3S
    (3S)-8-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]-1-oxa-8-azaspiro[4.5]decan-3-ol
    —— (2S)-N-[2-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]oxane-2-carboxamide —— C13H22N4O2S
    (2S)-N-[2-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]oxane-2-carboxamide
    —— (2R)-N-[2-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]oxane-2-carboxamide —— C13H22N4O2S
    (2R)-N-[2-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]oxane-2-carboxamide
    —— 2-[(2S)-4-propan-2-ylmorpholin-2-yl]-N-(2-pyridin-2-ylsulfanylethyl)acetamide —— C16H25N3O2S
    2-[(2S)-4-propan-2-ylmorpholin-2-yl]-N-(2-pyridin-2-ylsulfanylethyl)acetamide
    —— 4-[(3S)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]piperidin-3-yl]pyrimidine —— C17H20N6OS
    4-[(3S)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]piperidin-3-yl]pyrimidine
    —— 2-[(2R)-4-propan-2-ylmorpholin-2-yl]-N-(2-pyridin-2-ylsulfanylethyl)acetamide —— C16H25N3O2S
    2-[(2R)-4-propan-2-ylmorpholin-2-yl]-N-(2-pyridin-2-ylsulfanylethyl)acetamide
    —— 3-chloro-N-[3,5-dichloro-4-[[5-(trifluoromethyl)-1,3-benzothiazol-2-yl]sulfanyl]phenyl]-5-(trifluoromethyl)benzenesulfonamide —— C21H9Cl3F6N2O2S3
    3-chloro-N-[3,5-dichloro-4-[[5-(trifluoromethyl)-1,3-benzothiazol-2-yl]sulfanyl]phenyl]-5-(trifluoromethyl)benzenesulfonamide
    —— 4-[(3R)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]piperidin-3-yl]pyrimidine —— C17H20N6OS
    4-[(3R)-1-[[5-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]furan-2-yl]methyl]piperidin-3-yl]pyrimidine
    —— dichloromanganese;3-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]propan-1-ol —— C24H41Cl2MnN5OS
    dichloromanganese;3-[[(4R,9R,14R,19R)-3,10,13,20,26-pentazatetracyclo[20.3.1.04,9.014,19]hexacosa-1(25),22(26),23-trien-24-yl]sulfanyl]propan-1-ol
    —— 2-[6-chloro-3-[[2,2-difluoro-2-(1-oxidopyridin-1-ium-2-yl)ethyl]amino]-2-oxopyrazin-1-yl]-N-[[3-(2,2,2-trifluoroethylsulfanyl)pyridin-2-yl]methyl]acetamide —— C21H18ClF5N6O3S
    2-[6-chloro-3-[[2,2-difluoro-2-(1-oxidopyridin-1-ium-2-yl)ethyl]amino]-2-oxopyrazin-1-yl]-N-[[3-(2,2,2-trifluoroethylsulfanyl)pyridin-2-yl]methyl]acetamide
    —— (4R)-N-[3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propyl]-2-oxo-1-oxaspiro[4.5]decane-4-carboxamide —— C16H23N3O3S2
    (4R)-N-[3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propyl]-2-oxo-1-oxaspiro[4.5]decane-4-carboxamide
    —— (4S)-N-[3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propyl]-2-oxo-1-oxaspiro[4.5]decane-4-carboxamide —— C16H23N3O3S2
    (4S)-N-[3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propyl]-2-oxo-1-oxaspiro[4.5]decane-4-carboxamide
    —— (Z)-3-(dimethylamino)-2-ethylsulfonylprop-2-enenitrile —— C7H12N2O2S
    (Z)-3-(dimethylamino)-2-ethylsulfonylprop-2-enenitrile
    —— ethyl (2R)-2-(4-cyclopropylsulfanylphenyl)-2-hydroxyacetate —— C13H16O3S
    ethyl (2R)-2-(4-cyclopropylsulfanylphenyl)-2-hydroxyacetate