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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide —— C19H22FNOS
    (2S)-2-(2,4-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— [2-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] 2-phenylsulfanylacetate —— C19H18N2O3S2
    [2-[2,5-Dimethyl-1-(1,3-thiazol-2-yl)pyrrol-3-yl]-2-oxoethyl] 2-phenylsulfanylacetate
    —— [2-[2-(2,4-Dioxo-1,3-thiazolidin-3-yl)ethylamino]-2-oxoethyl] 2-phenylsulfanylacetate —— C15H16N2O5S2
    [2-[2-(2,4-Dioxo-1,3-thiazolidin-3-yl)ethylamino]-2-oxoethyl] 2-phenylsulfanylacetate
    —— [(2R)-1-[[(1S,2R)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate —— C18H25NO3S
    [(2R)-1-[[(1S,2R)-2-methylcyclohexyl]amino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate
    —— 2-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one —— C18H20N4O2S
    2-[(1R)-1-[5-(4-methylphenyl)-1,3,4-oxadiazol-2-yl]ethyl]sulfanyl-4-propyl-1H-pyrimidin-6-one
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[(2S)-2-phenylpropyl]acetamide —— C19H23NOS
    2-(2,4-dimethylphenyl)sulfanyl-N-[(2S)-2-phenylpropyl]acetamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide —— C15H21NO3S2
    2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-3-methyl-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C15H21NO2S
    2-(2,4-dimethylphenyl)sulfanyl-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— N-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C11H12N4O2S3
    N-[2-(4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— (2R)-2-(2,5-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide —— C19H22FNOS
    (2R)-2-(2,5-dimethylphenyl)sulfanyl-N-[2-(4-fluorophenyl)ethyl]propanamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C20H25NO3S2
    2-(2,4-dimethylphenyl)sulfanyl-1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C15H16FN3OS
    (2S)-N-[(1S)-1-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H21N5OS2
    N-[(1S)-1-cyano-1-cyclopropylethyl]-2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2R)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-pyrimidin-2-ylsulfanylpropan-1-one —— C20H17ClN4O2S
    (2R)-1-[(3R)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-pyrimidin-2-ylsulfanylpropan-1-one
    —— (2R)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-pyrimidin-2-ylsulfanylpropan-1-one —— C18H19N3O2S
    (2R)-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-pyrimidin-2-ylsulfanylpropan-1-one
    —— N-[2-(4-fluorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C16H19FN4OS
    N-[2-(4-fluorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— (2R)-N-(1-adamantyl)-2-pyrimidin-2-ylsulfanylpropanamide —— C17H23N3OS
    (2R)-N-(1-adamantyl)-2-pyrimidin-2-ylsulfanylpropanamide
    —— 2-[[5-(2-Methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C12H12N4OS
    2-[[5-(2-Methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H22N4O2S
    N-tert-butyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-benzyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H20N4O2S
    N-benzyl-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 6-Amino-5-[2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione —— C15H20N6O3S
    6-Amino-5-[2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetyl]-1-propylpyrimidine-2,4-dione
    —— 2-(Furan-2-yl)-5-(pyrimidin-2-ylsulfanylmethyl)-1,3,4-oxadiazole —— C11H8N4O2S
    2-(Furan-2-yl)-5-(pyrimidin-2-ylsulfanylmethyl)-1,3,4-oxadiazole
    —— 1-[1-(Furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C19H22N4O2S
    1-[1-(Furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— N-[(4-fluorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H19FN4O2S
    N-[(4-fluorophenyl)methyl]-2-[[5-(2-methylfuran-3-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C15H16FN3OS
    (2R)-N-[(1R)-1-(4-fluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide —— C16H20N4O3S3
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide
    —— 1-(5-Phenyl-3,4-dihydropyrazol-2-yl)-2-pyrimidin-2-ylsulfanylethanone —— C15H14N4OS
    1-(5-Phenyl-3,4-dihydropyrazol-2-yl)-2-pyrimidin-2-ylsulfanylethanone
    —— N-[(1S)-1-(4-ethylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C16H19N3OS
    N-[(1S)-1-(4-ethylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— 1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-pyrimidin-2-ylsulfanylethanone —— C16H19N3O3S2
    1-[1-[(3S)-1,1-dioxothiolan-3-yl]-2,5-dimethylpyrrol-3-yl]-2-pyrimidin-2-ylsulfanylethanone
    —— N-[[(2R)-oxolan-2-yl]methyl]-2-pyrimidin-2-ylsulfanylacetamide —— C11H15N3O2S
    N-[[(2R)-oxolan-2-yl]methyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— (2S)-N-(1-cyanocyclohexyl)-2-pyrimidin-2-ylsulfanylpropanamide —— C14H18N4OS
    (2S)-N-(1-cyanocyclohexyl)-2-pyrimidin-2-ylsulfanylpropanamide
    —— N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide —— C14H13F2N3OS
    N-[(1R)-1-(2,4-difluorophenyl)ethyl]-2-pyrimidin-2-ylsulfanylacetamide
    —— 1-[1-[2-(4-Fluorophenyl)ethyl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C22H25FN4OS
    1-[1-[2-(4-Fluorophenyl)ethyl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 2-(Furan-2-yl)-5-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole —— C13H13N5O2S
    2-(Furan-2-yl)-5-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanylmethyl]-1,3,4-oxadiazole
    —— (2S)-N-(1-adamantyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C19H28N4OS
    (2S)-N-(1-adamantyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-(2-cyanoethyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C11H15N5OS
    N-(2-cyanoethyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 1-[1-[(2-Chlorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C21H23ClN4OS
    1-[1-[(2-Chlorophenyl)methyl]-2,5-dimethylpyrrol-3-yl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 7-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C13H8N4O3S2
    7-[[5-(Furan-2-yl)-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 2-(2-cyanophenyl)sulfanyl-N-[(4-fluorophenyl)methyl]-N-methylbenzamide —— C22H17FN2OS
    2-(2-cyanophenyl)sulfanyl-N-[(4-fluorophenyl)methyl]-N-methylbenzamide
    —— 2-[(4-Cyclopropyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone —— C14H17N3OS2
    2-[(4-Cyclopropyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-(2,5-dimethylthiophen-3-yl)ethanone
    —— [(2R)-1-amino-1-oxopropan-2-yl] 2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylbenzoate —— C18H17N3O3S2
    [(2R)-1-amino-1-oxopropan-2-yl] 2-(5,6-dimethylthieno[2,3-d]pyrimidin-4-yl)sulfanylbenzoate
    —— [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 3-methyl-1,2-oxazole-5-carboxylate —— C16H18N2O4S
    [2-[2-(4-Methylphenyl)sulfanylethylamino]-2-oxoethyl] 3-methyl-1,2-oxazole-5-carboxylate
    —— 2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-N-(cyclopenten-1-yl)-N-ethylacetamide —— C15H16ClF3N2OS
    2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-N-(cyclopenten-1-yl)-N-ethylacetamide
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C15H22N4O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— N-(cyclohexen-1-yl)-N-cyclopropyl-2-(1-methyltetrazol-5-yl)sulfanylacetamide —— C13H19N5OS
    N-(cyclohexen-1-yl)-N-cyclopropyl-2-(1-methyltetrazol-5-yl)sulfanylacetamide
    —— (2S)-2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylpropanenitrile —— C22H18N4S2
    (2S)-2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-3-phenylpropanenitrile
    —— 2-[(1R)-1-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C11H10N4OS3
    2-[(1R)-1-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— [(1S)-2-(dimethylamino)-2-oxo-1-phenylethyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C24H20N2O3S
    [(1S)-2-(dimethylamino)-2-oxo-1-phenylethyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— N-cyclopentyl-2-(2,4-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide —— C19H27NO3S2
    N-cyclopentyl-2-(2,4-dimethylphenyl)sulfanyl-N-[(3R)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(1R)-1-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C16H15N5O2S2
    2-[(1R)-1-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-thiophen-2-yl-1,3,4-oxadiazole